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Zinc phosphorus trisulfide (ZnPS$_3$), a promising material for photocatalysis and energy storage, is shown in this study to exhibit remarkable stability under extreme conditions. We explore its optical and structural properties under high…

Antiferromagnetic (AFM) FePS3 has gained significant interest recently for its potential applications in spin-related devices. A single layer is comprised of a honeycomb network, stabilized by long-range spin-exchange interactions, with a…

We have performed electrochemical treatment of the van der Waals antiferromagnetic materials FePS$_3$ and NiPS$_3$ with the ionic liquid EMIM-BF$_4$, achieving significant molecular intercalation. Mass analysis of the intercalated…

Strongly Correlated Electrons · Physics 2024-05-07 Cong Li , Ze Hu , Xiaofei Hou , Sheng Xu , Zhanlong Wu , Kefan Du , Shuo Li , Xiaoyu Xu , Ying Chen , Zeyu Wang , Tiancheng Mu , Tian-Long Xia , Yanfeng Guo , B. Normand , Weiqiang Yu , Yi Cui

Here, a magnetic model with an unprecedentedly large number of parameters was determined from first-principles calculations for transition-metal phosphorus trisulfides (TMPS$_3$'s), which reproduced the measured magnetic ground states of…

Materials Science · Physics 2021-12-14 Tae Yun Kim , Cheol-Hwan Park

Pressure-induced insulator-to-metal transition (IMT) has been studied in the van der Waals compound iron thiophosphate (FePS3) using first-principles calculations within the periodic linear combination of atomic orbitals method with hybrid…

Materials Science · Physics 2020-04-27 R. A. Evarestov , A. Kuzmin

Exfoliated magnetic 2D materials enable versatile tuning of magnetization, e.g., by gating or providing proximity-induced exchange interaction. However, their electronic band structure after exfoliation has not been probed, most likely due…

We have systematically investigated the structural property and electrical structures of the transition metal intercalated titanium disulfide compound Fe$_x$TiS$_2$ ($0\leq x\leq0.33$) from angle-resolved photoelectron spectroscopy with…

Materials Science · Physics 2010-08-25 X. Y. Cui , H. Negishi , A. N. Titov , S. G. Titova , M. Shi , L. Patthey

Differential resistance spectra (${\rm d}V/{\rm d}I-V$ characteristics) have been measured for point-contacts between the heavy-fermion superconductor (HFS) CePt$_{3}$Si and a normal metal. Some contacts show a peak at V=0 that is…

Strongly Correlated Electrons · Physics 2009-11-13 R. Onuki , A. Sumiyama , Y. Oda , T. Yasuda , R. Settai , Y. Onuki

Triphosphides, with a chemical formula of XP$_3$ (X is a group IIIA, IVA, or VA element), have recently attracted much attention due to their great potential in several applications. Here, using density functional theory calculations, we…

The layered antiferromagnet FePS$_3$ has been shown to undergo a structural transition under pressure linked to an insulator-metal transition, with two incompatible models previously proposed for the highest-pressure structure. We present a…

Resonant Inelastic X-ray Scattering (RIXS) was used to measure the local electronic structure in few-layer exfoliated flakes of the van der Waals antiferromagnet NiPS$_3$. The resulting spectra show a systematic softening and broadening of…

Strongly Correlated Electrons · Physics 2024-02-09 M. F. DiScala , D. Staros , A. de la Torre , A. Lopez , D. Wong , C. Schulz , M. Bartkowiak , B. Rubenstein , K. W. Plumb

The pressure-induced insulator to metal transition (IMT) of layered magnetic nickel phosphorous tri-sulfide NiPS3 was studied in-situ under quasi-uniaxial conditions by means of electrical resistance (R) and X-ray diffraction (XRD)…

Strongly Correlated Electrons · Physics 2021-11-23 Takahiro Matsuoka , Amanda Haglund , Rui Xue , Jesse S. Smith , Maik Lang , Antonio M. dos Santos , David Mandrus

The crystallographic, magnetic, and transport properties of the van der Waals bonded, layered compound CrTe3 have been investigated on single crystal and polycrystalline materials. The crystal structure contains layers made up of lozenge…

Strongly Correlated Electrons · Physics 2017-04-19 Michael A. McGuire , V. Ovidiu Garlea , Santosh KC , Valentino R. Cooper , Jiaqiang Yan , Huibo Cao , Brian C. Sales

The transition metal thiophosphates $M$PS$_3$ ($M$ = Mn, Fe, Ni) are a class of van der Waals stacked insulating antiferromagnets that can be exfoliated down to the ultrathin limit. MnPS$_3$ is particularly interesting because its…

Strongly Correlated Electrons · Physics 2020-01-22 H. Chu , C. J. Roh , J. O. Island , C. Li , S. Lee , J. Chen , J. G. Park , A. F. Young , J. S. Lee , D. Hsieh

Nickel phosphorus trisulfide (NiPS3), a van der Waals (vdW) 2D antiferromagnet, has captivated enormous attention for its intriguing physics in recent years. However, despite its fundamental importance in physics of magnetism and promising…

Materials Science · Physics 2024-06-17 Qishuo Tan , Connor A. Occhialini , Hongze Gao , Jiaruo Li , Hikari Kitadai , Riccardo Comin , Xi Ling

Single layers of transition-metal thiophosphates (2D-TMPS$_{3}$) van der Waals magnets are an ideal platform for studying antiferromagnetic interactions in two dimensions. However, the magnetic coupling mechanism between two or more…

Materials Science · Physics 2024-10-18 Andrea León , Beatriz Costa , Thomas Heine , Thomas Brumme

In this work we use first-principles density-functional theory (DFT) calculations combined with the maximally localized Wannier function tight binding Hamiltonian (MLWF-TB) and Bethe-Salpeter equation (BSE) formalism to investigate…

Photoemission spectroscopy is used to investigate the electronic structure of the newly discovered iron-based superconductors LaFeAsO_{1-x}F_x and LaFePO_{1-x}F_x. Line shapes of the Fe 2p core-level spectra suggest an itinerant character…

We investigated low-frequency current fluctuations, i.e. noise, in the quasi-two-dimensional (2D) van der Waals antiferromagnetic semiconductor FePS3 with the electronic bandgap of 1.5 eV. The electrical and noise characteristics of the…

The van der Waals ferromagnet Fe$_3$GeTe$_2$ has recently attracted extensive research attention due to its intertwined magnetic, electronic and topological properties. Here, using high-resolution angle-resolved photoemission spectroscopy,…