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We introduce a computational method developed for study of long-range molecular Rydberg states of such systems that can be approximated by two electrons in a model potential of the atomic cores. Only diatomic molecules are considered. The…

Chemical Physics · Physics 2016-01-26 Michal Tarana , Roman Čurík

We investigate the non-adiabatic quantum dynamics of ultralong-range Rydberg molecules using a vibronically coupled two-channel treatment. The two channels are composed of coupled trilobite and butterfly electronic states, formed as a…

Atomic Physics · Physics 2026-03-17 Felix Giering , Rohan Srikumar , Peter Schmelcher

We demonstrate Rydberg blockade due to the charge-dipole interaction between a single Rb atom and a single RbCs molecule confined in optical tweezers. The molecule is formed by magnetoassociation of a Rb+Cs atom pair and subsequently…

We examine interactions between atoms continuously and coherently driven between the ground state and a Rydberg state, producing "Rydberg-dressed atoms." Because of the large dipolar coupling between two Rydberg atoms, a small admixture of…

Atomic Physics · Physics 2015-05-19 J. E. Johnson , S. L. Rolston

We have performed high resolution photoassociation spectroscopy of rubidium ultra long-range Rydberg molecules in the vicinity of the 25$P$ state. Due to the hyperfine interaction in the ground state perturber atom, the emerging mixed…

Atomic Physics · Physics 2017-08-24 Thomas Niederprüm , Oliver Thomas , Tanita Eichert , Herwig Ott

We probe resonant dipolar interactions between ultracold $^{40}$K$^{87}$Rb molecules and Rydberg $^{87}$Rb atoms in an optically trapped ensemble. Through state-selective ionization detection of the KRb molecules, we observe resonant energy…

Atomic Physics · Physics 2025-04-10 Lingbang Zhu , Jeshurun Luke , Roy Shaham , Yi-Xiang Liu , Kang-Kuen Ni

We describe the emergence of strong spatial correlations, akin to liquid-like behavior and crystallization effects, in low (one and two) dimensional gases of cold Rydberg atoms. The presence of an external electric field permanently…

Using the multipolar expansion of electrostatic and magnetostatic potential energies, we characterize the long-range interactions between two weakly-bound diatomic molecules, taking as an example the paramagnetic Er$_2$ Feshbach molecules…

Atomic Physics · Physics 2017-04-11 Maxence Lepers , Goulven Quéméner , Eliane Luc-Koenig , Olivier Dulieu

We present experimental evidence for spin-orbit interaction of an electron as it scatters from a neutral atom. The scattering process takes place within a Rb$_2$ ultralong-range Rydberg molecule, consisting of a Rydberg atomic core, a…

We present a new mechanism contributing to the detection of photoassociated long-range Rydberg molecules via pulsed-field ionization: ionic products, created by the decay of a long-range Rydberg molecule, modify the excitation spectrum of…

Atomic Physics · Physics 2023-01-26 Michael Peper , Martin Trautmann , Johannes Deiglmayr

We show that very large nonlocal nonlinear interactions between pairs of colliding slow-light pulses can be realized in atomic vapors in the regime of electromagnetically induced transparency. These nonlinearities are mediated by strong,…

Quantum Physics · Physics 2007-05-23 Inbal Friedler , David Petrosyan , Michael Fleischhauer , Gershon Kurizki

We report on the observation of highly excited ($\nu \sim 100)$ vibrational states of a trilobite ultralong-range Rydberg molecule in $^{87}$Rb. These states manifest spectroscopically in a regularly spaced series of peaks red-detuned from…

We investigate triatomic molecules that consist of two ground state atoms and a highly excited Rydberg atom, bound at large internuclear distances of thousands of \AA ngstroms. In the molecular state the Rydberg electron is in a…

Atomic Physics · Physics 2019-02-27 Christian Fey , Frederic Hummel , Peter Schmelcher

We investigate the collective excitation effect in a scheme where three identical Rydberg atoms are arranged in an equilateral triangular lattice. By using a static electric field polarizing the atomic dipoles, the dipole-dipole…

Atomic Physics · Physics 2016-08-24 Jing Qian

We present a novel binding mechanism where a neutral Rydberg atom and an atomic ion form a molecular bound state at large internuclear distance. The binding mechanism is based on Stark shifts and level crossings which are induced in the…

Atomic Physics · Physics 2021-12-28 Markus Deiß , Shinsuke Haze , Johannes Hecker Denschlag

A few-body approach relying on static line broadening theory is developed to treat the spectroscopy of a single Rydberg excitation to a trilobite-like state immersed in a high density ultracold medium. The present theoretical framework…

Atomic Physics · Physics 2016-09-14 Jesús Pérez-Ríos , Matthew T Eiles , Chris H Greene

Rydberg states of atoms are of great current interest for quantum manipulation of mesoscopic samples of atoms. Long-range Rydberg-Rydberg interactions can inhibit multiple excitations of atoms under the appropriate conditions. These…

Atomic Physics · Physics 2009-11-10 Thad G. Walker , Mark Saffman

Resonant laser excitation of multiple Rydberg atoms are prohibited, leading to Rydberg blockade, when the long-range van der Waals interactions are stronger than the laser-atom coupling. Rydberg blockade can be violated, i.e. simultaneous…

Quantum Physics · Physics 2021-10-04 Shi-Lei Su , Weibin Li

We present a comprehensive study of the diverse properties of heteronuclear Rydberg molecules, placing a special emphasis on those composed of the light alkali atoms, Li, Na, and K. Electron-atom scattering phase shifts, which determine the…

Atomic Physics · Physics 2019-02-13 Matthew T. Eiles

We theoretically investigate trapped ions interacting with atoms that are coupled to Rydberg states. The strong polarizabilities of the Rydberg levels increases the interaction strength between atoms and ions by many orders of magnitude, as…

Quantum Physics · Physics 2016-07-27 Thomas Secker , Rene Gerritsma , Alexander W. Glaetzle , Antonio Negretti