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Neutron powder diffraction has been used to investigate the structural and magnetic behavior of the isoelectronically doped Fe pnictide material PrFe1-xRuxAsO. Substitution of Ru for Fe suppresses the structural and magnetic phase…

Superconductivity · Physics 2016-11-11 Yuen Yiu , V. Ovidiu Garlea , Michael A. McGuire , Ashfia Huq , David Mandrus , Stephen E. Nagler

Empirical A-site cation substitution has advanced the stability and efficiency of hybrid organic-inorganic lead halide perovskites solar cells and the functionality of X-ray detectors. Yet, the fundamental mechanisms underpinning their…

Modifying the optoelectronic properties of nanostructured materials through introduction of dopant atoms has attracted intense interest. Nevertheless, the approaches employed are often trial and error, preventing rational design. We…

Materials Science · Physics 2021-07-13 Michael G. Taylor , Heather J. Kulik

Using neutron elastic and inelastic scattering and high-energy x-ray diffraction, we present a comparison of 40% Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$-60% PbTiO$_{3}$ (PMN-60PT) with pure Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ (PMN) and PbTiO$_{3}$…

Materials Science · Physics 2009-11-11 C. Stock , D. Ellis , I. P. Swainson , Guangyong Xu , H. Hiraka , Z. Zhong , H. Luo , X. Zhao , D. Viehland , R. J. Birgeneau , G. Shirane

Different techniques of the X-ray Diffraction Line Profile Analysis (XRDLPA) have been used to assess the microstructure of the irradiated Zr-1.0%Nb-1.0%Sn-0.1%Fe alloy. The domain size, microstrain, density of dislocation and the stacking…

Materials Science · Physics 2007-05-23 A. Sarkar , P. Mukherjee , P. Barat

We use resonant soft X-ray diffraction to track the photo-induced dynamics of the antiferromagnetic structure in a NdNiO$_{3}$ thin film. Femtosecond laser pulses with a photon energy of 0.61 eV, resonant with electron transfer between…

Dynamic nuclear polarization experiments use microwave irradiation to transfer the larger electron polarization to nuclear spins of interest, and thus enhance the NMR transitions above thermal equilibrium. How the polarization transfer from…

Chemical Physics · Physics 2026-01-12 Gian-Marco Camenisch , Nino Wili , Gunnar Jeschke , Matthias Ernst

The nanoscopic magneto-electronic phase separation in doped La1-xSrxCoO3 perovskites was studied with local probes. The phase separation is directly observed by M\"ossbauer spectroscopy in the studied doping range of 0.05 <= x <= 0.25 both…

Scanning nanofocus X-ray diffraction (nXRD) performed at a synchrotron is used for the first time to simultaneously probe the morphology and the structural properties of spin-coated CH3NH3PbI3 (MAPI) perovskite films for photovoltaic…

We present a temperature and doping dependent resonant inelastic X-ray scattering experiment at the V L$_{2,3}$ and O K edges in La$_{1-x}$Sr$_x$VO$_3$ for $x=0$ and $x=0.1$. This material is a canonical example of a compound that exhibits…

Optically-pumped color centers in semiconductor powders can potentially induce high levels of nuclear spin polarization in surrounding solids or fluids at or near ambient conditions, but complications stemming from the random orientation of…

Electronic and structural degrees of freedom are often intimately coupled in strongly correlated systems, which result in intriguing macroscopic and microscopic phenomena. Using the well-studied material VO$_2$ as a prototype, here we…

We report neutron diffuse scattering measurements on a single crystal of 68%Pb(Mg1/3Nb2/3)O3-32%PbTiO3. Strong diffuse scattering is observed at low temperatures. An external field applied along the [001] direction affects the diffuse…

Materials Science · Physics 2008-08-26 Jinsheng Wen , Guangyong Xu , C. Stock , P. M. Gehring

Local fluctuations in the distribution of dopant atoms are a suspected cause of nanoscale electronic disorder or phase separation observed within the pnictide superconductors. Atom probe tomography results present the first direct…

Superconductivity · Physics 2011-06-30 W. K. Yeoh , B. Gault , X. Y. Cui , C. Zhu , M. P. Moody , L. Li , R. K. Zheng , W. X Li , X. L. Wang , S. X. Dou , C. T. Lin , S. P. Ringer

Perovskite nitrides are starting to be explored for their promising properties distinct from their oxide counterparts. Here, through first-principles density functional computations, we study the intricate relationship between…

Materials Science · Physics 2024-08-27 Harshvardhan Singh Deora , Awadhesh Narayan

Double perovskite, (Sr1-xNdx)2FeMoO6, was doped with electrons through partial substitution of divalent Sr by trivalent Nd (0 < x < 0.2). The Fe valence and the degree of B-site order were probed by 57Fe Mossbauer spectroscopy. Replacing Sr…

Strongly Correlated Electrons · Physics 2009-11-10 J. Linden , T. Shimada , T. Motohashi , H. Yamauchi , M. Karppinen

The recent observation of superconductivity in infinite-layer Nd$_{1-x}$Sr$_x$NiO$_2$ thin films has attracted a lot of attention, since this compound is electronically and structurally analogous to the superconducting cuprates. Due to the…

Astronomical X-ray observatories with grazing incidence optics face the problem of pseudo-focusing of low energy protons from the mirrors towards the focal plane. Those protons constitute a variable, unpredictable component of the non X-ray…

Instrumentation and Methods for Astrophysics · Physics 2020-04-15 R. Amato , T. Mineo , A. D'Aì , S. Diebold , V. Fioretti , A. Guzman , S. Lotti , C. Macculi , S. Molendi , E. Perinati , C. Tenzer , A. Santangelo

We present a combined study of Ni $K$-edge resonant x-ray scattering and density functional calculations to probe and distinguish electronically driven ordering and lattice distortions in nickelate heterostructures. We demonstrate that due…

Doping substantially influences the electronic and photophysical properties of semiconducting single-wall carbon nanotubes (s-SWNTs). Although prior studies have noted that surplus charge carriers modify optical spectra and accelerate…

Materials Science · Physics 2023-07-19 Klaus H. Eckstein , Pascal Kunkel , Markus Voelckel , Friedrich Schöppler , Tobias Hertel