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We show that individual vibrational modes in single-molecule junctions with asymmetric molecule-lead coupling can be selectively excited by applying an external bias voltage. Thereby, a non-statistical distribution of vibrational energy can…

Mesoscale and Nanoscale Physics · Physics 2017-09-13 R. Volkovich , R. Härtle , M. Thoss , U. Peskin

Phonons, quantized vibrations of the atomic lattice, are fundamental to understanding thermal transport, structural stability, and phase behavior in crystalline solids. Despite advances in computational materials science, most predictions…

Materials Science · Physics 2026-01-15 Huiju Lee , Zhi Li , Jiangang he , Yi Xia

Self-assembled molecular structures have been intensively used in molecular electronics and spintronics. However, detailed nature of the interfaces between molecular layers and extended metallic contacts used to bias the real devices…

We describe how to treat the interaction of travelling electrons with localised vibrational modes in nanojunctions. We present a multichannel scattering technique which can be applied to calculate the transport properties for realistic…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 H. Ness , A. J. Fisher

We investigate the role of electronic-vibrational coupling in resonant electron transport through single-molecule junctions, taking into account that the corresponding coupling strengths may depend on the charge and excitation state of the…

Mesoscale and Nanoscale Physics · Physics 2016-03-23 Andre Erpenbeck , Rainer Härtle , Michel Bockstedte , Michael Thoss

We calculate numerically the normal modes of vibrations in 3D jammed packings of soft spheres as a function of the packing fraction and obtain the energy diffusivity, a spectral measure of transport that controls sound propagation and…

Disordered Systems and Neural Networks · Physics 2013-05-29 Vincenzo Vitelli , Ning Xu , Matthieu Wyart , Andrea J. Liu , Sidney R. Nagel

In this work, we consider an open single level molecular junction with electrons coupled to a single frequency phonon mode, in which the phonons are also coupled to another heat bath. By applying a temperature gradient between the…

Mesoscale and Nanoscale Physics · Physics 2019-09-20 Amir Eskandari-asl

Diamond is studied by path integral molecular dynamics simulations of the atomic nuclei in combination with a tight-binding Hamiltonian to describe its electronic structure and total energy. This approach allows us to quantify the influence…

Materials Science · Physics 2009-11-11 Rafael Ramirez , Carlos P. Herrero , Eduardo R. Hernandez

The high energy transfer efficiency of photosynthetic complexes has been a topic of research across many disciplines. Several attempts have been made in order to explain this energy transfer enhancement in terms of quantum mechanical…

Quantum Physics · Physics 2022-09-02 Ali Pedram , Barış Çakmak , Özgür E. Müstecaplıoğlu

The realization of single-molecule thermal conductance measurements has driven the need for theoretical tools to describe conduction processes that occur over atomistic length scales. In macroscale systems, the principle that is typically…

Mesoscale and Nanoscale Physics · Physics 2023-05-17 Galen T. Craven , Abraham Nitzan

Following the nonequilibrium Green's function formalism we study the thermal transport in a composite chain subject to a time-dependent perturbation. The system is formed by two finite linear asymmetric harmonic chains subject to an on-site…

Mesoscale and Nanoscale Physics · Physics 2016-09-21 N. Beraha , A. Soba , M. F. Carusela

Transport phenomena are ubiquitous throughout the science, engineering and technology disciplines as it concerns energy, mass, charge and information exchange between systems. In particular, energy transport in the nanoscale regime has…

Quantum Physics · Physics 2018-07-26 Chikako Uchiyama , William J. Munro , Kae Nemoto

This paper reviews the formulation of the Feynman-Vernon model of linear dissipative systems for a standard Brownian particle moving in an external potential $V(x,t)$ and introduces the formulation of a generalized oscillator model of a…

Quantum Physics · Physics 2018-03-29 Marco Patriarca

Recent experiments at the nanoscales confirm that thermal rectifiers, the thermal equivalent of electrical diodes, can operate in the quantum regime. We present a thorough investigation of the effect of different particle exchange…

Mesoscale and Nanoscale Physics · Physics 2022-11-10 Stephania Palafox , Ricardo Román-Ancheyta , Barış Çakmak , Özgür E. Müstecaplıoğlu

We present a detailed treatment of the nonequilibrium Green's function method for thermal transport due to atomic vibrations in nanostructures. Some of the key equations, such as self-energy and conductance with nonlinear effect, are…

Statistical Mechanics · Physics 2011-11-09 Jian-Sheng Wang , Nan Zeng , Jian Wang , Chee Kwan Gan

We study inelastic vibration-assisted charge transfer effects in two-site molecular junctions, focusing on signatures of vibrational anharmonicity on the electrical characteristics and the thermoelectric response of the junction. We…

Statistical Mechanics · Physics 2017-12-27 Hava Meira Friedman , Bijay Kumar Agarwalla , Dvira Segal

Boltzmann transport theory, the standard framework for predicting thermal conductivity, assumes that every vibrational mode eventually scatters, acquiring a finite lifetime that yields a convergent, length-independent thermal conductivity:…

Mesoscale and Nanoscale Physics · Physics 2026-05-22 P. M. Martinez , O. Mateos-Lopez , J. C. Cuevas , J. G. Vilhena

The influence of the environment in the thermal equilibrium properties of a bipartite continuous variable quantum system is studied. The problem is treated within a system-plus-reservoir approach. The considered model reproduces the…

Quantum Physics · Physics 2011-07-05 D. M. Valente , A. O. Caldeira

In this work we theoretically study properties of electric current driven by a temperature gradient through a quantum dot/molecule coupled to the source and drain charge reservoirs. We analyze the effect of Coulomb interactions between…

Mesoscale and Nanoscale Physics · Physics 2015-12-01 Natalya A. Zimbovskaya

We propose a new method for computing the temperature dependence of the heat capacity in complex molecular systems. The proposed scheme is based on the use of the Langevin equation with low frequency color noise. We obtain the temperature…

Computational Physics · Physics 2009-11-13 Sahin Buyukdagli , Alexander V. Savin , Bambi Hu