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Anion and cation emission following water dissociation was studied for 6.6-keV $^{16}$O$^{+}$ + H$_{2}$O collisions. Absolute cross sections for the emission of all positively and negatively charged fragments, differential in both energy…

We perform molecular dynamics simulations using the extended simple point charge SPC/E water model in order to investigate the dynamical behavior of supercooled-stretched water. We focus on the behavior of the translational diffusion…

Statistical Mechanics · Physics 2007-05-23 P. A. Netz , F. Starr , M. C. Barbosa , H. Eugene Stanley

We present quantum dynamical calculations that describe the rotational excitation of H$_2$O due to collisions with H atoms. We used a recent, high accuracy potential energy surface, and solved the collisional dynamics with the…

Astrophysics of Galaxies · Physics 2015-06-23 F. Daniel , A. Faure , P. J. Dagdigian , M. -L. Dubernet , F. lique , G. Pineau des forêts

Certain subterranean environments of Earth have naturally accumulated long-lived radionuclides, such as 238U, 232Th and 40K, near the presence of liquid water. In these natural radioactive environments (NRE), water radiolysis can produce…

Our knowledge about the "cold" Universe often relies on molecular spectra. A general property of such spectra is that the energy level populations are rarely at local thermodynamic equilibrium. Solving the radiative transfer thus requires…

Instrumentation and Methods for Astrophysics · Physics 2018-01-23 Jérôme Loreau , François Lique , Alexandre Faure

In the present work, molecular dynamics study of diffusion of Gamma Aminobutyric acid in water at different temperatures 298.2 K, 303.2 K, 313.2 K, 323.2 K, 333.2 K have been performed. The solute and solvent is modeled using OPLS AA…

Chemical Physics · Physics 2018-06-27 Esha Mishra , Narayan Prasad Adhikari

We use {\it ab initio} molecular dynamics simulations to study a sample of liquid silica containing 3.84 wt.% H$_2$O.We find that, for temperatures of 3000 K and 3500 K,water is almost exclusively dissolved as hydroxyl groups, the silica…

Disordered Systems and Neural Networks · Physics 2009-11-10 Markus Poehlmann , Magali Benoit , Walter Kob

We consider a particle diffusing inside a wedge with absorbing boundaries and driven by a radial flow of incompressible fluid generated by a source at the apex. The survival probability decays as (time)^{-b} with exponent depending on the…

Fluid Dynamics · Physics 2022-08-02 P. L. Krapivsky

A dielectric solvation model is applied to the prediction of the equilibrium ionization of liquid water over a wide range of density and temperature with the objective of calibrating that model for the study of ionization in water of…

chem-ph · Physics 2009-09-25 Gregory J. Tawa , Lawrence R. Pratt

The results of the molecular dynamics simulation of the radiation influence on the structure and thermophysical properties of water are presented. The changes in the radial distribution functions, momentum distribution function and the…

Statistical Mechanics · Physics 2017-01-25 L. A. Bulavin , K. V. Cherevko , D. A. Gavryushenko , V. M. Sysoev , T. S. Vlasenko

Aqueous radiation chemistry emerges through ultrafast proton transfer and ion-radical formation with unexplored energy-redistribution dynamics steering the subsequent reactions. We performed time-resolved disruptive probing on pure water…

Understanding the degradation mechanisms of aliphatic polymers by thermal oxidation and radio-oxidation is very important in order to assess their lifetime in a variety of industrial applications. We focus here on polyethylene as a…

Soft Condensed Matter · Physics 2021-07-01 Yunho Ahn , Xavier Colin , Guido Roma

Low-temperature hydrocarbon autooxidation involves radical intermediates whose reactivity depends not only on the stereochemistry of the intermediates themselves, but also on that of the transient species encountered along the reaction…

Chemical Physics · Physics 2026-04-21 Raghunathan Ramakrishnan

Understanding the damage of DNA bases from hydrogen abstraction by free OH radicals is of particular importance to reveal the effect of hydroxyl radicals produced by the secondary effect of radiation. Previous studies address the problem…

Computational Physics · Physics 2016-09-28 Ramin M. Abolfath , P. K. Biswas , R. Rajnarayanam , Thomas Brabec , Reinhard Kodym , Lech Papiez

We present a density-functional theory based molecular-dynamics study of the structural, dynamical, and electronic properties of liquid methanol under ambient conditions. The calculated radial distribution functions involving the oxygen and…

Chemical Physics · Physics 2009-11-07 Jan-Willem Handgraaf , Titus S. van Erp , Evert Jan Meijer

A low pressure discharge sustained in molecular hydrogen with help of the electron cyclotron resonance heating at a frequency of 2.45 GHz is simulated using a fully electromagnetic implicit charge- and energy-conserving…

The transport of low-energy electrons through the coating of a radiosensitizing metallic nanoparticle under fast ion irradiation is analyzed theoretically and numerically. As a case study, we consider a poly(ethylene glycol)-coated gold…

Atomic and Molecular Clusters · Physics 2018-06-26 Kaspar Haume , Pablo de Vera , Alexey Verkhovtsev , Eugene Surdutovich , Nigel J. Mason , Andrey V. Solov'yov

Molecular dynamics simulation is a prominent way of analyzing the dynamic properties of a system. The molecular dynamics simulation of diffusion, an important transport property, of dilute solution of cysteine in SPCE water at five…

Chemical Physics · Physics 2018-09-25 Hem Prasad Bhusal , Narayan Prasad Adhikari

The diffusion of active microscopic organisms in complex environments plays an important role in a wide range of biological phenomena from cell colony growth to single organism transport. Here, we investigate theoretically and…

Fluid Dynamics · Physics 2018-01-16 Juan L. Aragones , Shahrzad Yazdi , Alfredo Alexander-Katz

Photoevaporation is an important dispersal mechanism for protoplanetary disks. We conduct hydrodynamic simulations coupled with ray-tracing radiative transfer and consistent thermochemistry to study photoevaporative winds driven by…

Earth and Planetary Astrophysics · Physics 2017-09-20 Lile Wang , Jeremy J. Goodman