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Chemical, mechanical, thermal and/or electronic properties of bulk or low-dimensional materials can be engineered by introducing structural defects to form novel functionalities. When using particles irradiation, these defects can be…

Materials Science · Physics 2022-02-07 L. Basta , A. Moscardini , S. Veronesi , F. Bianco

We present a systematic Raman study of unconventionally-stacked double-layer graphene, and find that the spectrum strongly depends on the relative rotation angle between layers. Rotation-dependent trends in the position, width and intensity…

Mesoscale and Nanoscale Physics · Physics 2012-06-15 Kwanpyo Kim , Sinisa Coh , Liang Z. Tan , William Regan , Jong Min Yuk , Eric Chatterjee , M. F. Crommie , Marvin L. Cohen , Steven G. Louie , A. Zettl

A theoretical model supported by experimental results explains the dependence of the Raman scattering signal on the evolution of structural parameters along the amorphization trajectory of polycrystalline graphene systems. Four parameters…

Raman spectroscopy plays a key role in studies of graphene and related carbon systems. Graphene is perhaps the most promising material of recent times for many novel applications, including electronics. In this paper, the traditional and…

Materials Science · Physics 2015-12-07 Eric J. Heller , Yuan Yang , Lucas Kocia , Wei Chen , Shiang Fang , Mario Borunda , Efthimios Kaxiras

We present detailed multi frequency resonant Raman measurements of potassium graphite intercalation compounds (GICs). From a well controlled and consecutive in-situ intercalation and high temperature de-intercalation approach the response…

Materials Science · Physics 2013-10-25 J. C. Chacon-Torres , L. Wirtz , T. Pichler

We have studied, both experimentally and theoretically, the change of the so-called 2D band of the Raman scattering spectrum of graphene (the two-phonon peak near 2700 cm-1) in an external magnetic field applied perpendicular to the…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 C. Faugeras , P. Kossacki , D. M. Basko , M. Amado , M. Sprinkle , C. Berger , W. A. de Heer , M. Potemski

We study the retardation regime of doped graphene plasmons, given by the nominal crossing of the unretarded plasmon and light-cone. In addition to modifications in the plasmon dispersion relation, retardation implies strong coupling between…

Mesoscale and Nanoscale Physics · Physics 2012-08-16 G. Gómez-Santos , T. Stauber

Multi-layer graphene with rhombohedral stacking is a promising carbon phase possibly displaying correlated states like magnetism or superconductivity due to the occurrence of a flat surface band at the Fermi level. Recently, flakes of…

Materials Science · Physics 2017-09-27 Abderrezak Torche , Francesco Mauri , Jean-Christophe Charlier , Matteo Calandra

Graphene has extraordinary mechanical and electronic properties, making it a promising material for membrane based nanoelectromechanical systems (NEMS). Here, chemical-vapor-deposited graphene is transferred onto target substrates to…

In contrary to the widely reported single and symmetric peak feature of G' (or 2D) band in Raman spectrum of graphene, we herein report the observation of splitting in G' band in free standing graphene. Our experimental findings provide a…

Materials Science · Physics 2015-06-04 Zhiqiang Luo , Chunxiao Cong , Jun Zhang , Qihua Xiong , Ting Yu

Raman spectroscopy is a fast, non-destructive means to characterize graphene samples. In particular, the Raman spectra show a significant dependence on doping. While the change in position and width of the G peak can be explained by the…

Materials Science · Physics 2015-05-13 D. M. Basko , S. Piscanec , A. C. Ferrari

Graphene grown by chemical vapor deposition and supported on SiO2 and sapphire substrates was studied following controlled introduction of defects induced by 35 keV carbon ion irradiation. Changes in Raman spectra following fluences ranging…

A plasmonic nanostructure-based substrate, serving as a surface-enhanced Raman scattering (SERS) substrate, enhances the Raman scattering of molecules. By employing an electron beam lithography followed by our recently developed…

We demonstrate electrochemical top gating of graphene by using a solid polymer electrolyte. This allows to reach much higher electron and hole doping than standard back gating. In-situ Raman measurements monitor the doping. The G peak…

The Raman peak position and linewidth provide insight into phonon anharmonicity and electron-phonon interactions (EPI) in materials. For monolayer graphene, prior first-principles calculations have yielded decreasing linewidth with…

Materials Science · Physics 2022-01-27 Zherui Han , Xiaolong Yang , Sean E. Sullivan , Tianli Feng , Li Shi , Wu Li , Xiulin Ruan

Density functional theory has been employed to study graphene on the (111), (100) and (110) surfaces of silicon (Si) substrates. There are several interesting findings. First, carbon atoms in graphene form covalent bonds with Si atoms, when…

Materials Science · Physics 2021-07-14 Y. W. Sun , D. Holec , D. Gehringer , L. Li , O. Fenwick , D. J. Dunstan , C. J. Humphreys

The symmetry group analysis is applied to classify the phonon modes of $N$-stacked graphene layers (NSGL's) with AB- and AA-stacking, particularly their infra-red and Raman properties. The dispersions of various phonon modes are calculated…

Materials Science · Physics 2008-06-30 Jin-Wu Jiang , Hui Tang , Bing-Shen Wang , Zhao-Bin Su

Raman signals from molecules adsorbed on a noble metal surface are enhanced by many orders of magnitude due to the plasmon resonances of the substrate. Additionally, the enhanced spectra are modified compared to the spectra of neat…

Mesoscale and Nanoscale Physics · Physics 2010-10-01 Semion K. Saikin , Yizhuo Chu , Dmitrij Rappoport , Kenneth B. Crozier , Alan Aspuru-Guzik

We assessed the efficiencies of surface plasmon excitation by an aloof-scattered electron beam on metals and graphene. Graphene is shown to exhibit high energy transfer efficiencies at very low electron kinetic energy requirements. We show…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 Kelvin J. A. Ooi , Wee Shing Koh , Hong Son Chu , Dawn T. H. Tan , L. K. Ang

Fano resonances and their strong doping dependence are observed in Raman scattering of single-layer graphene (SLG). As the Fermi level is varied by a back-gate bias, the Raman G band of SLG exhibits an asymmetric line shape near the charge…

Mesoscale and Nanoscale Physics · Physics 2013-05-27 Duhee Yoon , Dongchan Jeong , Hu-Jong Lee , Riichiro Saito , Young-Woo Son , Hyun Cheol Lee , Hyeonsik Cheong