Related papers: Vibrational relaxation of hot ground state cations…
We report the results of an analysis of data obtained with the INTEGRAL, Swift and RXTE observatories during the 2010 April and September outbursts of the X-ray pulsar RX J0440.9+4431. The temporal and spectral properties of the pulsar in a…
We have investigated the vibrational density of states (VDOS) of a thin Cu nanowire with $<100>$ axial orientation and considered the effect of axial strain. The VDOS are calculated using a real space Green's function approach with the…
Collective electronic excitations "excitons" in planar optical lattices exhibit strong modifications of the radiative damping rate and directional emission pattern as compared to a single excited atom. Excitons for long wave numbers and…
Low-lying collective excitations in even-even vibrational and transitional nuclei may be described semi-classically as quadrupole running waves on the surface of the nucleus ("tidal waves"), and the observed vibrational-rotational behavior…
A recent proposal for practical calculation of vibrational mode lifetimes is tested on simple, low-dimensional anharmonic models. The proposed scheme approximates the mode lifetime in terms of ensemble averages of specific functions in…
Excited state normal modes analysis is systematically applied to investigate and compare relaxation and internal conversion dynamics of a free-base porphyrin with a novel functional porphyrin derivative. We discuss strenghts and limitation…
A coherent control scheme for the population distribution in the vibrational states of nonpolar molecules is proposed. Our theoretical analysis and results of numerical simulations for the interaction of the hydrogen molecular ion in its…
A vibrational wavepacket in SF$_6$, created by impulsive stimulated Raman scattering with a few-cycle infrared pulse, is mapped onto five sulfur core-excited states using table-top soft X-ray transient absorption spectroscopy between…
Low-energy vibrational excitations associated with the fluctuation of quadrupole deformed shapes are discussed within the frame of state-of-the-art Configuration Interaction calculations, actually performed via the Quasi-particle Vacua…
We study nanomechanical resonators with frequency fluctuations due to diffusion of absorbed particles. The diffusion depends on the vibration amplitude through inertial effect. We find that, if the diffusion coefficient is sufficiently…
The article presents the result of an extended in silico experiment on computational vibrational spectroscopy of graphene molecules performed using the virtual vibrational spectrometer UHF VVS, previously proposed in the first part of the…
We calculate the potential energy curves, the permanent dipole moment curves, and the lifetimes of the ground and excited vibrational states of the heteronuclear alkali dimers XY (X, Y = Li, Na, K, Rb, Cs) in the X1{\Sigma}+ electronic…
Electron-phonon coupling in atoms and molecules adsorbed at metal surfaces gives rise to finite vibrational linewidths in infrared or electron energy loss spectra. When it is the dominant contribution to the vibrational lifetime, it…
Intensity enhancement in vibrational circular dichroism (VCD) arises in open-shell transition metal complexes from coupling between ground-state vibrational transitions and magnetic dipole-allowed transitions to low-lying excited states…
The radiative decay of excited states of the negative ion of rhodium, Rh$^-$, has been investigated experimentally and theoretically. The experiments were conducted at the Double ElectroStatic Ion Ring Experiment (DESIREE) facility at…
We report electronic, vibrational, and rotational spectroscopic parameters for the ground state, X$^2\Sigma^{+}$, of singly charged aluminium monohalides, employing single-reference coupled-cluster theory with single and double excitations…
Energies of ns[1/2] (n= 6-9), np[j] (n = 6-8), nd[j] (n= 6-7), and 5f[j] states in neutral Au and Au-like ions with nuclear charges Z = 80 - 83 are calculated using relativistic many-body perturbation theory. Reduced matrix elements,…
Vibrational properties of graphene nanoribbons are examined with density functional based tight-binding method and non-resonant bond polarization theory. We show that the recently discovered reconstructed zigzag edge can be identified from…
We formulate a vibrationally resolved kinetics for molecular hydrogen and its cation in the primordial Universe chemistry. Formation, destruction and relaxation processes for each vibrational level are studied and included as chemical…
We propose a general approach to characterise fluctuations of measured cross sections of nuclear giant resonances. Simulated cross sections are obtained from a particular, yet representative self-energy which contains all information about…