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In this paper we study the controllability problem for a symmetric-top molecule, both for its classical and quantum rotational dynamics. The molecule is controlled through three orthogonal electric fields interacting with its electric…

Mathematical Physics · Physics 2021-09-20 Ugo Boscain , Eugenio Pozzoli , Mario Sigalotti

We consider the Schr\"odinger partial differential equation of a rotating symmetric rigid molecule (symmetric rotor) driven by a z-linearly polarized electric field, as prototype of degenerate infinite-dimensional bilinear control system.…

Optimization and Control · Mathematics 2022-02-11 Thomas Chambrion , Eugenio Pozzoli

We present a sufficient condition for approximate controllability of the bilinear discrete-spectrum Schr\"odinger equation exploiting the use of several controls. The controllability result extends to simultaneous controllability,…

Optimization and Control · Mathematics 2013-02-19 Ugo Boscain , Marco Caponigro , Mario Sigalotti

The angular momentum of molecules, or, equivalently, their rotation in three-dimensional space, is ideally suited for quantum control. Molecular angular momentum is naturally quantized, time evolution is governed by a well-known Hamiltonian…

Quantum Physics · Physics 2019-10-23 Christiane P. Koch , Mikhail Lemeshko , Dominique Sugny

We show the approximate rotational controllability of a polar linear molecule by means of three nonresonant linear polarized laser fields. The result is based on a general approximate controllability result for the bilinear Schr\"odinger…

Optimization and Control · Mathematics 2013-02-14 Ugo Boscain , Marco Caponigro , Mario Sigalotti

It is noted that the Schrodinger equation with any self-adjoint Hamiltonian is unitary equivalent to a set of non-interacting classical harmonic oscillators and in this sense any quantum dynamics is completely integrable. Higher order…

Mathematical Physics · Physics 2019-11-06 Igor V. Volovich

We examine the impact of the combination of a static electric field and a non resonant linearly polarized laser field on an asymmetric top molecule. Within the rigid rotor approximation, we analyze the symmetries of the Hamiltonian for all…

Chemical Physics · Physics 2015-05-28 J. J. Omiste , R. González-Férez , P. Schmelcher

We study the most general form of a three dimensional classical integrable system with axial symmetry and invariant under the axis reflection. We assume that the three constants of motion are the Hamiltonian, $H$, with the standard form of…

Mathematical Physics · Physics 2009-11-13 M. Gadella , J. Negro , G. P. Pronko

We provide sufficient conditions for the approximate controllability of infinite-dimensional quantum control systems corresponding to form perturbations of the drift Hamiltonian modulated by a control function. We rely on previous results…

Optimization and Control · Mathematics 2025-04-02 Aitor Balmaseda , Davide Lonigro , Juan Manuel Pérez-Pardo

We study the stability of the Schr\"odinger equation generated by time-dependent Hamiltonians with constant form domain. That is, we bound the difference between solutions of the Schr\"odinger equation by the difference of their…

Mathematical Physics · Physics 2024-07-11 Aitor Balmaseda , Davide Lonigro , Juan Manuel Pérez-Pardo

This analysis is concerned with the controllability of quantum systems in the case where the standard dipolar approximation, involving the permanent dipole moment of the system, is corrected with a polarizability term, involving the field…

Analysis of PDEs · Mathematics 2014-06-17 Nabile Boussaid , Marco Caponigro , Thomas Chambrion

Identifying the real and imaginary parts of wave functions with coordinates and momenta, quantum evolution may be mapped onto a classical Hamiltonian system. In addition to the symplectic form, quantum mechanics also has a positive-definite…

Quantum Physics · Physics 2009-11-07 R. Vilela Mendes , V. I. Man'ko

In this article we discuss which controllability properties of classical Hamiltonian systems are preserved after quantization. We discuss some necessary and some sufficient conditions for small-time controllability of classical systems and…

Optimization and Control · Mathematics 2024-06-19 Ivan Beschastnyi , Ugo Boscain , Mario Sigalotti

We study the quantum dynamics of diatomic molecule driven by a circularly polarized resonant electric field. We look for a quantum effect due to classical chaos appearing due to the overlapping of nonlinear resonances associated to the…

Quantum Physics · Physics 2015-05-20 G. V. Lopez , J. G. T. Zanudo

The evolution problem for a quantum particle confined in a 1D box and interacting with one fixed point through a time dependent point interaction is considered. Under suitable assumptions of regularity for the time profile of the…

Analysis of PDEs · Mathematics 2015-05-19 Andrea Mantile

We investigate the spin dynamics of a dipole-coupled system by comparing a direct solution of the Schrodinger equation for quantum spins with simulations of classical spins. Although classical spins have long been used in microscopic spin…

Quantum Physics · Physics 2026-04-28 Victor Henner , Alexander Nepomnyashchy , Tatyana Belozerova

In this paper, the classical Schr\"odinger equation, which allows the study of classical dynamics in terms of wave functions, is analyzed theoretically and numerically. First, departing from classical (Newtonian) mechanics, and assuming an…

Quantum Physics · Physics 2016-11-23 Albert Benseny , David Tena , Xavier Oriols

We consider the generalized rotor Hamiltonians capable of describing quantum systems invariant with respect to symmetry point-groups that go beyond the usual D_2-symmetry of a tri-axial rotor. We discuss the canonical de-quantisation…

Nuclear Theory · Physics 2009-11-10 M. Miskiewicz , A. Gozdz , J. Dudek

A major challenge to the control of infinite dimensional quantum systems is the irreversibility which is often present in the system dynamics. Here we consider systems with discrete-spectrum Hamiltonians operating over a Schwartz space…

Quantum Physics · Physics 2014-03-13 Roger S. Bliss , Daniel Burgarth

In this paper, we present efficient quantum algorithms that are exponentially faster than classical algorithms for solving the quantum optimal control problem. This problem involves finding the control variable that maximizes a physical…

Quantum Physics · Physics 2023-10-02 Xiantao Li , Chunhao Wang
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