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Hydrogen (H2) is a promising carbon-neutral energy carrier. However, its deployment is limited by the lack of lightweight, reversible storage media that operate under practical conditions. Here, we establish nitrogen-doped graphdiyne…

Materials Science · Physics 2026-05-15 Wael Othman , Ibrahim Alghoul , K-F. Aguey-Zinsou5 , Nacir Tit , Tanveer Hussain

Motivated by the recent realization of graphene sensors to detect individual gas molecules, we investigate the adsorption of H2O, NH3, CO, NO2, and NO on a graphene substrate using first-principles calculations. The optimal adsorption…

Materials Science · Physics 2009-11-13 O. Leenaerts , B. Partoens , F. M. Peeters

Magnetic properties of graphenic carbon nanostructures, relevant for future spintronic applications, depend crucially on doping and on the presence of defects. In this paper we study the magnetism of the recently detected substitutional Ni…

Mesoscale and Nanoscale Physics · Physics 2008-09-18 E. J. G. Santos , A. Ayuela , S. B. Fagan , J. Mendes Filho , D. L. Azevedo , A. G. Souza Filho , D. Sánchez-Portal

Based on first principles calculation, the electronic properties of graphene on metal (Ti, Ca, Ni, Mn, Co, Fe, Cr, K) modified SiO2 substrate have been studied. The results of binding energies supported graphene indicate that the metal…

Mesoscale and Nanoscale Physics · Physics 2012-03-02 L. Shen , F. Jiang , M. Xiao , R. Zhang , M. X. Yu , L. Miao , J. J. Jiang

The high carrier mobility in graphene promises its utility in electronics applications. Azobenzene is a widely studied organic molecule for switchable optoelectronic devices that can be synthesized with a wide variety of ligands and…

Materials Science · Physics 2015-06-18 Jonathan Trinastic , Hai-Ping Cheng

Graphene is an excellent candidate for the next generation of electronic materials due to the strict two-dimensionality of its electronic structure as well as the extremely high carrier mobility. A prerequisite for the development of…

Materials Science · Physics 2009-10-01 Isabella Gierz , Christian Riedl , Ulrich Starke , Christian R. Ast , Klaus Kern

Due to the weak spin-orbit interaction and the peculiar relativistic dispersion in graphene, there are exciting proposals to build spin qubits in graphene nanoribbons with armchair boundaries. However, the mutual interactions between…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Hsiu-Hau Lin , Toshiya Hikihara , Horng-Tay Jeng , Bor-Luen Huang , Chung-Yu Mou , Xiao Hu

We showed how a structural modification of graphene, which gives a carbon allotrope graphyne, can induce an energy gap at the K point of the Brillouin zone. Upon adsorption on metallic surfaces, the same mechanism is responsible for the…

Mesoscale and Nanoscale Physics · Physics 2014-10-16 P. Lazic , Z. Crljen

Graphene grown on metal surface, Cu(111), with a boron nitride(BN) buffer layer is studied for the first time. Our first-principles calculations reveal that charge is transferred from the copper substrate to graphene through the BN buffer…

Materials Science · Physics 2007-12-27 Y. H. Lu , P. M. He , Y. P. Feng

Sodium, magnesium and aluminum adatoms, which, respectively, possess one, two and three valence electrons in terms of 3s, $3s^2$, and ($3s^2$, 3p) orbitals, are very suitable for helping us understand the adsorption-induced diverse…

Materials Science · Physics 2020-03-06 Ngoc Thanh Thuy Tran , Godfrey Gumbs , Duy Khanh Nguyen , Ming-Fa Lin

We have performed a first-principles study on the deformation effect of the electronic structures of graphite nanoribbon arrays with zigzag edges on both sides, and the edge atoms are terminated with hydrogen atoms. A uniaxial strain is…

Materials Science · Physics 2008-10-28 W. S. Su , B. R. Wu , T. C. Leung

We use density functional theory (DFT) with a recently developed van der Waals density functional (vdW-DF) to study the adsorption of graphene on Al, Cu, Ag, Au, Pt, Pd, Co and Ni(111) surfaces. In constrast to the local density…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 M. Vanin , J. J. Mortensen , A. K. Kelkkanen , J. M. Garcia-Lastra , K. S. Thygesen , K. W. Jacobsen

Many of the proposed future applications of graphene require the controlled introduction of defects into its perfect lattice. Energetic ions provide one way of achieving this challenging goal. Single heavy ions with kinetic energies in the…

Materials Science · Physics 2010-09-27 S. Akcöltekin , H. Bukowska , T. Peters , O. Osmani , I. Monnet , I. Alzaher , B. Ban d'Etat , H. Lebius , M. Schleberger

The anchoring of benzene molecules on lithium adsorption sites at the surface of graphene and nanoribbons thereof are investigated. The effects of adsorbate densities, specific adsorption locations, and spin states on the structural…

Materials Science · Physics 2013-10-01 Dana Krepel , Oded Hod

We prescribe general rules to predict the existence of edge states and zero-energy flat bands in graphene nanoribbons and graphene edges of arbitrary shape. No calculations are needed. For the so-called {\it{minimal}} edges, the projection…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 W. Jaskolski , A. Ayuela , M. Pelc , H. Santos , L. Chico

The effect of increased electron-density (from adsorbed Li atoms) in polyacenes and in nano-ribbons with zig-zag edge is discussed in terms of resonance theoretical considerations and in terms edge-localized frontier molecular orbitals. The…

Chemical Physics · Physics 2025-11-10 Yenni P. Ortiz , Douglas J. Klein , Thomas H. Seligman

Implantation and subsequent behaviour of heavy noble gases (Ar, Kr, Xe) in few-layer graphene sheets and in nanodiamonds is studied both using computational methods and experimentally using X-ray absorption spectroscopy. X-ray absorption…

Mesoscale and Nanoscale Physics · Physics 2021-10-07 Andrey A. Shiryaev , Alexander L. Trigub , Ekaterina N. Voronina , Kristina O. Kvashnina , Valentin L. Bukhovets

We have demonstrated that the island nucleation in the initial stage of epitaxial thin film growth can be tuned by substrate surface charge doping. This charge effect was investigated using spin density functional theory calculation in…

Materials Science · Physics 2015-06-19 Wenmei Ming , Feng Liu

We report an experimental investigation of the edge effect on the room-temperature transport in graphene nanoribbon and graphene sheet (both single-layer and bilayer). By measuring the resistance scaling behaviors at both low and high…

Mesoscale and Nanoscale Physics · Physics 2011-02-15 Guangyu Xu , Carlos M. Torres , Jianshi Tang , Jingwei Bai , Emil B. Song , Yu Huang , Xiangfeng Duan , Yuegang Zhang , Kang L. Wang

A promising material for hydrogen storage at room temperature-Al doped graphene was proposed theoretically by using density functional theory calculation. Hydrogen storage capacity of 5.13 wt% was predicted at T = 300 K and P = 0.1 Gpa with…

Materials Science · Physics 2009-11-13 Z. M. Ao , Q. Jiang , R. Q. Zhang , T. T. Tan , S. Li