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Catalytic processes are vital in the chemical industry, with nitrogen-to-ammonia conversion being a major industrial process. Designing catalysts relies on computational chemistry methods like Density Functional Theory (DFT), which have…

Accurate computational predictions of metal-organic frameworks (MOFs) and their properties is crucial for discovering optimal compositions and applying them in relevant technological areas. This work benchmarks density functional theory…

Materials Science · Physics 2025-03-11 Joshua Edzards , Julia Santana Andreo , Holger-Dietrich Saßnick , Caterina Cocchi

Two-dimensional (2D) metal-organic frameworks (MOFs) in a kagome lattice can exhibit strong electron-electron interactions, which can lead to tunable quantum phases including many exotic magnetic phases. While technological developments of…

Strongly Correlated Electrons · Physics 2022-11-10 Bernard Field , Agustin Schiffrin , Nikhil V. Medhekar

Virtual high throughput screening (VHTS) and machine learning (ML) have greatly accelerated the design of single-site transition-metal catalysts. VHTS of catalysts, however, is often accompanied with high calculation failure rate and wasted…

Chemical Physics · Physics 2022-03-03 Chenru Duan , Aditya Nandy , Husain Adamji , Yuriy Roman-Leshkov , Heather J. Kulik

The increasing CO2 level is a critical concern and suitable materials are needed to capture such gases from the environment. While experimental and conventional computational methods are useful in finding such materials, they are usually…

Metal organic frameworks (MOFs) are promising photocatalytic materials due to their high surface area and tuneability of their electronic structure. We discuss here how to engineer the band structures and optical properties of a family of…

Organic molecular crystals are ideally placed to become next-generation piezoelectric materials due to their diverse chemistries that can be used to engineer tailor-made solid-state assemblies. Using crystal engineering principles, and…

Materials Science · Physics 2024-12-11 Shubham Vishnoi , Geetu Kumari , Robert Guest , Pierre-André Cazade , Sarah Guerin

Discovering heterogeneous catalysts tailored for specific reaction intermediates remains a fundamental bottleneck in materials science. While traditional trial-and-error methods and recent generative models have shown promise, they struggle…

Materials Science · Physics 2026-05-19 Minkyu Kim , Nayoung Kim , Honghui Kim , Sungsoo Ahn

Recent decades have witnessed great advancements in multiobjective evolutionary algorithms (MOEAs) for multiobjective optimization problems (MOPs). However, these progressively improved MOEAs have not necessarily been equipped with scalable…

Neural and Evolutionary Computing · Computer Science 2023-02-28 Songbai Liu , Qiuzhen Lin , Jianqiang Li , Kay Chen Tan

Metal-organic frameworks (MOFs) are highly interesting and tunable materials. By incorporating spatial defects into their atomic structure, MOFs can be finetuned to exhibit precise chemical functionalities, extending their applicability in…

Materials Science · Physics 2025-04-08 Pieter Dobbelaere , Sander Vandenhaute , Veronique Van Speybroeck

Compositionally complex alloys or concentrated solid solutions are the latest frontier in catalyst design, but mixing different elements in one catalyst may result in surface segregation. Atomistic simulations can predict segregation…

Materials Science · Physics 2022-12-12 Alberto Ferrari , Vadim Sotskov , Alexander V. Shapeev , Fritz Körmann

An exciting development over the past few decades has been the use of high-throughput computational screening as a means of identifying promising candidate materials for a variety of structural or functional properties. Experimentally, it…

Materials Science · Physics 2020-02-12 Christina A. C. Garcia , Joshua D. Bocarsly , Ram Seshadri

Nanoscale design of surfaces and interfaces is essential for modern technologies like organic LEDs, batteries, fuel cells, superlubricating surfaces, and heterogeneous catalysis. However, these systems often exhibit complex surface…

Materials Science · Physics 2025-07-08 Lukas Hörmann , Wojciech G. Stark , Reinhard J. Maurer

The sustainable production of many bulk chemicals relies on heterogeneous catalysis. The rational design or improvement of the required catalysts critically depends on insights into the underlying mechanisms at the atomic scale. In recent…

Chemical Physics · Physics 2024-11-04 Amir Omranpour , Jan Elsner , K. Nikolas Lausch , Jörg Behler

High-throughput approximations of quantum mechanics calculations and combinatorial experiments have been traditionally used to reduce the search space of possible molecules, drugs and materials. However, the interplay of structural and…

Quantum Physics · Physics 2019-10-29 Alain Tchagang , Julio Valdés

We investigate the existence of linear magnetism in the metal organic framework materials MOF-74-Fe, MOF-74-Co, and MOF-74-Ni, using first-principles density functional theory. MOF-74 displays regular quasi-linear chains of open-shell…

Materials Science · Physics 2013-03-08 Pieremanuele Canepa , Yves J. Chabal , T. Thonhauser

Metal-organic frameworks (MOFs) are crystalline materials consisting of metal centers and organic linkers forming open and porous structures. They have been extensively studied due to various possible applications exploiting their large…

Materials Science · Physics 2019-11-20 Tomas Kamencek , Natalia Bedoya-Martínez , Egbert Zojer

A force field is a critical component in molecular dynamics simulations for computational drug discovery. It must achieve high accuracy within the constraints of molecular mechanics' (MM) limited functional forms, which offers high…

Machine Learning · Computer Science 2024-10-10 Tianze Zheng , Ailun Wang , Xu Han , Yu Xia , Xingyuan Xu , Jiawei Zhan , Yu Liu , Yang Chen , Zhi Wang , Xiaojie Wu , Sheng Gong , Wen Yan

ChatMOF is an autonomous Artificial Intelligence (AI) system that is built to predict and generate metal-organic frameworks (MOFs). By leveraging a large-scale language model (GPT-4 and GPT-3.5-turbo), ChatMOF extracts key details from…

Computation and Language · Computer Science 2023-08-28 Yeonghun Kang , Jihan Kim

Metal-organic framework (MOFs) are nanoporous materials that could be used to capture carbon dioxide from the exhaust gas of fossil fuel power plants to mitigate climate change. In this work, we design and train a message passing neural…

Materials Science · Physics 2020-12-08 Ali Raza , Faaiq Waqar , Arni Sturluson , Cory Simon , Xiaoli Fern