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We present a systematic experimental and theoretical study of the two-phonon (2D) Raman scattering in graphene under uniaxial tension. The external perturbation unveils that the 2D mode excited with 785nm has a complex line-shape mainly due…

Graphene is a mechanically robust 2D material promising for flexible optoelectronic applications. However, its electromagnetic properties under strain are experimentally poorly understood. Here we present the far-infrared transmission…

Mesoscale and Nanoscale Physics · Physics 2017-05-22 Manisha Chhikara , Iaroslav Gaponenko , Patrycja Paruch , Alexey. B. Kuzmenko

Raman intensity of Rhodamine B (RhB) is enhanced by inserting a thin high \k{appa} dielectric layer which reduces the surface plasmon damping at the gold-graphene interface. The results indicate that the Raman intensity increases sharply by…

Optics · Physics 2015-06-22 Xuechao Yu , Jin Tao , Youde Shen , Guozhen Liang , Tao Liu , Yongzhe Zhang , Qi Jie Wang

The effect of grain boundaries and wrinkles on the electrical properties of polycrystalline graphene is pronounced. Here we investigate the stitching between grains of polycrystalline graphene, specifically, overlapping of layers at the…

Materials Science · Physics 2014-06-09 Rahul Rao , Neal Pierce , Avetik R. Harutyunyan

In this work we study the behavior of the optical phonon modes in bilayer graphene devices by applying top gate voltage, using Raman scattering. We observe the splitting of the Raman G band as we tune the Fermi level of the sample, which is…

Mesoscale and Nanoscale Physics · Physics 2012-06-07 D. L. Mafra , P. Gava , L. M. Malard , R. S. Borges , G. G. Silva , J. A. Leon , F. Plentz , F. Mauri , M. A. Pimenta

We review the different results obtained in the last decade in the field of Raman scattering of graphene based systems, with an applied magnetic field. Electronic properties of graphene based systems with an applied magnetic field will…

Mesoscale and Nanoscale Physics · Physics 2018-02-14 C. Faugeras , M. Orlita , M. Potemski

Surface enhanced Raman scattering (SERS) exploits surface plasmons induced by the incident field in metallic nanostructures to significantly increase the Raman intensity. Graphene provides the ideal prototype two dimensional (2d) test…

Mesoscale and Nanoscale Physics · Physics 2013-04-03 F. Schedin , E. Lidorikis , A. Lombardo , V. G. Kravets , A. K. Geim , A. N. Grigorenko , K. S. Novoselov , A. C. Ferrari

Graphene covered metal nanoparticles constitute a novel type of hybrid materials, which provide a unique platform to study plasmonic effects, surface-enhanced Raman scattering (SERS), and metal-graphene interactions at the nanoscale. Such a…

We report a Raman spectroscopy study of graphene field-effect transistors (GFET) with a controlled amount of defects introduced in graphene by exposure to electron-beam irradiation. Raman spectra are taken at T = 8 K over a range of back…

Materials Science · Physics 2015-06-22 Isaac Childres , Luis A. Jauregui , Yong P. Chen

Micro-ring resonators (MRRs) "trap" incoming light, and therefore, have been shown to achieve extremely high local intensities of light. Thus, they can be used to facilitate highly non-linear optical signals. By embedding materials that…

Mesoscale and Nanoscale Physics · Physics 2024-09-04 A. Sharma , Y. Li , M. K. Prasad , W. L. Ho , S. T. Chu , I. V. Borzenets

The experimental Raman spectra of graphene exhibit a few intense two-phonon bands, which are enhanced through double-resonant scattering processes. Though there are many theoretical papers on this topic, none of them predicts the spectra…

Mesoscale and Nanoscale Physics · Physics 2014-12-17 Valentin N. Popov , Philippe Lambin

We study theoretically the Raman spectrum of the rotated double-layer graphene, consisting of two graphene layers rotated with respect to each other by an arbitrary angle \theta. We find a relatively simple dependence of the Raman G peak…

Mesoscale and Nanoscale Physics · Physics 2013-11-05 Sinisa Coh , Liang Z. Tan , Steven G. Louie , Marvin L. Cohen

We present a comprehensive study of graphene grown by chemical vapor deposition on copper single crystals with exposed (100), (110) and (111) faces. Direct examination of the as-grown graphene by Raman spectroscopy using a range of visible…

Mesoscale and Nanoscale Physics · Physics 2014-02-03 Otakar Frank , Jana Vejpravova , Vaclav Holy , Ladislav Kavan , Martin Kalbac

We investigate the evolution of the Raman spectrum of defected graphene as a function of doping. Polymer electrolyte gating allows us to move the Fermi level up to 0.7eV, as monitored by \textit{in-situ} Hall-effect measurements. For a…

Materials Science · Physics 2014-10-14 M. Bruna , A. K. Ott , M. Ijas , D. Yoon , U. Sassi , A. C. Ferrari

We present a detailed calculation of intensities of two-phonon and four-phonon Raman peaks in graphene. Writing the low-energy hamiltonian of the interaction of electrons with the crystal vibrations and the electromagnetic field from pure…

Materials Science · Physics 2009-11-13 D. M. Basko

Graphene is an ideal platform to study the coherence of quantum interference pathways by tuning doping or laser excitation energy. The latter produces a Raman excitation profile that provides direct insight into the lifetimes of…

Mesoscale and Nanoscale Physics · Physics 2023-01-24 Xue Chen , Sven Reichardt , Miao-Ling Lin , Yu-Chen Leng , Yan Lu , Heng Wu , Rui Mei , Ludger Wirtz , Xin Zhang , Andrea C. Ferrari , Ping-Heng Tan

We investigated Raman spectra of single-layer and multi-layer graphene under ultraviolet laser excitation at the wavelength of 325 nm. It was found that while the G peak of graphene remains pronounced in UV Raman spectra, the 2D band…

Materials Science · Physics 2015-05-13 Irene Calizo , Igor Bejenari , Muhammad Rahman , Guanxiong Liu , Alexander A. Balandin

We report a comprehensive micro-Raman scattering study of electrochemically-gated graphene field-effect transistors. The geometrical capacitance of the electrochemical top-gates is accurately determined from dual-gated Raman measurements,…

Mesoscale and Nanoscale Physics · Physics 2016-08-08 Guillaume Froehlicher , Stéphane Berciaud

We report the observation of an intense anomalous peak at 1608 cm$^{-1}$ in the Raman spectrum of graphene associated to the presence of chromium nanoparticles in contact with graphene. Bombardment with an electron beam demonstrates that…

Measurements and calculations have shown significant disagreement regarding the sign and variations of the thermal expansion coefficient (TEC) of graphene $\alpha(T)$. Here we report dedicated Raman scattering experiments conducted for…