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Na-ion conduction, and correlations between Na-ion conduction pathways and crystal structure have been investigated as a function of temperature in the layered battery material Na2Ni2TeO6 by impedance spectroscopy and neutron diffraction,…

Materials Science · Physics 2020-07-15 A. K. Bera , S. M. Yusuf

The complex electric modulus and the ac conductivity of carbon nanoonion/polyaniline composites were studied from 1 mHz to 1 MHz at isothermal conditions ranging from 15 K to room temperature. The temperature dependence of the electric…

Alkaline electrolyte solutions are important components in rechargeable batteries and alkaline fuel cells. As the ionic conductivity is thought to be a limiting factor in the performance of these devices, which are often operated at…

The polyanionic compound Na2MnSiO4 is regarded as one of the promising cathode materials for Na-ion batteries due to good specific capacity with its attractive prospect of utilization of two electrons in the redox processes. So, in this…

Materials Science · Physics 2021-10-19 Vishnu Sudarsanan , Anu Maria Augustine , P Ravindran

The behaviors of resistance, magnetoresistance (up to 5 T), and Hall electromotive force (EMF) with varying temperature (from 10 to 300 K) and measuring current (from 10 mkA to 10 mA) are studied for the Si sample with CrSi2…

Mesoscale and Nanoscale Physics · Physics 2014-10-14 V. V. Andrievskii , Yu. F. Komnik , I. B. Berkutov , I. G. Mirzoiev , N. G. Galkin , D. L. Goroshko

In the quest of green energy, Solid Oxide Fuel Cells (SOFC) have drawn considerable attention for chemical-to-electric energy conversion. In the present paper, we report an enhancement of ionic conductivity in Cu2P2-xVxO7 by vanadium…

We report the temperature dependent dielectric properties and impedance spectroscopy investigation of Na$_3$Zr$_2$Si$_2$PO$_{12}$ in the frequency range of 20 Hz--2 MHz. The Rietveld refinement of x-ray diffraction pattern confirms the…

Materials Science · Physics 2022-11-23 Ramcharan Meena , Rajendra S. Dhaka

We prepared Na$_x$TO$_2$ (T = Mn, Co) nanostructures to use as cathode material in Na-ion batteries. The Rietveld refinement of x-ray diffraction data confirms the hexagonal symmetry. Scanning and transmission electron microscopy…

Materials Science · Physics 2018-06-06 Mahesh Chandra , Rishabh Shukla , Muhammad Rashid , Amit Gupta , Suddhasatwa Basu , R. S. Dhaka

Thermoelectric materials enables the harvest of waste heat and directly conversion into electricity. In search of high efficient thermoelectric materials, low thermal conductivity of a material is essential and critical. Here, we have…

Materials Science · Physics 2019-01-30 Cong Wang , Y. B. Chen , Shu-Hua Yao , Jian Zhou

We have used the pulsed muon source at ISIS to study high-temperature Na-ion dynamics in the quasi-one-dimensional (Q1D) metallic antiferromagnet NaV2O4. By performing systematic zero-field and longitudinal-field measurements as a function…

We calculated the influence of surface tension on the barriers of oxygen ionic conductivity in nanograin ceramics. Activation energy of oxygen ions diffusion via oxygen vacancies which were considered as the dilatational centers was…

Materials Science · Physics 2007-05-23 M. D. Glinchuk , P. I. Bykov , B. Hilczer

We study the temperature dependence of the conductivity of the 2D electronic solid. In realistic samples, a domain structure forms in the solid and each domain randomly orients in the absence of the in-plane field. At higher temperature,…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Shi-Jie Yang , Yue Yu

Highly conductive solid electrolytes are one key component for the development of safe and high-power all-solid-state batteries. Enormous progress has been achieved in the field of lithium solid electrolytes. Meanwhile, their ion…

Materials Science · Physics 2017-12-14 Marc Duchardt , Uwe Ruschewitz , Stefanie Dehnen , Bernhard Roling

A radical anion based functionalization of the basal plane of two-dimensional (2D) materials is proposed in the present study. Simple charge neutral radical functionalizations typically detach from the basal planes upon reduction. For…

Materials Science · Physics 2021-05-26 Karoly Nemeth

We report the exfoliation of layered Na2Ti3O7, a promising anode material for Na-ion batteries, and restacking using HNO3 and NaOH to form H-Ti3O7 and Na(x)-Ti3O7 compositions, respectively. The materials were characterised by a range of…

Short nanopores have various applications in biosensing, desalination, and energy conversion. Here, the modulation of charged exterior surfaces on ionic transport is investigated through simulations with sub-200 nm long nanopores under…

Soft Condensed Matter · Physics 2024-02-08 Long Ma , Zhe Liu , Jia Man , Jianyong Li , Zuzanna S. Siwy , Yinghua Qiu

In search of the potential cathode materials for sodium-ion batteries and to understand the diffusion kinetics, we report the detailed analysis of electrochemical investigation of honeycomb structured Na$_{2}$Ni$_{2}$TeO$_{6}$ material…

Chemical Physics · Physics 2021-12-02 Jayashree Pati , Hari Raj , Simranjot K. Sapra , Anita Dhaka , A. K. Bera , S. M. Yusuf , R. S. Dhaka

The interplay between charge ordering and its manifestation in macroscopic electrical transport in low-dimensional materials is crucial for understanding resistive switching mechanisms. In this study, we investigate the electronic transport…

Strongly Correlated Electrons · Physics 2025-11-11 Nitin Kumar , Nicholas Jerla , John Ponis , Sarbajit Banerjee , G. Sambandamurthy

We have performed thermal expansion and compressibility measurements on the recently discovered superconducting material NaxCoO2*4xD2O (x=1/3) using neutron powder diffraction over the temperature range 10-295 K and the pressure range 0-0.6…

Superconductivity · Physics 2009-11-11 J. D. Jorgensen , M. Avdeev , D. G. Hinks , P. W. Barnes , S. Short

The realization of green and economically friendly energy storage systems needs materials with outstanding properties. Future batteries based on Na as an abundant element take advantage of non-flammable ceramic electrolytes with very high…

Materials Science · Physics 2017-09-12 S. Lunghammer , D. Prutsch , S. Breuer , D. Rettenwander , I. Hanzu , Q. Ma , F. Tietz , M. Wilkening
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