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Strong light-matter interactions in both the single-emitter and collective strong coupling regimes attract significant attention due to emerging quantum and nonlinear optics applications, as well as opportunities for modifying…

Mesoscale and Nanoscale Physics · Physics 2019-09-11 Tuomas P. Rossi , Timur Shegai , Paul Erhart , Tomasz J. Antosiewicz

Polaritonic chemistry exploits strong light-matter coupling between molecules and confined electromagnetic field modes to enable new chemical reactivities. In systems displaying this functionality, the choice of the cavity determines both…

Optics · Physics 2022-08-25 Jacopo Fregoni , Francisco J. García-Vidal , Johannes Feist

Strong coupling between molecules and quantized fields has emerged as an effective methodology to engineer molecular properties. New hybrid states are formed when molecules interact with quantized fields. Since the properties of these…

Chemical Physics · Physics 2023-06-28 Marco Romanelli , Rosario R. Riso , Tor S. Haugland , Enrico Ronca , Stefano Corni , Henrik Koch

We present an ab initio correlated approach to study molecules that interact strongly with quantum fields in an optical cavity. Quantum electrodynamics coupled cluster theory provides a non-perturbative description of cavity-induced effects…

Chemical Physics · Physics 2020-12-07 Tor S. Haugland , Enrico Ronca , Eirik F. Kjønstad , Angel Rubio , Henrik Koch

The effect of confinement on surface plasmon polariton in a planar nanocavity was studied. The generalized modes were obtained and studied in detail. It was demonstrated that these modes result from the strong coupling of plasmon-like and…

Materials Science · Physics 2011-11-28 Aurore Castanié , Didier Felbacq

We theoretically investigate plasmon polaritons in cubic lattices of spherical metallic nanoparticles. The nanoparticles, each supporting triply-degenerate localized surface plasmons, couple through the Coulomb dipole-dipole interaction,…

Mesoscale and Nanoscale Physics · Physics 2018-03-12 Simon Lamowski , Charlie-Ray Mann , Felicitas Hellbach , Eros Mariani , Guillaume Weick , Fabian Pauly

Polaritons are quasiparticles arising from the strong coupling of electromagnetic waves in cavities and dipolar oscillations in a material medium. In this framework, localized surface plasmon in metallic nanoparticles defining optical…

In the past decade, advances in nanotechnology have led to the development of plasmonic nanocavities which facilitate light-matter strong coupling in ambient conditions. The most robust example is the nanoparticle-on-mirror (NPoM) structure…

Molecular polaritons are the optical excitations which emerge when molecular transitions interact strongly with confined electromagnetic fields. Increasing interest in the hybrid molecular-photonic materials that host these excitations…

Mesoscale and Nanoscale Physics · Physics 2018-02-26 Raphael F. Ribeiro , Luis A. Martínez-Martínez , Matthew Du , Jorge Campos-Gonzalez-Angulo , Joel Yuen-Zhou

Molecular polaritons arise when molecules interact so strongly with light that they become entangled with each other. This light-matter hybridization alters the chemical and physical properties of the molecular system and allows chemical…

Chemical Physics · Physics 2023-07-28 Tor S. Haugland , John P. Philbin , Tushar K. Ghosh , Ming Chen , Henrik Koch , Prineha Narang

Crystals of plasmonic metal nanoparticles have intriguing optical properties. They reach the regimes of ultrastrong and deep strong light-matter coupling, where the photonic states need to be included in the simulation of material…

The experimental observation of quantum phenomena in strongly correlated many particle systems is difficult because of the short length- and timescales involved. Obtaining at the same time detailed control of individual constituents appears…

Quantum Physics · Physics 2007-05-23 Michael J. Hartmann , Fernando G. S. L. Brandao , Martin B. Plenio

There is an increasing scientific and technological interest on the design and implementation of nanoscale sources of quantum light. Here, we investigate the quantum statistics of the light scattered from a plasmonic nanocavity coupled to a…

Mesoscale and Nanoscale Physics · Physics 2019-03-14 R. Sáez-Blázquez , J. Feist , A. I. Fernández-Domínguez , F. J. García-Vidal

Localized plasmonic modes of metallic nanoparticles may hybridize like those of atoms forming a molecule. However, the rapid decay of the plasmonic fields outside the metal severely limits the range of these interactions to tens of…

Optics · Physics 2013-03-05 Adi Salomon , Yehiam Prior , Radoslaw Kolkowski , Joseph Zyss

The proposed paradigm of plasmonic atoms and plasmonic molecules allows one to describe and predict the strongly localized plasmonic oscillations in the clusters of nanoparticles and some other nanostructures in uniform way. Strongly…

Optics · Physics 2009-11-13 V. V. Klimov , D. V. Guzatov

We develop coupled-cluster theory for systems of electrons strongly coupled to photons, providing a promising theoretical tool in polaritonic chemistry with a perspective of application to all types of fermion-boson coupled systems. We show…

Strong light-matter coupling between molecules and plasmonic nanoparticles give rise to new hybrid eigenstates of the coupled system, commonly referred to as polaritons, or more precisely, plexcitons. Over the last decade it has been amply…

Chemical Physics · Physics 2024-02-06 Marco Romanelli , Stefano Corni

We consider a simple cubic array of metallic nanoparticles supporting extended collective plasmons that arise from the near-field dipolar interaction between localized surface plasmons in each nanoparticle. We develop a fully analytical…

Mesoscale and Nanoscale Physics · Physics 2015-01-12 Guillaume Weick , Eros Mariani

We simulate the near-field effects of strong coupling between molecular excitons and localized surface plasmons, supported by aluminum nanodisks. The simulations are done using a simple model of a two-level system, implemented in a…

Mesoscale and Nanoscale Physics · Physics 2020-01-29 Nadav Fain , Tal Ellenbogen , Tal Schwartz

We introduce crystal polaritons, hybrid excitations formed when the collective excitations of a periodic quantum-emitter array strongly couple to the resonant Bloch modes of a metasurface. This realizes a cavity-QED platform in which…

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