Related papers: Non-adiabatic decay of Rydberg-atom-ion molecules
Long-range Rydberg molecules are typically bound in wells formed in their oscillatory potential energy curves. In alkaline Rydberg molecules, bound vibrational states exist even when these potential wells are disrupted by level repulsion…
The lifetimes and decay channels of ultralong-range Rydberg molecules created in a dense BEC are examined by monitoring the time evolution of the Rydberg population using field ionization. Studies of molecules with values of principal…
Ultralong-range Rydberg molecules (ULRM) are highly imbalanced bound systems formed via the low-energy scattering of a Rydberg electron with a ground-state atom. We investigate for $^{23}$Na the $d$-state and the energetically close-by…
Long-range Rydberg molecules (LRMs) form when a highly excited Rydberg electron scatters from ground-state atoms inside its orbit, creating oscillatory, long-range potentials. We present a combined theoretical and experimental study of…
Nonadiabatic geometric quantum computation provides a means to perform fast and robust quantum gates. It has been implemented in various physical systems, such as trapped ions, nuclear magnetic resonance and superconducting circuits.…
The lifetimes of the lower-lying vibrational states of ultralong-range strontium Rydberg molecules comprising one ground-state 5s2 1S0 atom and one Rydberg atom in the 5s38s 3S1 state are reported. The molecules are created in an ultracold…
We investigate the non-adiabatic quantum dynamics of ultralong-range Rydberg molecules using a vibronically coupled two-channel treatment. The two channels are composed of coupled trilobite and butterfly electronic states, formed as a…
We study the occurrence of Rydberg atom-ion molecules (RAIMs) in a hybrid atom-ion system with an ion crystal trapped in a Paul trap coupled to Rydberg atoms on its either ends. To assess the feasibility of such a system, we perform a…
Among the thriving quantum computation and quantum simulation platforms based on arrays of Rydberg atoms, those using circular Rydberg atoms are particularly promising. These atoms uniquely combine the strong dipole-dipole interactions…
A remarkable property of Rydberg atoms is the possibility to create molecules formed by one highly excited atom and another atom in the ground state. The first realisation of such a Rydberg molecule has opened an active field of physical…
Ultralong-range Rydberg molecules provide an exciting testbed for molecular physics at exaggerated scales. In the so-called trilobite and butterfly Rydberg molecules, the Born-Oppenheimer approximation can fail due to strong non-adiabatic…
Rydberg atom arrays are a leading platform for quantum computing and simulation, combining strong interactions with highly coherent operations and flexible geometries. However, the achievable fidelities are limited by the finite lifetime of…
Recently, Rydberg atoms appeared as a viable alternative to the quantum gates built on atomic or molecular ions. The lifetimes of the circular Rydberg states can be in the millisecond range. That prevents inherent metastability of the…
Avoided crossings of level pairs with opposite slopes can form potential energy curves for the external degree of freedom of quantum particles. We investigate nonadiabatic decay of metastable states on such avoided crossings (MSACs) using…
Assemblies of highly excited Rydberg atoms in an ultracold gas can be set into motion by a combination of van-der-Waals and resonant dipole-dipole interactions. Thereby, the collective electronic Rydberg state might change due to…
We have developed an all-optical method for measuring the lifetimes of $n S$ and $n D$ Rydberg states and demonstrate its capabilities with measurements on a dilute cloud of ultracold ${}^{87}$Rb atoms in a cryogenic environment. The method…
Nonadiabatic ring-polymer molecular dynamics employs the mapping approach to describe nonadiabatic effects within the ring-polymer ansatz. In this paper, it is generalized to allow for the nuclear and electronic degrees of freedom to be…
We consider ultralong-range polyatomic Rydberg molecules formed by combining a Rydberg cesium atom and a ground-state RbCs molecule. We explore the regime where the charge-dipole interaction due to the Rydberg electron with the diatomic…
Coherence time and gate fidelities in Rydberg atom quantum simulators and computers are fundamentally limited by the Rydberg state lifetime. Circular Rydberg states are highly promising candidates to overcome this limitation by orders of…
Accurate description of nonadiabatic dynamics of molecules at metal surfaces involving electron transfer has been a longstanding challenge for theory. Here, we tackle this problem by first constructing high-dimensional neural network…