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Water's ability to autoionize into hydroxide and hydronium ions profoundly influences surface properties, rendering interfaces either basic or acidic. While it is well-established that protons show an affinity to the air-water interface, a…

Chemical Physics · Physics 2025-02-05 Xavier R. Advincula , Kara D. Fong , Angelos Michaelides , Christoph Schran

We consider phoretic self-propulsion of a chemically active colloid where solute is consumed at both the colloid boundary and within the bulk solution. Assuming first-order kinetics, the dimensionless transport problem is governed by the…

Fluid Dynamics · Physics 2023-10-10 Rodolfo Brandão , David Saintillan , Ehud Yariv

Active drops emit/absorb chemical solutes, whose concentration gradients cause interfacial flows driving their own transport and the propulsion of the droplet. Such non-linear coupling enables active drops to achieve directed…

Fluid Dynamics · Physics 2022-12-01 Nikhil Desai , Sebastien Michelin

Particles that are immersed in a fluid exchange momentum via the fluid, hence their Brownian motion is correlated. By means of multiparticle-collision dynamics simulations we study the interactions between two colloidal beads in a sheared…

Soft Condensed Matter · Physics 2012-03-16 Marc Radu , Tanja Schilling

Using fluorescence microscopy we study the adsorption of single latex microparticles at a water/water interface between demixing aqueous solutions of polymers, generally known as a water-in-water emulsion. Similar microparticles at the…

Soft Condensed Matter · Physics 2018-05-23 Louis Keal , Carlos E. Colosqui , Hans Tromp , Cecile Monteux

Colloidal aggregation could be implemented in various fields ranging from purely colloidal thermodynamics to protein interactions, their stability, and maybe folding. Indeed, colloidal aggregation is closely linked to the so-called…

Soft Condensed Matter · Physics 2013-01-03 Pierre de Thier

The development of microfluidic devices has recently revived the interest in "old" problems associated with transport at, or across, interfaces. As the characteristic sizes are decreased, the use of pressure gradients to transport fluids…

Materials Science · Physics 2016-08-16 Lydéric Bocquet , J. -L. Barrat

Using molecular dynamics simulations we study the slow dynamics of a hard sphere fluid confined in a disordered porous matrix. The presence of both discontinuous and continuous glass transitions as well as the complex interplay between…

Soft Condensed Matter · Physics 2009-09-29 Jan Kurzidim , Daniele Coslovich , Gerhard Kahl

If an active Janus particle is trapped at the interface between a liquid and a fluid, its self-propelled motion along the interface is affected by a net torque on the particle due to the viscosity contrast between the two adjacent fluid…

Soft Condensed Matter · Physics 2016-02-15 P. Malgaretti , M. N. Popescu , S. Dietrich

The behaviour of rod-coil diblock copolymers close to a surface is discussed by using extended scaling methods. The copolymers are immersed in selective solvent such that the rods are likely to aggregate to gain energy. The rods are assumed…

Soft Condensed Matter · Physics 2009-11-11 C. Nowak , T. A. Vilgis

The behavior of proteins near interfaces is relevant for biological and medical purposes. Previous results in bulk show that, when the protein concentration increases, the proteins unfold and, at higher concentrations, aggregate. Here, we…

Soft Condensed Matter · Physics 2021-01-19 David March , Valentino Bianco , Giancarlo Franzese

Surface effects are generally prevailing in confined colloidal systems. Here we report on dispersed nanoparticles close to a fluid membrane. Exact results regarding the static organization are derived for a dilute solution of non-adhesive…

Statistical Mechanics · Physics 2009-11-10 Thomas Bickel , Mabrouk Benhamou , Hamid Kaidi

Self-driven nanofluidic flow at the liquid-air interface is a non-intuitive phenomenon. This flow behaviour was not driven by classical pressure difference or evaporation only. Depending on the position of the nanofluidic pore we can…

Quantum Physics · Physics 2022-09-02 Vinitha Johny , Sonia Contera , Siddharth Ghosh

We show theoretically that near a fluid-fluid interface a single active colloidal particle generating, e.g., chemicals or a temperature gradient experiences an effective force of hydrodynamic origin. This force is due to the fluid flow…

Soft Condensed Matter · Physics 2016-03-16 Alvaro Domínguez , Paolo Malgaretti , Mihail N. Popescu , Siegfried Dietrich

We present the hydrodynamic theory of coherent collective motion ("flocking") at a solid-liquid interface, and many of its predictions for experiment. We find that such systems are stable, and have long-range orientational order, over a…

Soft Condensed Matter · Physics 2022-01-05 Niladri Sarkar , Abhik Basu , John Toner

Fluids consisting of hard platelike particles near a hard wall are investigated using density functional theory. The density and orientational profiles as well as the surface tension and the excess coverage are determined and compared with…

Statistical Mechanics · Physics 2009-11-07 L. Harnau , S. Dietrich

We investigate hydrodynamic interaction effects between colloidal particles in the vicinity of a wall in the low Reynolds-number limit. Hydrodynamically interacting pairs of beads being dragged by a force parallel to a wall, as for instance…

Soft Condensed Matter · Physics 2013-09-09 Steffen Schreiber , Jochen Bammert , Philippe Peyla , Walter Zimmermann

Interfaces are a most common motif in complex systems. To understand how the presence of interfaces affect hydrophobic phenomena, we use molecular simulations and theory to study hydration of solutes at interfaces. The solutes range in size…

Soft Condensed Matter · Physics 2014-09-05 Amish J. Patel , Patrick Varilly , Sumanth N. Jamadagni , Hari Acharya , Shekhar Garde , David Chandler

Colloidal probes immersed in an active bath have been found to behave like active particles themselves. Here, we use coarse-grained simulations to investigate the mechanisms behind this behavior. We find that the active motion of the…

Soft Condensed Matter · Physics 2024-01-18 Jeanine Shea , Gerhard Jung , Friederike Schmid

The macroscopic phenomenon of filtration is the separation between suspended and liquid phases and it takes place in natural environments (e.g. groundwater, soil, hyporheic zone) and industrial systems (e.g. filtration plants,…