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A non-iterative method is presented to calculate the closest Wannier functions (CWFs) to a given set of localized guiding functions, such as atomic orbitals, hybrid atomic orbitals, and molecular orbitals, based on minimization of a…

Materials Science · Physics 2023-07-03 Taisuke Ozaki

We present a robust algorithm that computes (maximally localized) Wannier functions (WFs) without the need of providing an initial guess. Instead, a suitable starting point is constructed automatically from so-called local orbitals which…

Materials Science · Physics 2020-07-01 Sebastian Tillack , Andris Gulans , Claudia Draxl

We present an automatized approach towards maximally localized Wannier functions (MLWFs) applicable to both occupied and unoccupied states. We overcome limitations of the standard optimized projection function (OPF) method and its…

Materials Science · Physics 2025-02-17 Sebastian Tillack , Claudia Draxl

We have developed a practical scheme to construct partly occupied, maximally localized Wannier functions (WFs) for a wide range of systems. We explain and demonstrate how the inclusion of selected unoccupied states in the definition of the…

Materials Science · Physics 2009-11-11 K. S. Thygesen , L. B. Hansen , K. W. Jacobsen

Maximally localized Wannier functions (MLWFs) are widely used to construct first-principles tight-binding models that accurately reproduce the electronic structure of materials. Recently, robust and automated approaches to generate these…

Computational Physics · Physics 2023-11-02 Junfeng Qiao , Giovanni Pizzi , Nicola Marzari

Maximally-localized Wannier functions are quantum wavefunctions resembling atomic orbitals that are used to describe electrons in condensed matter. Since their introduction in 1997, these functions have become ubiquitous in ab initio…

Computational Physics · Physics 2026-04-09 Sabyasachi Tiwari , Bruno Cucco , Viet-Anh Ha , Feliciano Giustino

Maximally-localized Wannier functions (MLWFs) are widely employed as an essential tool for calculating the physical properties of materials due to their localized nature and computational efficiency. Projectability-disentangled Wannier…

Materials Science · Physics 2025-11-25 Yuhao Jiang , Junfeng Qiao , Nataliya Paulish , Weisheng Zhao , Nicola Marzari , Giovanni Pizzi

Since the seminal work of Marzari and Vanderbilt, maximally localized Wannier functions have become widely used as a real-space representation of the electronic structure of periodic materials. In this paper we introduce selectively…

Strongly Correlated Electrons · Physics 2016-04-08 Runzhi Wang , Emanuel A. Lazar , Hyowon Park , Andrew J. Millis , Chris A. Marianetti

We provide a new variational definition for the spread of an orbital under periodic boundary conditions (PBCs) that is continuous with respect to the gauge, consistent in the thermodynamic limit, well-suited to diffuse orbitals, and…

Materials Science · Physics 2023-05-18 Kangbo Li , Hsin-Yu Ko , Robert A. DiStasio , Anil Damle

We introduce a scheme for constructing partly occupied, maximally localized Wannier functions (WFs) for both molecular and periodic systems. Compared to the traditional occupied WFs the partly occupied WFs posses improved symmetry and…

Materials Science · Physics 2009-11-10 K. S. Thygesen , L. B. Hansen , K. W. Jacobsen

Maximally localized Wannier functions (MLWFs) are conventionally constructed by iteratively minimizing a spread functional over a high-dimensional gauge landscape. In this work, we present a non-variational constructive algorithm that…

Materials Science · Physics 2026-05-15 Yuji Hamai , Katsunori Wakabayashi

The construction of Wannier functions from Bloch orbitals offers a unitary freedom that can be exploited to yield Wannier functions with advantageous properties. Minimizing the spatial variance is a well-known choice; another, previously…

Materials Science · Physics 2026-04-29 Aaron Mahler , Jacob Z. Williams , Neil Qiang Su , Weitao Yang

We present a method for obtaining well-localized Wannier-like functions (WFs) for energy bands that are attached to or mixed with other bands. The present scheme removes the limitation of the usual maximally-localized WFs method (N. Marzari…

Materials Science · Physics 2009-11-07 Ivo Souza , Nicola Marzari , David Vanderbilt

We propose an algorithm to determine Maximally Localized Wannier Functions (MLWFs). This algorithm, based on recent theoretical developments, does not require any physical input such as initial guesses for the Wannier functions, unlike…

Materials Science · Physics 2017-03-13 Éric Cancès , Antoine Levitt , Gianluca Panati , Gabriel Stoltz

Over the last two decades, following the early developments on maximally localized Wannier functions, an ecosystem of electronic-structure simulation techniques and software packages leveraging the Wannier representation has flourished.…

We discuss a method for determining the optimally-localized set of generalized Wannier functions associated with a set of Bloch bands in a crystalline solid. By ``generalized Wannier functions'' we mean a set of localized orthonormal…

Materials Science · Physics 2009-10-30 Nicola Marzari , David Vanderbilt

A procedure to construct symmetry-adapted Wannier functions in the framework of the maximally-localized Wannier function approach[Marzari and Vanderbilt, Phys. Rev. B \textbf{56}, 12847 (1997); Souza, Marzari, and Vanderbilt, \textit{ibid.}…

Strongly Correlated Electrons · Physics 2015-06-16 R. Sakuma

Maximally localized Wannier functions are widely used in electronic structure theory for analyses of bonding, electric polarization, orbital magnetization, and for interpolation. The state of the art method for their construction is based…

Materials Science · Physics 2015-12-02 Jamal I. Mustafa , Sinisa Coh , Marvin L. Cohen , Steven G. Louie

A standard task in solid state physics and quantum chemistry is the computation of localized molecular orbitals known as Wannier functions. In this manuscript, we propose a new procedure for computing Wannier functions in one-dimensional…

Mathematical Physics · Physics 2025-10-21 Abinand Gopal , Hanwen Zhang

Maximally-localized Wannier functions (MLWFs) are a powerful and broadly used tool to characterize the electronic structure of materials, from chemical bonding to dielectric response to topological properties. Most generally, one can…

Computational Physics · Physics 2023-11-07 Junfeng Qiao , Giovanni Pizzi , Nicola Marzari
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