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The formation of molecules in the interstellar medium (ISM) remains a complex and unresolved question in astrochemistry. A group of molecules of particular interest involves the linkage between a -carboxyl and -amine group, similar to that…

Astrophysics of Galaxies · Physics 2022-12-21 Caden Schuessler , Anthony Remijan , Ci Xue , Joshua Carder , Haley Scolati , Brett McGuire

The peptide-like molecules, cyanoformamide (NCCONH2), is the cyano (CN) derivative of formamide (NH2CHO). It is known to play a role in the synthesis of nucleic acid precursors under prebiotic conditions. In this paper, we present a…

Numerous complex organic molecules have been detected in the universe among which amides are considered as models for species containing the peptide linkage. Acrylamide bears in its backbone not only the peptide bond, but also the vinyl…

Interstellar molecules with a peptide link -NH-C(=O)-, like formamide (NH$_2$CHO), acetamide (NH$_2$COCH$_3$) and isocyanic acid (HNCO) are particularly interesting for their potential role in pre-biotic chemistry. We have studied their…

Solar and Stellar Astrophysics · Physics 2015-06-22 E. Mendoza , B Lefloch , A. López-Sepulcre , C. Ceccarelli , C. Codella , H. M. Boechat-Roberty , R. Bachiller

Acetamide (CH$_{3}$CONH$_{2}$), a key interstellar amide and a methyl derivative of formamide (NH$_{2}$CHO), has been sparsely detected, limiting insights into its prebiotic relevance. We present the first systematic survey for acetamide…

Astrophysics of Galaxies · Physics 2025-09-19 Chunguo Duan , Xuefang Xu , Qian Gou , Tie Liu , Laurent Pagani , Fengwei Xu , Ke Wang , Xunchuan Liu , Jun Kang , Mingwei He , Jiaxiang Jiao

Molecules with an amide functional group resemble peptide bonds, the molecular bridges that connect amino acids, and may thus be relevant in processes that lead to the formation of life. In this study, the solid state formation of some of…

Solar and Stellar Astrophysics · Physics 2018-08-08 N. F. W. Ligterink , J. Terwisscha van Scheltinga , V. Taquet , J. K. Jørgensen , S. Cazaux , E. F. van Dishoeck , H. Linnartz

Peptide-like molecule, which has a close connection with the origin of life, has been detected in universe. Mapping observations of HCONH$_2$ and CH$_3$CONH$_2$, two simplest peptide-like molecules, are performed towards Sagittarius B2 (Sgr…

Astrophysics of Galaxies · Physics 2023-10-26 Siqi Zheng , Juan Li , Junzhi Wang , Yao Wang , Feng Gao , Donghui Quan , Fujun Du , Yajun Wu , Edwin Bergin , Yuqiang Li

In recent years, organic molecules of increasing complexity have been found toward the prolific Galactic center source Sagittarius B2. We wish to explore the degree of complexity that the interstellar chemistry can reach in star-forming…

Astrophysics of Galaxies · Physics 2014-08-25 A. Belloche , R. T. Garrod , H. S. P. Müller , K. M. Menten , C. Comito , P. Schilke

A gas-phase formation route is proposed for the recently detected propargylimine molecule. In analogy to other imines, such as cyanomethanimine, the addition of a reactive radical (C$_2$H in the present case) to methanimine (CH$_2$NH})…

Astrophysics of Galaxies · Physics 2020-11-18 Jacopo Lupi , Cristina Puzzarini , Vincenzo Barone

Small imines containing up to three carbon atoms are present in the interstellar medium. As alkynyl compounds are abundant in this medium, propargylimine thus represents a promising candidate for a new interstellar detection. The goal of…

The saturated n-propyl cyanide was recently detected in Sagittarius B2(N). The next larger unbranched alkyl cyanide is n-butyl cyanide. We provide accurate rest frequency predictions beyond the millimeter wave range to search for this…

Astrophysics of Galaxies · Physics 2013-08-06 M. H. Ordu , H. S. P. Müller , A. Walters , M. Nuñez , F. Lewen , A. Belloche , K. M. Menten , S. Schlemmer

The radical hydrocarbon molecule C$_2$H is widely detected in various stages of star and planet formation, and has emerged as a useful tracer of high-C/O gas within the photochemically active surface layers of mature (Class II)…

Astrophysics of Galaxies · Physics 2025-08-07 Jack G. Anderson , Jennifer B. Bergner , Yao-Lun Yang , Yichen Zhang , Nami Sakai

In this work, we identify carbodiimide (HNCNH), which is an isomer of the well-known interstellar species cyanamide (NH2CN), in weak maser emission, using data from the GBT PRIMOS survey toward Sgr B2(N). All spectral lines observed are in…

In the interstellar medium, the amide-type molecules play an important role in the formation of the prebiotic molecules in the hot molecular cores or high-mass star formation regions. The complex amide-related molecule cyanamide…

Astrophysics of Galaxies · Physics 2022-11-02 Arijit Manna , Sabyasachi Pal

C-cyanomethanimine (HNCHCN), existing in the two $Z$ and $E$ isomeric forms, is a key prebiotic molecule, but, so far, only the $E$ isomer has been detected toward the massive star-forming region. Sagittarius B2(N) using transitions in the…

For all the amides detected in the interstellar medium (ISM), the corresponding nitriles or isonitriles have also been detected in the ISM, some of which have relatively high abundances. Among the abundant nitriles for which the…

Understanding whether prebiotic molecules can endure and reform through the energetic stages of star formation is essential for tracing the continuity of interstellar chemistry toward life. Glycolamide, an isomer of glycine, was recently…

Astrophysics of Galaxies · Physics 2026-05-06 Chunguo Duan , Fengwei Xu , Qian Gou , Xuefang Xu , Donghui Quan , Laurent Pagani , Xi Chen , Jun Kang , Jiaxin Du

Ethanediol is one of the largest complex organic molecules detected in space thus far. It has been found in different types of molecular clouds. The two propanediol isomers are the next larger diols. Hence, they are viable candidates to be…

Atomic and Molecular Clusters · Physics 2014-10-08 J. -B. Bossa , M. H. Ordu , H. S. P. Müller , F. Lewen , S. Schlemmer

After hydrogen, oxygen, and carbon, nitrogen is one of the most chemically active species in the interstellar medium (ISM). Nitrogen bearing molecules have great importance as they are actively involved in the formation of biomolecules.…

Solar and Stellar Astrophysics · Physics 2021-08-30 Prasanta Gorai , Bratati Bhat , Milan Sil , Suman K. Mondal , Rana Ghosh , Sandip K. Chakrabarti , Ankan Das

In star formation regions, the complex organic molecules (COMs) that contain peptide bonds ($-$NH$-$C(=O)$-$) play a major role in the metabolic process because $-$NH$-$C(=O)$-$ is connected to amino acids (R-CHNH$_{2}$$-$COOH). Over the…

Astrophysics of Galaxies · Physics 2024-07-09 Arijit Manna , Sabyasachi Pal
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