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Carbon nanotubes (CNTs) are a promising material for high-performance electronics beyond silicon. But unlike silicon, the nature of the transport band gap in CNTs is not fully understood. The transport gap in CNTs is predicted to be…

Osmotic transport in nanoconfined aqueous electrolytes provides new venues for water desalination and "blue energy" harvesting; the osmotic response of nanofluidic systems is controlled by the interfacial structure of water and electrolyte…

Chemical Physics · Physics 2022-08-16 Laurent Joly , Robert H. Meißner , Marcella Iannuzzi , Gabriele Tocci

The high field charge injection and transport properties in reinforced silicone dielectrics were investigated by measuring the time-dependent space charge distribution and the current under dc conditions up to the breakdown field, and were…

Materials Science · Physics 2016-08-04 Yanhui Huang , Linda. S. Schadler

Using computer simulations, the electrophoretic motion of a positively charged colloid (macroion) in an electrolyte solution is studied in the framework of the primitive model. Hydrodynamic interactions are fully taken into account by…

Soft Condensed Matter · Physics 2015-06-25 Apratim Chatterji , Jürgen Horbach

To bridge the gap between single/isolated pore systems to multi-pore systems, such as membranes/electrodes, we studied an array of nanochannels with varying interchannel spacing that controlled the degree of channel communication. Instead…

Fluid Dynamics · Physics 2015-01-29 Yoav Green , Sinwook Park , Gilad Yossifon

We consider a coupled system of Navier Stokes, Maxwell Stefan and Poisson Boltzmann equations by incorporating the variation of dielectric constant, which governs the electro osmotic flow in nano channel, describing the evolution of the…

Fluid Dynamics · Physics 2016-02-24 Rajendra Padidhapu , Shahnaz Bathul , V. Brahmajirao

We uncover a new pathway towards multiferroicity, showing how magnetism can drive ferroelectricity without relying on inversion symmetry breaking of the magnetic ordering. Our free-energy analysis demonstrates that any commensurate…

Materials Science · Physics 2009-11-11 Joseph J. Betouras , Gianluca Giovannetti , Jeroen van den Brink

Force field have for decades proven to be an indispensable tool for molecular simulations which are out of reach for ab-initio methods. Recent efforts to improve the accuracy of these simulations have focused on the inclusion of many-body…

Chemical Physics · Physics 2020-06-26 Ruben Goeminne , Toon Verstraelen

Passive particle transport through narrow channels is well studied, while for active particle systems, it is not well understood. Here, we demonstrate the active control of the transport through a nanopore via mean-field analysis and…

Soft Condensed Matter · Physics 2021-07-21 Cheng Lian , Wei Zhong

Transport of water through ion-exchange membranes is of importance both for electrodialysis (ED) and reverse electrodialysis (RED). In this work, we extend our previous theory [J. Membrane Sci., 510, (2016) 370-381] and include water…

Chemical Physics · Physics 2019-12-24 M. Tedesco , H. V. M. Hamelers , P. M. Biesheuvel

We present a numerical study of polyelectrolytes electrophoresing in free solution while squeezed by an axisymmetric confinement force transverse to their net displacement. Hybrid multi-particle collision dynamics and molecular dynamics…

Soft Condensed Matter · Physics 2016-06-22 Tyler N. Shendruk , Martin Bertrand , Gary W. Slater

We demonstrate that a highly charged polyelectrolyte confined in a spherical cavity undergoes reversible transformations between amorphous conformations to a four-fold symmetry morphology as a function of dielectric mismatch between the…

Soft Condensed Matter · Physics 2019-08-20 Trung Dac Nguyen , Monica Olvera de la Cruz

The ferroelectric polarization of perovskite oxides is much larger than implied by displacement of static ionic charges. We use an explicitly correlated scheme to investigate the phenomenon; charge transport is evaluated as a geometric…

Condensed Matter · Physics 2012-07-07 R. Resta , S. Sorella

Electrokinetic transport behavior in nanochannels is different to that in larger sized channels. Specifically, molecular dynamics (MD) simulations in nanochannels have demonstrated two little understood phenomena which are not observed in…

A nanocomposite film containing highly polarizable inclusions in a fluid background is explored when an external electric field is applied perpendicular to the planar film. For small electric fields, the induced dipole moments of the…

Soft Condensed Matter · Physics 2025-06-27 Elshad Allahyarov , Hartmut Löwen

Most ionic liquids contain at least one rather complex ion species exhibiting a dipolar moment. In the present work, we provide a thorough evaluation of broadband dielectric spectra of 12 ionic liquids taking into account the often…

Soft Condensed Matter · Physics 2018-11-21 P. Sippel , S. Krohns , D. Reuter , P. Lunkenheimer , A. Loidl

Most organic and inorganic surfaces (e.g., glass, nucleic acids or lipid membranes) become charged in aqueous solutions. The resulting ionic distribution induces effective interactions between the charged surfaces. Stacks of like-charged…

One of the most promising applications in nanoscience is the design of new materials to improve water permeability and selectivity of nanoporous membranes. Understanding the molecular architecture behind these fascinating structures and how…

Soft Condensed Matter · Physics 2021-09-10 João P. K. Abal , Rodrigo F. Dillenburg , Mateus H. Köhler , Marcia C. Barbosa

Nanopores are both a tool to study single-molecule biophysics and nanoscale ion transport, but also a promising material for desalination or osmotic power generation. Understanding the physics underlying ion transport through nano-sized…

Soft Condensed Matter · Physics 2021-04-02 Sanjin Marion , Michal Macha , Sebastian J. Davis , Andrey Chernev , Aleksandra Radenovic

The transport of fluids at the nanoscale is fundamental to manifold biological and industrial processes, ranging from neurotransmission to ultrafiltration. Yet, it is only recently that well-controlled channels with cross-sections as small…

Mesoscale and Nanoscale Physics · Physics 2022-10-05 Nikita Kavokine , Paul Robin , Lydéric Bocquet