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The strong coherent coupling of quantum emitters to vacuum fluctuations of the light field offers opportunities for manipulating the optical and transport properties of nanomaterials, with potential applications ranging from ultrasensitive…

An ensemble of identical, intrinsically non-interacting molecules exposed to quantum light is discussed. Their interaction with the quantum light induces interactions between the molecules. The resulting hybrid light-matter states exhibit…

Chemical Physics · Physics 2024-06-19 Lorenz S. Cederbaum

The demonstration of strong and ultrastrong coupling regimes of cavity QED with polyatomic molecules has opened new routes to control chemical dynamics at the nanoscale. We show that strong resonant coupling of a cavity field with an…

Quantum Physics · Physics 2016-06-09 Felipe Herrera , Frank C. Spano

An opalic plasmonic sample, constituted by a hexagonal arrangement of metallized silica spheres, presents remarkable optical properties due to the mixing of periodic arrangement and singularities at the sphere touching points. It is…

Molecular polaritons have become an emerging platform for remotely controlling molecular properties through strong light-matter interactions. Herein, a semiclassical approach is developed for describing molecular polaritons by…

Chemical Physics · Physics 2022-04-19 Tao E. Li , Zhen Tao , Sharon Hammes-Schiffer

Molecular polaritons have gained considerable attention due to their potential to control nanoscale molecular processes by harnessing electromagnetic coherence. Although recent experiments with liquid-phase vibrational polaritons have shown…

A model designed to mimic the implications of the collective optical response of molecular ensembles in optical cavities on molecular vibronic dynamics is investigated. Strong molecule-radiation field coupling is often reached when a large…

Chemical Physics · Physics 2022-10-05 Bingyu Cui , Abraham Nitzan

Intermixed light-matter quasiparticles - polaritons - possess unique optical properties owned to their compositional nature. These intriguing hybrid states have been extensively studied over the past decades in a wide range of realizations…

We theoretically designed and experimentally demonstrated a mechanism to protect a spatially segregated mixed light-matter state, known as intercavity exciton-polariton in strongly coupled optical cavities. This excitation, shared across…

The strong coupling of molecules with surface plasmons results in hybrid states which are part molecule, part surface-bound light. Since molecular resonances may acquire the spatial coherence of plasmons, which have mm-scale propagation…

Optics · Physics 2022-05-26 Marie S Rider , Rakesh Arul , Jeremy J Baumberg , William L Barnes

Molecular vibrations couple to visible light only weakly, have small mutual interactions, and hence are often ignored for non-linear optics. Here we show the extreme confinement provided by plasmonic nano- and pico-cavities can sufficiently…

Plasmonic chirality exhibits great potential for novel nanooptical devices due to the generation of a strong chiroptical response. Previous reports on plasmonic chirality explanations are mainly based on phase retardation and coupling. We…

Mesoscale and Nanoscale Physics · Physics 2016-05-05 Li Hu , Yingzhou Huang , Yurui Fang

Polaritons are an emerging platform for exploration of synthetic materials [1] and quantum information processing [2] that draw properties from two disparate particles: a photon and an atom. Cavity polaritons are particularly promising, as…

Recent experimental progress in the field of cavity quantum electrodynamics allows to study the regime of strong interaction between quantized light and complex matter systems. Due to the coherent coupling between photons and matter-degrees…

Quantum Physics · Physics 2021-02-24 Florian Buchholz

Molecular complexes are held together via a variety of bonds, but they all share the common feature that their individual entities are in contact. In this work, we introduce and demonstrate the concept of a \textit{molecular optical bond},…

Mesoscale and Nanoscale Physics · Physics 2025-01-03 Jahangir Nobakht , André Pscherer , Jan Renger , Stephan Götzinger , Vahid Sandoghdar

When mid-infrared light interacts with nanoscale polar dielectric structures optical phonon propagation cannot be ignored, leading to a rich nonlocal phenomenology which we have only recently started to uncover. In properly crafted…

Mesoscale and Nanoscale Physics · Physics 2021-08-10 Christopher R. Gubbin , Simone De Liberato

Hybrid molecular-plasmonic nanostructures have demonstrated their potential for surface enhanced spectroscopies, sensing or quantum control at the nanoscale. In this work, we investigate the strong coupling regime and explicitly describe…

Quantum Physics · Physics 2017-07-05 H. Varguet , B. Rousseaux , D. Dzsotjan , H. Jauslin , S. Guerin , G. Colas des Francs

We propose a method that enables strong, coherent coupling between individual optical emitters and electromagnetic excitations in conducting nano-structures. The excitations are optical plasmons that can be localized to sub-wavelength…

Quantum Physics · Physics 2009-11-13 D. E. Chang , A. S. Sorensen , P. R. Hemmer , M. D. Lukin

Polaritonic chemistry has become a rapidly developing field within the last few years. A multitude of experimental observations suggest that chemical properties can be fundamentally altered and novel physical states appear when matter is…

Mesoscale and Nanoscale Physics · Physics 2020-11-09 Dominik Sidler , Christian Schäfer , Michael Ruggenthaler , Angel Rubio

This review provides a brief introduction to the physics of coupled exciton-plasmon systems, the theoretical description and experimental manifestation of such phenomena, followed by an account of the state-of-the-art methodology for the…

Mesoscale and Nanoscale Physics · Physics 2017-10-25 Maxim Sukharev , Abraham Nitzan