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Strong-field photoelectron momentum imaging of the prototypical biomolecule indole was disentangled in a combined experimental and computational approach. Experimentally, strong control over the molecules enabled the acquisition of…

Atomic Physics · Physics 2021-02-03 Joss Wiese , Jolijn Onvlee , Sebastian Trippel , Jochen Küpper

An ab initio simulation of strong-field photodissociation of diatomic molecules was developed, inspired by recent dissociation experiments of F2-. The transition between electronic states was modeled, including the laser pulse and…

Atomic Physics · Physics 2020-06-26 Bar Ezra , Shimshon Kallush , Ronnie Kosloff

We investigate dissociative single and double ionization of HeH+ induced by intense femtosecond laser pulses. By employing a semi-classical model with nuclear trajectories moving on field-dressed surfaces and ionization events treated as…

Atomic Physics · Physics 2018-10-24 Lun Yue , Philipp Wustelt , A. Max Sayler , Gerhard G. Paulus , Stefanie Gräfe

We describe the results of experiments and simulations performed with the aim of extending photoelectron spectroscopy with intense laser pulses to the case of molecular compounds. Dimer frame photoelectron angular distributions generated by…

We present a combined experimental and theoretical study on strong-field ionization of a three-dimensionally oriented asymmetric top molecule, benzonitrile (C$_7$H$_5$N), by circularly polarized, nonresonant femtosecond laser pulses. Prior…

We report on the unambiguous observation of the sub-cycle ionization bursts in sequential strong-field double ionization of H$_2$ and their disentanglement in molecular frame photoelectron angular distributions. This observation was made…

We present combined experimental and theoretical results on strong-field ionization of oriented carbonyl-sulphide molecules by circularly-polarized laser pulses. The obtained molecular frame photoelectron angular distributions show…

We demonstrate that the angular distribution of photoelectrons from a strongly polarizable target exposed to a laser field can deviate noticeably from the prediction of conventional theory. Even within the dipole-photon approximation the…

Atomic and Molecular Clusters · Physics 2009-11-13 A. V. Korol , A. V. Solov'yov

We carry out a combined theoretical and experimental investigation on the population distributions in the ground and excited states of tunnel ionized N2 molecules at various driver wavelengths in the near- and mid-infrared range. Our…

Photoionization of an atom $A$ by a strong laser field in the presence of a spatially well-separated neighboring atom $B$ is considered. The laser field frequency is assumed to lie below the ionization potential of atom $A$ and be resonant…

Atomic Physics · Physics 2018-10-03 J. Fedyk , A. B. Voitkiv , C. Müller

The combination of photoelectron spectroscopy and ultrafast light sources is on track to set new standards for detailed interrogation of dynamics and reactivity of molecules. A crucial prerequisite for further progress is the ability to not…

Strong-field ionization of polar molecules contains rich dynamical processes such as tunneling, excitation, and Stark shift. These processes occur on a sub-cycle time scale and are difficult to distinguish in ultrafast measurements. Here,…

Atomic Physics · Physics 2021-12-15 Jia-Yin Che , Chao Chen , Shang Wang , Guo-Guo Xin , Yan-Jun Chen

A new mode of effective interaction of molecular rotational degrees of freedom with an intense, nonresonant, ultrashort laser pulse is explored. Transient nonadiabatic charge redistribution (TNCR) in larger molecules or molecular ions…

Optics · Physics 2020-01-01 D. A. Romanov , R. J. Levis

We demonstrate that strong-field ionization of atoms driven by circularly polarized light becomes an adiabatic process when described in the frame rotating with the laser field. As a direct consequence, a conservation law emerges: in the…

We explore a new fashion, named energy-resolved population image (EPI), to represent on an equal footing the temporary electronic transition and nuclear motion during laser-molecular interaction. By using the EPI we have intuitively…

Atomic and Molecular Clusters · Physics 2015-06-19 Kunlong Liu , Pengfei Lan , Cheng Huang , Qingbin Zhang , Peixiang Lu

We investigate the role of nuclear motion and strong-field-induced electronic couplings during the double ionization of deuterated water using momentum-resolved coincidence spectroscopy. By examining the three-body dicationic dissociation…

When a strong laser pulse induces the ionization of an atom, momentum conservation dictates that the absorbed photons transfer their momentum $p_{\gamma}=E_{\gamma}/c$ to the electron and its parent ion. Even after 30 years of studying…

The angular distribution of the emitted electrons, following the two-photon ionization of the hydrogen-like ions, is studied within the framework of second order perturbation theory and the Dirac equation. Using a density matrix approach,…

Atomic Physics · Physics 2007-05-23 Peter Koval , Stephan Fritzsche , Andrey Surzhykov

Collisional--radiative (CR) models based on \textit{ab initio} atomic structure calculation have been utilized over 20 years to analyze many-electron atomic and ionic spectra. Although the population distribution of the excited states in…

Atomic Physics · Physics 2020-11-25 Akira Nishio , Julian C. Berengut , Masahiro Hasuo , Keisuke Fujii

A new pathway of strong laser field induced ionization of an atom is identified which is based on recollisions under the tunneling barrier. With an amended strong field approximation, the interference of the direct and the under-the-barrier…

Atomic Physics · Physics 2018-01-10 Michael Klaiber , Karen Z. Hatsagortsyan , Christoph H. Keitel
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