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Related papers: Charged Vacancy Defects in Black Phosphorus Monola…

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We have investigated the electronic structure of charged bilayer and trilayer phoshporene using first-principles, density-functional-theory calculations. We find that the effective dielectric constant for an external electric field applied…

Mesoscale and Nanoscale Physics · Physics 2017-08-09 Bukyoung Jhun , Cheol-Hwan Park

Hybrid functional calculations reveal the Zn-O divacancy in ZnO, consisting of adjacent Zn and O vacancies, as an electrically active defect exhibiting charge states ranging from $2+$ to $2-$ within the band gap. Notably, the divacancy…

Materials Science · Physics 2019-05-16 Y. K. Frodason , K. M. Johansen , A. Alkauskas , L. Vines

By means of a multi-scale first-principles approach, a description of the local electronic structure of two-dimensional and narrow phosphorene sheets with various types of modifications is presented. First, a rational argument based on the…

Materials Science · Physics 2016-02-03 Alejandro Lopez-Bezanilla

Monolayer phosphorene provides a unique two-dimensional (2D) platform to investigate the fundamental dynamics of excitons and trions (charged excitons) in reduced dimensions. However, owing to its high instability, unambiguous…

Materials Science · Physics 2015-04-30 Jiong Yang , Renjing Xu , Jiajie Pei , Ye Win Myint , Fan Wang , Zhu Wang , Shuang Zhang , Zongfu Yu , Yuerui Lu

Black phosphorus is a monoatomic semiconducting layered material that degrades exothermically in the presence of light and ambient contaminants. Its degradation dynamics remain largely unknown. Even before degradation, local-probe studies…

Recently, the successful synthesis of the pentagonal form of PdTe$_{2}$ monolayer (\emph{p}-PdTe$_{2}$) was reported [Liu~\emph{et al.}, Nature Materials \textbf{23}, 1339 (2024)]. In this work, we present an extensive first-principles…

Materials Science · Physics 2025-01-07 Poonam Sharma , Vaishali Roondhe , Alok Shukla

Phosphorene, a new elemental two dimensional (2D) material recently isolated by mechanical exfoliation, holds the feature of a direct band gap of around 2.0 eV, overcoming graphene's weaknesses (zero band gap) to realize the potential…

Materials Science · Physics 2016-12-07 Liujiang Zhou , Jin Zhang , Zhiwen Zhuo , Liangzhi Kou , Wei Ma , Bin Shao , Aijun Du , Sheng Meng , Thomas Frauenheim

The presence of finite bandgap and high mobility in semiconductor few-layer black phosphorus offers an attractive prospect for using this material in future two-dimensional electronic devices. Here we demonstrate for the first time fully…

Experimental studies on two-dimensional (2D) materials are still in the early stages, and most of the theoretical studies performed to screen these materials are limited to the room-temperature carrier-mobility in the free standing 2D…

Mesoscale and Nanoscale Physics · Physics 2020-07-30 Gautam Gaddemane , Maarten L. Van de Put , William G. Vandenberghe , Edward Chen , Massimo V. Fischetti

The tuning black phosphorene properties such as structural, electronic, transport are explored via substitutional C-doped. We employed density functional theory (DFT) calculations in combination with non-equilibrium Green's function (NEGF)…

Materials Science · Physics 2019-12-02 Renan N. Pedrosa , Wanderlã L. Scopel , Rodrigo G. Amorim

Defects are inevitably present in materials and always can affect their properties. Here, first-principles calculations are performed to systematically study the stability, structural and electronic properties of ten kinds of point defects…

Materials Science · Physics 2015-09-22 Wei Hu , Jinlong Yang

The effect of the number of stacking layers and the type of stacking on the electronic and optical properties of bilayer and trilayer black phosphorus are investigated by using first principles calcula- tions within the framework of density…

Mesoscale and Nanoscale Physics · Physics 2015-10-28 Deniz Cakir , Cem Sevik , Francois M. Peeters

We study the effects of a vertical electric field on the electronic band structure and transport in multilayer phosphorene and its nanoribbons. In phosphorene, at a critical value of the vertical electric field ($E_c$), the band gap closes…

Mesoscale and Nanoscale Physics · Physics 2017-10-24 S. Soleimanikahnoj , I. Knezevic

Density functional theory calculations are performed on phosphorene quantum dots having different shapes and edge terminations to investigate their structure stability, electronic properties, and gas sensing ability. All the selected…

Mesoscale and Nanoscale Physics · Physics 2018-12-05 Hazem Abdelsalam , Vasil A. Saroka , Waleed O. Younis

Black phosphorus is emerging as a promising semiconductor for electronic and optoelectronic applications. To study fundamental carrier properties, we performed ultrafast femtosecond pump-probe spectroscopy on thin film black phosphorus…

Mesoscale and Nanoscale Physics · Physics 2017-03-13 Vasudevan Iyer , Peide Ye , Xianfan Xu

Tuning band gaps in two-dimensional (2D) materials is of great interest in the fundamental and practical aspects of contemporary material sciences. Recently, black phosphorus (BP) consisting of stacked layers of phosphorene was…

Materials Science · Physics 2017-09-13 Sun-Woo Kim , Hyun Jung , Hyun-Jung Kim , Jin-Ho Choi , Su-Huai Wei , Jun-Hyung Cho

Recently rediscovered black phosphorus is a layered semiconductor with promising electronic and photonic properties. Dynamic control of its bandgap can enable novel device applications and allow for the exploration of new physical…

Mesoscale and Nanoscale Physics · Physics 2017-04-21 Bingchen Deng , Vy Tran , Hao Jiang , Cheng Li , Yujun Xie , Qiushi Guo , Xiaomu Wang , He Tian , Han Wang , Judy J. Cha , Qiangfei Xia , Li Yang , Fengnian Xia

The low formation energy of atomic vacancies in black phosphorus allows it to serve as an ideal prototypical system for exploring the dynamics of interlayer interstitial-vacancy (I-V) pairs (i.e. Frenkel defects) which account for Wigner…

Materials Science · Physics 2022-02-02 Devesh R. Kripalani , Yongqing Cai , Ming Xue , Kun Zhou

Phosphorene, an elemental 2D material, which is the monolayer of black phosphorus, has been mechanically exfoliated recently. In its bulk form, black phosphorus shows high carrier mobility (~10000 cm2/Vs) and a ~0.3 eV direct bandgap.…

Mesoscale and Nanoscale Physics · Physics 2014-10-30 Yexin Deng , Zhe Luo , Nathan J. Conrad , Han Liu , Yongji Gong , Sina Najmaei , Pulickel M. Ajayan , Jun Lou , Xianfan Xu , Peide D. Ye

The shortcomings of mono-component systems, e.g., the gapless nature of graphene, the lack of air-stability in phosphorene, etc. have drawn great attention toward stacked materials expected to show interesting electronic and optical…

Mesoscale and Nanoscale Physics · Physics 2020-12-24 Maryam Mahdavifar , Sima Shekarforoush , Farhad Khoeini