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The efficiency of an heat engine is traditionally defined as the ratio of its average output work over its average input heat. Its highest possible value was discovered by Carnot in 1824 and is a cornerstone concept in thermodynamics. It…

Statistical Mechanics · Physics 2015-06-19 Gatien Verley , Tim Willaert , Christian Van den Broeck , Massimiliano Esposito

Macroscopic cyclic heat engines have been a major motivation for the emergence of thermodynamics. In the last decade, cyclic heat engines that have large fluctuations and operate at finite time were studied within the more modern framework…

Statistical Mechanics · Physics 2022-10-03 Arya Datta , Patrick Pietzonka , Andre C Barato

The efficiency of any heat engine, defined as the ratio of average work output to heat input, is bounded by Carnot's celebrated result. However, this measure is insufficient to characterize the properties of miniaturized heat engines…

Fluctuations of thermodynamic observables, such as heat and work, contain relevant information on the underlying physical process. These fluctuations are however not taken into account in the traditional laws of thermodynamics. While the…

Quantum Physics · Physics 2022-05-25 Timo Kerremans , Peter Samuelsson , Patrick P. Potts

Fluctuations of thermodynamic quantities become non-negligible and play an important role when the system size is small. We develop finite-time thermodynamics of fluctuations in microscopic heat engines whose environmental temperature and…

Statistical Mechanics · Physics 2022-02-16 Gentaro Watanabe , Yuki Minami

According to Thermodynamics, the efficiency of a heat engine is upper bounded by Carnot efficiency. For macroscopic systems, the Carnot efficiency is, however, achieved only for quasi static processes. And, considerable attention has been…

Statistical Mechanics · Physics 2023-05-03 Takaaki Monnai

Almost all processes -- highly correlated, weakly correlated, or correlated not at all---exhibit statistical fluctuations. Often physical laws, such as the Second Law of Thermodynamics, address only typical realizations -- as highlighted by…

Statistical Mechanics · Physics 2016-09-09 James P. Crutchfield , Cina Aghamohammadi

At the very foundation of the second law of thermodynamics lies the fact that no heat engine operating between two reservoires of temperatures $T_C\leq T_H$ can overperform the ideal Carnot engine: $\langle W \rangle / \langle Q_H \rangle…

Statistical Mechanics · Physics 2014-06-18 Michele Campisi

Fluctuation theorems are fundamental extensions of the second law of thermodynamics for small nonequilibrium systems. While work and heat are equally important forms of energy exchange, fluctuation relations have not been experimentally…

Statistical Mechanics · Physics 2022-02-24 Markus Rademacher , Michael Konopik , Maxime Debiossac , David Grass , Eric Lutz , Nikolai Kiesel

Miniaturized heat engines constitutes a fascinating field of current research. They are being studied theoretically as well as experimentally, with experiments involving colloidal particles and harmonic traps and even bacterial baths acting…

Statistical Mechanics · Physics 2017-07-04 Debarshi Basu , Joydip Nandi , A. M. Jayannavar , Rahul Marathe

The relationships between reversible Carnot cycles, the absence of perpetual motion machines and the existence of a non-decreasing, globally unique entropy function forms the starting point of many textbook presentations of the foundations…

Statistical Mechanics · Physics 2015-05-14 O. J. E. Maroney

In a stochastic heat engine driven by a cyclic non-equilibrium protocol, fluctuations in work and heat give rise to a fluctuating efficiency. Using computer simulations and tools from large deviation theory, we have examined these…

Statistical Mechanics · Physics 2014-10-27 Todd R. Gingrich , Grant M. Rotskoff , Suriyanarayanan Vaikuntanathan , Phillip L. Geissler

The Carnot statement of the second law of thermodynamics poses an upper limit on the efficiency of all heat engines. Recently, it has been studied whether generic quantum features such as coherence and quantum entanglement could allow for…

Statistical Mechanics · Physics 2015-10-14 Bartłomiej Gardas , Sebastian Deffner

The thermodynamic properties of quantum heat engines are stochastic owing to the presence of thermal and quantum fluctuations. We here experimentally investigate the efficiency and nonequilibrium entropy production statistics of a spin-1/2…

Quantum Physics · Physics 2021-04-29 Tobias Denzler , Jonas F. G. Santos , Eric Lutz , Roberto Serra

The Carnot theorem, one expression of the second law of thermodynamics, places a fundamental upper bound on the efficiency of heat engines operating between two heat baths. The Carnot theorem can be stated in a more generalized form for…

Statistical Mechanics · Physics 2022-06-03 Yuki Izumida

For macroscopic systems, the second law of thermodynamics establishes an inequality between the amount of work performed on a system in contact with a thermal reservoir, and the change in its free energy. For microscopic systems, this…

Statistical Mechanics · Physics 2010-02-08 Eliran Boksenbojm , Bram Wynants , Christopher Jarzynski

For a small driven system coupled strongly to a heat bath, internal energy and exchanged heat are identified such that they obey the usual additive form of the first law. By identifying this exchanged heat with the entropy change of the…

Statistical Mechanics · Physics 2016-02-03 Udo Seifert

We study the stochastic energetic exchanges in quantum heat engines. Due to microreversibility, these obey a fluctuation relation, called the heat engine fluctuation relation, which implies the Carnot bound: no machine can have an…

Quantum Physics · Physics 2015-03-24 Michele Campisi , Jukka Pekola , Rosario Fazio

The Heat theorem reveals the second law of equilibrium Thermodynamics (i.e.existence of Entropy) as a manifestation of a general property of Hamiltonian Mechanics and of the Ergodic Hypothesis, valid for 1 as well as $10^{23}$ degrees of…

Statistical Mechanics · Physics 2008-02-01 Giovanni Gallavotti

Nanoscale machines are strongly influenced by thermal fluctuations, contrary to their macroscopic counterparts. As a consequence, even the efficiency of such microscopic machines becomes a fluctuating random variable. Using geometric…

Statistical Mechanics · Physics 2019-04-16 Sreekanth K Manikandan , Lennart Dabelow , Ralf Eichhorn , Supriya Krishnamurthy
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