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We address the feasibility of imaging geometric and orbital structure of a polyatomic molecule on an attosecond time-scale using the laser induced electron diffraction (LIED) technique. We present numerical results for the highest molecular…

In this paper, we discuss the possibility of imaging molecular orbitals from photoelectron spectra obtained via Laser Induced Electron Diffraction (LIED) in linear molecules. This is an extension of our work published recently in Physical…

Atomic Physics · Physics 2017-08-18 R. Puthumpally-Joseph , J. Viau-Trudel , M. Peters , T. T. Nguyen-Dang , O. Atabek , E. Charron

Ultrafast diffraction imaging is a powerful tool to retrieve the geometric structure of gas-phase molecules with combined picometre spatial and attosecond temporal resolution. However, structural retrieval becomes progressively difficult…

Chemical Physics · Physics 2021-10-13 Xinyao Liu , Kasra Amini , Aurelien Sanchez , Blanca Belsa , Tobias Steinle , Jens Biegert

The ability to directly follow and time resolve the rearrangement of the nuclei within molecules is a frontier of science that requires atomic spatial and few-femtosecond temporal resolutions. While laser induced electron diffraction can…

Laser-induced electron diffraction is an evolving tabletop method, which aims to image ultrafast structural changes in gas-phase polyatomic molecules with sub-{\AA}ngstr\"om spatial and femtosecond temporal resolution. Here, we provide the…

Visualizing molecular transformations in real-time requires a structural retrieval method with {\AA}ngstr\"om spatial and femtosecond temporal atomic resolution. Imaging of hydrogen-containing molecules additionally requires an imaging…

By analyzing ``exact'' theoretical results from solving the time-dependent Schr\"odinger equation of atoms in few-cycle laser pulses, we established the general conclusion that differential elastic scattering and photo-recombination cross…

Atomic Physics · Physics 2008-04-04 Toru Morishita , Anh-Thu Le , Zhangjin Chen , C. D. Lin

Recently introduced speckle-correlations based techniques enable noninvasive imaging of objects hidden behind scattering layers. In these techniques the hidden object Fourier amplitude is retrieved from the scattered light autocorrelation,…

Optics · Physics 2022-01-19 Tengfei Wu , Ori Katz , Xiaopeng Shao , Sylvain Gigan

Knowledge of molecular structure is paramount in understanding, and ultimately influencing, chemical reactivity. For nearly a century, diffractive imaging has been used to identify the structures of many biologically-relevant gas-phase…

Chemical Physics · Physics 2020-03-09 Kasra Amini , Jens Biegert

We explore the laser-induced ionization dynamics of N2 and CO2 molecules subjected to a few-cycle, linearly polarized, 800\,nm laser pulse using effective two-dimensional single active electron time-dependent quantum simulations. We show…

Atomic Physics · Physics 2012-10-02 Michel Peters , Tung Nguyen-Dang , Eric Charron , Arne Keller , Osman Atabek

Structural information on electronically excited neutral molecules can be indirectly retrieved, largely through pump-probe and rotational spectroscopy measurements with the aid of calculations. Here, we demonstrate the direct structural…

Large polyatomic molecules typically exhibit low ionization potentials, Ip, leading to over-the-barrier ionization (OBI) already at relatively low intensities (~1013 W/cm2). We revisit laser-induced electron diffraction (LIED) in the…

Atomic Physics · Physics 2024-11-07 B. Belsa , K. M. Ziems , A. Sanchez , K. Chirvi , X. Liu , S. Grfe , J. Biegert

Based on the classical Lorentz model of the index of refraction, a new method is presented for the extraction of the complex index of refraction from the extinction efficiency of homogeneous and layered dielectric spheres that…

Optics · Physics 2022-06-28 Kalpa de Silva , Proity Akbar , Reinhold Blümel

Imaging the structure of molecules in transient excited states remains a challenge due to the extreme requirements for spatial and temporal resolution. Ultrafast electron diffraction from aligned molecules (UEDAM) provides atomic resolution…

Atomic Physics · Physics 2015-10-23 Jie Yang , Joshua Beck , Cornelis J. Uiterwaal , Martin Centurion

For the example of the SiC(111)-(3x3) reconstruction we show that a holographic interpretation of discrete Low Energy Electron Diffraction (LEED) spot intensities arising from ordered, large unit cell superstructures can give direct access…

Materials Science · Physics 2009-10-31 K. Reuter , J. Schardt , J. Bernhardt , H. Wedler , U. Starke , K. Heinz

Knowledge of the molecular structure is key to understanding the function of participating molecules in photo-induced chemical reactions. Visualizing the nuclear dynamics of a photochemical reaction requires an ultrafast measurement…

Chemical Physics · Physics 2021-12-21 Kasra Amini

Photoelectron spectroscopy in intense laser fields has proven to be a powerful tool for providing detailed insights into molecular structure. The ionizing molecular orbital, however, has not been reconstructed from the photoelectron…

Atomic Physics · Physics 2023-04-14 XuanYang Lai , RenPing Sun , ShaoGang Yu , YanLan Wang , Wei Quan , André Staudte , XiaoJun Liu

Signal recovery from nonlinear measurements involves solving an iterative optimization problem. In this paper, we present a framework to optimize the sensing parameters to improve the quality of the signal recovered by the given iterative…

Image and Video Processing · Electrical Eng. & Systems 2020-06-09 Zikui Cai , Rakib Hyder , M. Salman Asif

We report an iterative algorithm to retrieve accurate real space information from gas phase ultrafast diffraction measurements with missing data at low momentum transfer. The algorithm operates in a manner similar to phase retrieval…

Chemical Physics · Physics 2026-02-25 Yanwei Xiong , Nikhil Kumar Pachisia , Martin Centurion

Infrared (IR) spectroscopy, a type of vibrational spectroscopy, is widely used for molecular structure determination and provides critical structural information for chemists. However, existing approaches for recovering molecular structures…

Machine Learning · Computer Science 2026-03-09 Wenjin Wu , Aleš Leonardis , Linjiang Chen , Jianbo Jiao
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