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As the simplest element in nature, unraveling the phase diagram of hydrogen is a primary task for condensed matter physics. As conjectured many decades ago, in the low-temperature and high-pressure part of the phase diagram, solid hydrogen…

Superconductivity · Physics 2023-11-14 Mehmet Dogan , Sehoon Oh , Marvin L. Cohen

Ab initio molecular dynamic method within the framework of density functional theory is applied to analyze the structural and electronic properties of crystalline molecular hydrogen at temperature 100\,K. Pressure, pair correlation function…

Materials Science · Physics 2022-01-12 I. Saitov

Elucidating the phase diagram of solid hydrogen is a key objective in condensed matter physics. Several decades ago, it was proposed that at low temperatures and high pressures, solid hydrogen would be a metal with a high superconducting…

Superconductivity · Physics 2023-11-14 Mehmet Dogan , James R. Chelikowsky , Marvin L. Cohen

The 2014-2015 prediction, discovery, and confirmation of record high temperature superconductivity above 200K in H$_3$S, followed by the 2018 extension to superconductivity in the 250-280K range in lanthanum hydride, marks a new era in the…

Superconductivity · Physics 2019-11-13 Yundi Quan , Soham S. Ghosh , Warren E. Pickett

Superconductivity in the recently proposed ground-state structures of atomic metallic hydrogen is investigated over the pressure range 500 GPa to 3.5 TPa. Near molecular dissociation, the electron--phonon coupling $\lambda$ and renormalized…

Superconductivity · Physics 2015-05-28 Jeffrey M. McMahon , David M. Ceperley

Metallic hydrogen is expected to exhibit remarkable physics. Of particular interest in this work is the possibility of high-temperature superconductivity. Comparing calculations of the superconducting critical temperatures of the solid…

Superconductivity · Physics 2021-07-02 Craig M. Tenney , Zachary F. Croft , Jeffrey M. McMahon

Hydrogen has been the essential element in the development of atomic and molecular physics1). Moving to the properties of dense hydrogen has appeared a good deal more complex than originally thought by Wigner and Hungtinton in their seminal…

Materials Science · Physics 2019-06-14 Paul Loubeyre , Florent Occelli , Paul Dumas

Hydrogen-rich compounds have been extensively studied both theoretically and experimentally in the quest for novel high-temperature superconductors. Reports on sulfur-hydride attaining metallicity under pressure and exhibiting…

Following the idea that hydrogen-rich compounds might be high-T$_c$ superconductors at high pressures, and the very recent breakthrough in predicting and synthesizing hydrogen sulfide with record-high T$_c$ = 203 K, ab initio evolutionary…

Superconductivity · Physics 2017-04-19 M. M. Davari Esfahani , A. R. Oganov , H. Niu , J. Zhang

The highest critical temperature of superconductivity Tc has been achieved in cuprates: 133 K at ambient pressure and 164 K at high pressures. As the nature of superconductivity in these materials is still not disclosed, the prospects for a…

Superconductivity · Physics 2014-12-02 A. P. Drozdov , M. I. Eremets , I. A. Troyan

The use of high pressure to realize superconductivity in the vicinity of room temperature has a long history, much of it focused on achieving this in hydrogen rich materials. This paper provides a brief overview of the work presented at…

Superconductivity · Physics 2019-06-11 Russell J. Hemley , Muhtar Ahart , Hanyu Liu , Maddury Somayazulu

Due to its low atomic mass hydrogen is the most promising element to search for high-temperature phononic superconductors. However, metallic phases of hydrogen are only expected at extreme pressures (400 GPa or higher). The measurement of a…

Superconductivity · Physics 2016-03-23 José A. Flores-Livas , Antonio Sanna , E. K. U. Gross

Hydrogen sulfide (H2S) is a prototype molecular system and a sister molecule of water. The phase diagram of solid H2S at high pressures remains largely unexplored arising from the challenges in dealing with the looser S-H bond and larger…

Superconductivity · Physics 2015-03-26 Yinwei Li , Jian Hao , Yanling Li , Yanming Ma

By employing first-principles metadynamics simulations, we explore the 300 K structures of solid hydrogen over the pressure range 150-300 GPa. At 200 GPa, we find the ambient-pressure disordered hexagonal close-packed (hcp) phase transited…

Materials Science · Physics 2012-08-16 Hanyu Liu , Li Zhu , Wenwen Cui , Yanming Ma

A systematic ab initio search for low enthalpy phases of disilane (Si_2H_6) at high pressures was performed based on the minima hopping method. We found a novel metallic phase of disilane with Cmcm symmetry, which is enthalpically more…

Hydrogen is the most abundant element in the universe, and its properties under conditions of high temperature and pressure are crucial to understand the interior of of large gaseous planets and other astrophysical bodies. At ultra high…

Materials Science · Physics 2013-03-12 Hanyu Liu , E. R. Hernandez , Jun Yan , Yanming Ma

This article reports the experimentally clarified crystal structure of a recently discovered sulfur hydride in high temperature superconducting phase which has the highest critical temperature Tc over 200 K which has been ever reported. For…

In previous work,1 we showed that hydrogen metallizes in phase III at temperatures below ~200 K and at pressures near ~350 GPa. Here, we perform a detailed study of electrical conductivity R(T) in phase III over a pressure range of 200-400…

Materials Science · Physics 2021-09-24 M. I. Eremets , P. P. Kong , A. P. Drozdov

A superconductor is a material that can conduct electricity with no resistance below its critical temperature (Tc). The highest Tc that has been achieved in cuprates1 is 133 K at ambient pressure2 and 164 K at high pressures3. As the nature…

Superconductivity · Physics 2016-03-31 A. P. Drozdov , M. I. Eremets , I. A. Troyan , V. Ksenofontov , S. I. Shylin

Light-element compounds hold great promise of high critical temperature superconductivity judging from the theoretical perspective. Hydrogen-rich material, benzene, is such a kind of candidate but also an organic compound. A series of…

Superconductivity · Physics 2018-05-24 Guo-Hua Zhong , Chun-Lei Yang , Xiao-Jia Chen , Hai-Qing Lin
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