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We present a scalable implementation of the $GW$ approximation using Gaussian atomic orbitals to study the valence and core ionization spectroscopies of molecules. The implementation of the standard spectral decomposition approach to the…

Chemical Physics · Physics 2021-12-06 Daniel Mejia-Rodriguez , Alexander Kunitsa , Edoardo Aprà , Niranjan Govind

Within the framework of the full potential projector-augmented wave methodology, we present a promising low-scaling $GW$ implementation. It allows for quasiparticle calculations with a scaling that is cubic in the system size and linear in…

Materials Science · Physics 2016-10-12 Peitao Liu , Merzuk Kaltak , Jiří Klimeš , Georg Kresse

Developing an analytical theory for atomic coherence driven by ultrashort laster pulses has proved to be challenging due to the breakdown of the rotating wave approximation (RWA). In this paper, we present an approximate, closed-form…

Quantum Physics · Physics 2021-11-30 Nazar Pyvovar , Bing Zeng , Lingze Duan

The vertex function ($\Gamma$) within the Green's function formalism encapsulates information about all higher-order electron-electron interaction beyond those mediated by density fluctuations. Herein, we present an efficient approach that…

Chemical Physics · Physics 2023-03-28 Guorong Weng , Rushil Mallarapu , Vojtech Vlcek

One-electron self-energy in the $t$-$J$ model was computed using a recently developed large-$N$ method based on the path integral representation for Hubbard operators. One of the main features of the self-energy is its strong asymmetry with…

Strongly Correlated Electrons · Physics 2009-11-13 A. Foussats , A. Greco , M. Bejas

The parquet formalism and Hedin's $GW\gamma$ approach are unified into a single theory of vertex corrections, corresponding to an exact reformulation of the parquet equations in terms of boson exchange. The method has no drawbacks compared…

Strongly Correlated Electrons · Physics 2021-02-25 Friedrich Krien , Anna Kauch , Karsten Held

A stochastic cumulant GW method is presented, allowing us to map the evolution of photoemission spectra, quasiparticle energies, lifetimes and emergence of collective excitations from molecules to bulk-like systems with up to thousands of…

Mesoscale and Nanoscale Physics · Physics 2018-03-21 Vojtech Vlcek , Eran Rabani , Daniel Neuhauser

The $GW$ approximation is a widely used framework for studying correlated materials, but it struggles with certain limitations, such as its inability to explain pseudogap phenomena. To overcome these problems, we propose a systematic…

Strongly Correlated Electrons · Physics 2024-09-26 Hui Li , Yingze Su , Junnian Xiong , Haiqing Lin , Huaqing Huang , Dingping Li

We present a theoretical framework and implementation details for self-energy embedding theory (SEET) with the GW approximation for the treatment of weakly correlated degrees of freedom and configuration interactions solver for handing the…

Strongly Correlated Electrons · Physics 2017-10-11 Tran Nguyen Lan , Avijit Shee , Jia Li , Emanuel Gull , Dominika Zgid

Electron dynamics in a two-sites Hubbard model is studied using the nonequilibrium Green's function approach. The study is motivated by the empirical observation that a full solution of the integro-differential Kadanoff-Baym equation (KBE)…

Strongly Correlated Electrons · Physics 2024-01-23 Yaroslav Pavlyukh

We develop a formalism to calculate the quasi-particle energy within the GW many-body perturbation correction to the density functional theory (DFT). The occupied and virtual orbitals of the Kohn-Sham (KS) Hamiltonian are replaced by…

Mesoscale and Nanoscale Physics · Physics 2015-06-18 Daniel Neuhauser , Yi Gao , Christopher Arntsen , Cyrus Karshenas , Eran Rabani , Roi Baer

We present results for the electronic structure of plutonium by using a recently developed quasiparticle self-consistent $GW$ method (\qsgw). We consider a paramagnetic solution without spin-orbit interaction as a function of volume for the…

Strongly Correlated Electrons · Physics 2009-07-23 A. N. Chantis , R. C. Albers , A. Svane , N. E. Christensen

The fully self-consistent GW approximation is an established method for electronic structure calculations. Its most serious deficiency is known to be an incorrect prediction of the dielectric response. In this work we examine the GW…

Strongly Correlated Electrons · Physics 2017-05-24 Kris Van Houcke , Igor S. Tupitsyn , Andrey S. Mishchenko , Nikolay V. Prokof'ev

Generalized Hydrodynamics (GHD) has recently been devised as a method to solve the dynamics of integrable quantum many-body systems beyond the mean-field approximation. In its original form, a major limitation is the inability to predict…

We present and benchmark a self-energy approach for quasiparticle energy calculations that goes beyond Hedin's $GW$ approximation by adding the full second-order self-energy (FSOS-$W$) contribution. The FSOS-$W$ diagram involves two…

Materials Science · Physics 2021-05-18 Yanyong Wang , Patrick Rinke , Xinguo Ren

We investigate a semilinear wave equation with energy-critical nonlinearity and a nonlinear damping mechanism driven by the total energy of the system. The model combines the quintic defocusing term with a time-dependent dissipation of the…

Analysis of PDEs · Mathematics 2026-04-06 Marcelo Cavalcanti , Valéria Domingos Cavalcanti , Josiane Faria , Cintya Okawa

We present an accurate approach to compute X-ray photoelectron spectra based on the $GW$ Green's function method, that overcomes shortcomings of common density functional theory approaches. $GW$ has become a popular tool to compute valence…

Chemical Physics · Physics 2020-03-11 Dorothea Golze , Levi Keller , Patrick Rinke

Ground State Energy Estimation (GSEE) is a central problem in quantum chemistry and condensed matter physics, demanding efficient algorithms to solve complex electronic structure calculations. This work introduces a structured benchmarking…

The GW self-energy method has long been recognized as the gold standard for quasiparticle (QP) calculations of solids in spite of the fact that the neglect of vertex corrections and the use of a DFT starting point lacks rigorous…

Materials Science · Physics 2017-12-06 Per S. Schmidt , Christopher E. Patrick , Kristian S. Thygesen

In this article, we develop and analyse a new spectral method to solve the semi-classical Schr\"odinger equation based on the Gaussian wave-packet transform (GWPT) and Hagedorn's semi-classical wave-packets (HWP). The GWPT equivalently…

Numerical Analysis · Mathematics 2021-10-12 Borui Miao , Giovanni Russo , Zhennan Zhou
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