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We review both the fundamental aspects and the applications of functional magneto-optic and opto-magnetic metamaterials displaying collective and coupling effects on the nanoscale, where the concepts of optics and magnetism merge to produce…

Materials Science · Physics 2020-03-12 Nicolò Maccaferri

A plasmonic coupled-cavity system, which consists of a quarter-wave coupler cavity, a resonant Fabry-Perot detector nanocavity, and an off-resonant reflector cavity, is used to enhance the localization of surface plasmons in a plasmonic…

Mesoscale and Nanoscale Physics · Physics 2013-12-31 Kelvin J. A. Ooi , Ping Bai , Ming Xia Gu , Lay Kee Ang

A nanocomposite film containing highly polarizable inclusions in a fluid background is explored when an external electric field is applied perpendicular to the planar film. For small electric fields, the induced dipole moments of the…

Soft Condensed Matter · Physics 2025-06-27 Elshad Allahyarov , Hartmut Löwen

With the continuous emergence of molecular and cluster devices or systems, the relationship between the plasmonic properties of multiple clusters and molecular interactions and the properties of the original single cluster or molecule…

Mesoscale and Nanoscale Physics · Physics 2022-01-05 Nan Gao , Guodong Zhu , Yingzhou Huang , Yurui Fang

We study the interaction of focused radially-polarized light with metal nanospheres. By expanding the electromagnetic field in terms of multipoles, we gain insight on the excitation of localized surface plasmon-polariton resonances in the…

Optics · Physics 2009-11-13 Nassiredin M. Mojarad , Mario Agio

Polariton chemistry has been hailed as a potential new route to direct molecular processes with electromagnetic fields. To make further strides, it is essential for the community to clarify which unusual polaritonic phenomena are true…

Chemical Physics · Physics 2025-11-19 Alexander M. McKillop , Marissa L. Weichman

This review outlines several linear optical effects featured by molecular polaritons arising in the collective strong light-matter coupling regime. Under weak laser irradiation and when the single-molecule light-matter coupling can be…

We construct a model describing the response of a hybrid system where the electromagnetic field - in particular, surface plasmon polaritons - couples strongly with electronic excitations of atoms or molecules. Our approach is based on the…

Quantum Physics · Physics 2020-01-01 K. S. U. Kansanen , A. Asikainen , J. J. Toppari , G. Groenhof , T. T. Heikkilä

We investigate plasmon-emitter interactions in a nanoparticle-on-a-mirror cavity. We consider two different sorts of emitters, those that sustain dipolar transitions, and those hosting only quadrupolar, dipole-inactive, excitons. By means…

Mesoscale and Nanoscale Physics · Physics 2020-01-15 A. Cuartero-González , A. I. Fernández-Domínguez

We demonstrate that collective vibrational strong coupling of molecules in thermal equilibrium can give rise to significant local electronic polarizations in the thermodynamic limit. We do so by first showing that the full non-relativistic…

Despite recent numerical evidence, one of the fundamental theoretical mysteries of polaritonic chemistry is how and if collective strong coupling can induce local changes of the electronic structure to modify chemical properties. Here we…

Interaction between plasmonic nanostructures and molecules is modeled based on the concept of quantized optical cavity for surface enhanced Raman scattering process. We have found that the background emission from plasmonic nanostructures…

Optics · Physics 2017-03-22 Yuqing Cheng , Jingyi Zhao , Te Wen , Guantao Li , Jianning Xu , Qihuang Gong , Guowei Lu

A light-matter hybrid quasiparticle, called a polariton, is formed when molecules are strongly coupled to an optical cavity. Recent experiments have shown that polariton chemistry can manipulate chemical reactions. Polariton chemistry is a…

Chemical Physics · Physics 2024-01-11 Xinyang Li , Nicholas Lubbers , Sergei Tretiak , Kipton Barros , Yu Zhang

In cavity quantum electrodynamics, optical emitters that are strongly coupled to cavities give rise to polaritons with characteristics of both the emitters and the cavity excitations. We show that carbon nanotubes can be crystallized into…

The excitation of localized or delocalized surface plasmon polaritons in nanostructured or extended graphene has attracted a steadily increasing attention due to their promising applications in sensors, switches, and filters. These single…

Optics · Physics 2022-11-23 Renwen Yu , Rasoul Alaee , Falk Lederer , Carsten Rockstuhl

We present a model for molecular materials made up of polar and polarizable molecular units. A simple two state model is adopted for each molecular site and only classical intermolecular interactions are accounted for, neglecting any…

Materials Science · Physics 2009-11-10 Francesca Terenziani , Anna Painelli

We theoretically investigate strong coupling between a single molecule and a single metallic nanoparticle. A theory suited for the quantum-mechanical description of surface plasmon polaritons (SPPs) is developed. The coupling between these…

Mesoscale and Nanoscale Physics · Physics 2013-09-10 Andreas Truegler , Ulrich Hohenester

Recent experiments have demonstrated that polariton formation provides a novel strategy for modifying local molecular processes when a large ensemble of molecules is confined within an optical cavity. Herein, a numerical strategy based on…

Chemical Physics · Physics 2025-05-16 Andres Felipe Bocanegra Vargas , Tao E. Li

Molecular aggregates on plasmonic nanoparticles have emerged as attractive systems for the studies of cavity quantum electrodynamics. They are highly tunable, scalable, easy to synthesize and offer sub-wavelength confinement, all while…

We demonstrate strong coupling between molecular excited states and surface plasmon modes of a slit array in a thin metal film. The coupling manifests itself as an anti-crossing behavior of the two newly formed polaritons. As the coupling…

Mesoscale and Nanoscale Physics · Physics 2012-08-17 Adi Salomon , Robert J. Gordon , Yehiam Prior , Tamar Seideman , Maxim Sukharev