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Accurately simulating molecular vibronic spectra remains computationally challenging due to the exponential scaling of required calculations. Here, we show that employing the linear coupling model within the gaussian boson sampling…

Quantum Physics · Physics 2025-08-07 I. Konyshev , R. Pradip , O. Page , C. Ünlüer , R. T. Nasibullin , V. V. Rybkin , W. Pernice , S. Ferrari

Conformational dynamics of biomolecules are of fundamental importance for their function. Single-molecule F\"orster Resonance Energy Transfer (smFRET) is a powerful approach to inform on the structure and the dynamics of labeled molecules.…

Rescattering electrons offer great potential as probes of molecular properties on ultrafast timescales. The most famous example is molecular tomography, in which high harmonic spectra of oriented molecules are mapped to ``tomographic…

Atomic Physics · Physics 2016-09-28 Zachary B. Walters , Stefano Tonzani , Chris H. Greene

Diffusion Transformers (DiTs) have demonstrated strong performance in generative modeling, particularly in image synthesis, making them a compelling choice for molecular conformer generation. However, applying DiTs to molecules introduces…

Machine Learning · Computer Science 2025-11-12 J. Thorben Frank , Winfried Ripken , Gregor Lied , Klaus-Robert Müller , Oliver T. Unke , Stefan Chmiela

The application of the stabilization method [A.~U.\ Hazi and H.~S.\ Taylor, Phys.~Rev.~A {\bf 1}, 1109 (1970)]) to extract accurate energy and lifetimes of resonance states is challenging: The process requires labor-intensive numerical…

Computational Physics · Physics 2026-01-01 Johanna Langner , Anjan Sadhukhan , Jayanta K. Saha , Henryk A. Witek

We present Wavemoth, an experimental open source code for computing scalar spherical harmonic transforms (SHTs). Such transforms are ubiquitous in astronomical data analysis. Our code performs substantially better than existing publicly…

Instrumentation and Methods for Astrophysics · Physics 2012-02-17 D. S. Seljebotn

Accurate spectroscopic constants and electrical properties of small molecules are determined by means of W4 and post-W4 theories. For a set of 28 first- and second-row diatomic molecules for which very accurate experimental spectroscopic…

Chemical Physics · Physics 2015-05-19 Amir Karton , Jan M. L. Martin

We present the first non-LTE, co-moving frame molecular line calculations of a star-forming cluster simulated using smoothed particle hydrodynamics (SPH), from which we derive high-resolution synthetic observations. We have resampled a…

Solar and Stellar Astrophysics · Physics 2015-05-18 David Rundle , Tim J. Harries , David M. Acreman , Matthew R. Bate

Precision measurement of the cosmological recombination spectrum can provide an entire new window to look at the early universe. We aim to quantify the information hidden in the cosmological recombination spectrum and for this purpose we…

Cosmology and Nongalactic Astrophysics · Physics 2020-02-05 Debajyoti Sarkar , Rishi Khatri

Line-by-line calculations are becoming the standard procedure for carrying spectral simulations. However, it is important to insure the accuracy of such spectral simulations through the choice of adapted models for the simulation of key…

Optics · Physics 2007-05-23 M. Lino da Silva

Effective representation of molecules is a crucial factor affecting the performance of artificial intelligence models. This study introduces a flexible, fragment-based, multiscale molecular representation framework called t-SMILES…

Machine Learning · Computer Science 2024-05-22 Juan-Ni Wu , Tong Wang , Yue Chen , Li-Juan Tang , Hai-Long Wu , Ru-Qin Yu

There will be a paradigm shift in chemical and biological research, to be enabled by autonomous, closed-loop, real-time self-directed decision-making experimentation. Spectrum-to-structure correlation, which is to elucidate molecular…

Chemical Physics · Physics 2026-01-21 Xinyu Lu , Hao Ma , Hui Li , Jia Li , Yi Rong , Yuqiang Li , Tong Zhu , Guokun Liu , Bin Ren

Introduction: molecular geometry, the three-dimensional arrangement of atoms within a molecule, is fundamental to understanding chemical reactivity, physical properties, and biological activity. The prevailing models used to describe…

General Physics · Physics 2026-05-12 Sebastian Ali Sacasa-Cespedes

We show that combining vibrational spectroscopy with signal processing can result in a scheme for ultrasensitive detection of molecules. We consider the vibrational spectrum as a signal on the energy axis and apply a matched filter on that…

Computational Physics · Physics 2018-12-10 Tay Yong Boon , Ian Tay Rongde , Loy Liang Yi , Aw Ke Fun , Ong Zhi Li , Sergei Manzhos

We present a new adaptive resolution technique for efficient particle-based multiscale molecular dynamics (MD) simulations. The presented approach is tailor-made for molecular systems where atomistic resolution is required only in spatially…

Soft Condensed Matter · Physics 2007-05-23 Matej Praprotnik , Luigi Delle Site , Kurt Kremer

An algorithm for the calculation of hyperfine structure and spectra of diatomic molecules based on the variational nuclear motion is presented. Hyperfine coupling terms considered are Fermi-contact, nuclear spin-electron spin dipole-dipole,…

Chemical Physics · Physics 2022-02-15 Qianwei Qu , Sergei N. Yurchenko , Jonathan Tennyson

Studies of quantum thermal effects on molecular excitation dynamics have often relied on oversimplified models, such as energy eigenstates or low-dimensional potentials, which fail to capture the complexity of real chemical systems. In…

Chemical Physics · Physics 2025-12-30 Yankai Zhang , Yoshitaka Tanimura , So Hirata

With the aim of describing bound and continuum states for diatomic molecules, we develop and implement a spectral method that makes use of Generalized Sturmian Functions (GSF) in prolate spheroidal coordinates. In order to master all…

Atomic and Molecular Clusters · Physics 2021-06-02 D. M. Mitnik , F. A. Lopez , L. U. Ancarani

Spectral variability significantly impacts the accuracy and convergence of hyperspectral unmixing algorithms. Many methods address complex spectral variability; yet large-scale distortions to the scale of the observed pixel signatures due…

Image and Video Processing · Electrical Eng. & Systems 2026-05-18 Praveen Sumanasekara , Athulya Ratnayake , Buddhi Wijenayake , Keshawa Ratnayake , Roshan Godaliyadda , Parakrama Ekanayake , Vijitha Herath

By using Bohmian trajectory method, we investigate the dynamic interference in diatomic molecular high-order harmonic generation progress. It is demonstrated that the main characteristics of the molecular harmonic spectrum can be well…

Atomic Physics · Physics 2013-08-05 Yang Song , Bing-Bing Wang , Fu-Ming Guo , Su-Yu Li , Xue-Shen Liu , Ji-Gen Chen , Si-Liang Zeng , Yu-Jun Yang