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Hydrophobic solid-water interfaces underpin processes in nanofluidics, electrochemistry, and energy technologies. Microscopic insights into these systems are often inferred from our understanding of the air-water interface, which is assumed…

Thermal batteries based on a reversible adsorption-desorption of a working fluid rather than the conventional vapor compression is a promising alternative to exploit waste thermal energy for heat reallocation. In this context, there is an…

Mesoscale and Nanoscale Physics · Physics 2017-02-24 Daiane Damasceno Borges , Guillaume Maurin , Douglas S. Galvao

Adsorption at an attractive surface in a system with particles self-assembling into small clusters is studied by Molecular dynamics (MD) simulation. We assume Lennard-Jones plus repulsive Yukawa tail interactions, and focus on small…

Statistical Mechanics · Physics 2019-07-01 Marek Litniewski , Alina Ciach

Solvents are an essential element in the production and processing of two-dimensional (2D) materials. For example, the liquid phase exfoliation of layered materials requires a solvent to prevent the resulting monolayers from re-aggregating,…

Materials Science · Physics 2018-09-10 Urvesh Patil , Nuala M. Caffrey

Alkali-metal adsorption on the surface of materials is widely used for in situ surface electron doping, particularly for observing unoccupied band structures by angle-resolved photoemission spectroscopy (ARPES). However, the effects of…

I review our recent results concerning the metal abundances in quasar absorption-line spectra obtained with the UVES/VLT, HIRES/ KECK, and STIS/HST spectrographs. The analysis is based on the Monte Carlo inversion procedure aimed at the…

Astrophysics · Physics 2007-05-23 S. A. Levshakov

Metal ions play numerous important roles in biological systems being central to the function of biomolecules. In this letter we show that the absorption of X-rays by these ions leads to a complicated chain of ultrafast relaxation steps…

Chemical Physics · Physics 2016-03-23 Vasili Stumpf , Kirill Gokhberg , Lorenz S. Cederbaum

Employing density functional theory calculations we explore initial stage of competitive alloying of co-deposited silver and indium atoms into a silicon surface. Particularly, we identify respective adsorption positions and activation…

Materials Science · Physics 2023-02-17 D. V. Prodan , G. V. Paradezhenko , D. Yudin , A. A. Pervishko

Black body materials prove promising candidates to meet future energy demands as they are able to harvest energy from the total bandwidth of solar radiation. Here, we report on high absorption (> 98 %) near-black body-like structures…

Materials Science · Physics 2020-04-22 Mario Ziegler , Andre Dathe , Kilian Pollok , Falko Langenhorst , Uwe Huebner , Dong Wang , Peter Schaaf

Recently, a homogenization procedure has been proposed, based on the tight lower bounds of the Bergman-Milton formulation, and successfully applied to dilute ternary nanocomposites to predict optical data without using any fitting…

Materials Science · Physics 2016-12-09 Justin Trice , Hernando Garcia , Radhakrishna Sureshkumar , Ramki Kalyanaraman

In this study, the suitability of zeolite as a possible medium for ammonium adsorption, desorption and recovery from wastewater was investigated. Specifically, batch adsorption and desorption studies with solutions enriched in NH$_4^+$ were…

We evaluate the electric dipole absorption in small metal particles in a longitudinal electric field taking into account the Fermi-Thomas screening. When either the level broadening or the frequency of the field are larger than the mean…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 R. A. Serota , B. Goodman

By means of density, dielectric spectroscopy and sound velocity measurements we perform a systematic study on the polyoxyethylene $C_{12}E_{6}$ nonionic surfactant solutions as a function of temperature and concentration. Both density and…

Chemical Physics · Physics 2007-05-23 Luca Falconi , Marco Maccarini , Giuseppe Briganti , Giovanni D'Arrigo

Adsorption of eight organic molecules (acetone, acetonitrile, ammonia, benzene, methane, methanol, ethanol, and toluene) onto silicene has been investigated using van der Waals density functional theory calculations (DFT-D). The calculated…

Mesoscale and Nanoscale Physics · Physics 2014-09-23 Thaneshwor P. Kaloni , Georg Schreckenbach , Michael S. Freund

A lattice gas model of adsorption inside cylindrical pores is evaluated with Monte Carlo simulations. The model incorporates two kinds of site: (a line of) ``axial'' sites and surrounding ``cylindrical shell'' sites, in ratio 1:7. The…

Statistical Mechanics · Physics 2009-11-10 Raluca A. Trasca , M. Mercedes Calbi , Milton W. Cole , Jose L. Riccardo

Using first-principles calculations we show that the work function of noble metals can be decreased or increased by up to 2 eV upon the adsorption of self-assembled monolayers of organic molecules. We identify the contributions to these…

Other Condensed Matter · Physics 2007-05-23 Paul C. Rusu , Geert Brocks

This study examined the effects of surfactants on the motion and positioning of microparticles in an inhomogeneous electric field. The microparticles were suspended in oil with a surfactant and the electric field was generated using…

Soft Condensed Matter · Physics 2020-01-07 Marcos Masukawa , Masayuki Hayakawa , Masahiro Takinoue

Hydrogen uptake in complex multicomponent alloys, including high-entropy alloys (HEAs), governs both hydrogen storage capacity and resistance to hydrogen-induced degradation. We combine high-pressure experiments, density-functional theory…

In a world where capture and separation processes represent above 10% of global energy consumption, novel porous materials, such as Metal-Organic Frameworks (MOFs) used in adsorption-based processes are a promising alternative to dethrone…

Materials Science · Physics 2022-10-20 Azahara Luna-Triguero , Eduardo Andres-Garcia , Pedro Leo , Willy Rook , Freek Kapteijn

In this work we investigate the electronic properties of mercaptocarboxylic acids with several carbon chain lengths adsorbed on ZnO-(10-10) surfaces via density functional theory calculations using semi-local and hybrid exchange-correlation…

Materials Science · Physics 2018-10-05 Dennis Franke , Michael Lorke , Thomas Frauenheim , Andrea L. daRosa
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