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Linear scaling density functional theory approaches to electronic structure are often based on the tendency of electrons to localize even in large atomic and molecular systems. However, in many cases of actual interest, for example in…

Chemical Physics · Physics 2022-03-25 Marcel David Fabian , Ben Shpiro , Roi Baer

We explore and compare three approximate schemes allowing simple implementation of complex density functionals by making use of selfconsistent implementation of simpler functionals: (i) post-LDA evaluation of complex functionals at the LDA…

Chu et al. recently reported extensive results of local density approximation (LDA) and of four (4) different Green function and dressed Coulomb (GW) approximation calculations of electronic properties of several semiconductors and…

Materials Science · Physics 2016-10-18 Diola Bagayoko , Yacouba Issa Diakite , Lashounda Franklin

Accurate prediction of spin-state energy difference is crucial for understanding the spin crossover (SCO) phenomena and is very challenging for the density functional approximations, especially for the local and semi-local approximations,…

Chemical Physics · Physics 2023-02-22 Selim Romero , Tunna Baruah , Rajendra R. Zope

We investigate quantum phase transitions in the transverse field Ising chain with algebraically decaying long-range (LR) antiferromagnetic interactions using the variational Monte Carlo method with the restricted Boltzmann machine employed…

Statistical Mechanics · Physics 2024-06-14 Jicheol Kim , Dongkyu Kim , Dong-Hee Kim

Density functional approximations (DFAs) suffer from delocalization error, which limits their accuracy in predicting electron affinities (EAs), ionization potentials (IPs), and quasiparticle energies. In this work, we present a theoretical…

Chemical Physics · Physics 2026-04-07 Zipeng An , Xiaolong Yang , Xiao Zheng , Weitao Yang

We introduce the semiclassical limit to electronic systems by taking the limit $\hbar\rightarrow 0$ in the solution of Schr\"odinger equations. We show that this limit is closely related to one type of strong correlation that is…

Computational Physics · Physics 2025-01-07 Yunzhi Li , Chen Li

In a recent paper [Phys.~Rev.~A {\bf 89}, 022503 (2014)], the average density approximation (ADA) was implemented to develop a parameter-free, nonlocal kinetic energy functional to be used in the orbital-free density-functional theory of an…

Quantum Gases · Physics 2015-08-25 J. Towers , B. P. van Zyl , W. Kirkby

We use density-matrix renormalization group, applied to a one-dimensional model of continuum Hamiltonians, to accurately solve chains of hydrogen atoms of various separations and numbers of atoms. We train and test a machine-learned…

Strongly Correlated Electrons · Physics 2016-12-28 Li Li , Thomas E. Baker , Steven R. White , Kieron Burke

We investigate the critical behavior of the one-dimensional Ising model with long-range interactions using the functional renormalization group in the local potential approximation (LPA), and compare our findings with Dyson's hierarchical…

Statistical Mechanics · Physics 2025-12-23 Valerio Pagni , Guido Giachetti , Andrea Trombettoni , Nicolò Defenu

A systematic way of improving exchange-correlation energy functionals of density functional theory has been to make them satisfy more and more exact relations. Starting from the initial GGA functionals, this has culminated into the recently…

Chemical Physics · Physics 2017-10-11 Rabeet Singh , Manoj K. Harbola

The fabrication, utilisation, and efficiency of quantum technologies rely on a good understanding of quantum thermodynamic properties. Many-body systems are often used as hardware for these quantum devices, but interactions between…

Strongly Correlated Electrons · Physics 2022-04-26 Krissia Zawadzki , Amy Skelt , Irene D'Amico

We train a neural network as the universal exchange-correlation functional of density-functional theory that simultaneously reproduces both the exact exchange-correlation energy and potential. This functional is extremely non-local, but…

Computational Physics · Physics 2019-10-10 Jonathan Schmidt , Carlos L. Benavides-Riveros , Miguel A. L. Marques

Semi-local approximations to the density functional for the exchange-correlation energy of a many-electron system necessarily fail for lobed one-electron densities, including not only the familiar stretched densities but also the less…

Density functional theory (DFT) offers a desirable balance between quantitative accuracy and computational efficiency in practical many-electron calculations. Its central component, the exchange-correlation energy functional, has been…

It is known that the adiabatic approximation in time-dependent density functional theory usually provides a good description of low-lying excitations of molecules. In the present work, the capability of the adiabatic nonempirical…

Materials Science · Physics 2009-11-13 Jianmin Tao , Sergei Tretiak , Jian-Xin Zhu

The structure of the QCD gluonic cascade in configuration space is investigated. The explicit form of the inclusive single particle density in configuration space transverse coordinates is derived in the double logarithmic approximation…

High Energy Physics - Phenomenology · Physics 2007-05-23 B. Ziaja

We propose a way to improve energy density functionals (EDFs) in the density functional theory based on the combination of the inverse Kohn--Sham method and the density functional perturbation theory. Difference between the known EDF and…

Chemical Physics · Physics 2019-11-22 Tomoya Naito , Daisuke Ohashi , Haozhao Liang

The journey of theoretical study on semiconductors is reviewed in a non-conventional way. We have started with the basic introduction of Hartree-Fock method and introduce the fundamentals of Density Functional Theory (DFT). From the oldest…

Materials Science · Physics 2021-05-04 Sujoy Datta , Debnarayan Jana

Here we describe the form of the Asymmetric Superfluid Local Density Approximation (ASLDA), a Density Functional Theory (DFT) used to model the two-component unitary Fermi gas. We give the rational behind the functional, and describe…

Superconductivity · Physics 2008-10-29 Aurel Bulgac , Michael McNeil Forbes
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