Related papers: The Gibbs paradox
We study equilibrium droplets in two-phase systems at parameter values corresponding to phase coexistence. Specifically, we give a self-contained microscopic derivation of the Gibbs-Thomson formula for the deviation of the pressure and the…
The inclusion of the factor $\ln (1/N!)$ in the thermodynamic entropy proposed by Gibbs is shown to be equivalent to the validity of the fluctuation theorem with absolute irreversibility for gas mixing.
We report the study of a random Lorentz gas with a reaction of isomerization $A\rightleftharpoons B$ between the two colors of moving particles elastically bouncing on hard disks. The reaction occurs when the moving particles collide on…
The thermodynamic maximum principle for the Boltzmann-Gibbs-Shannon (BGS) entropy is reconsidered by combining elements from group and measure theory. Our analysis starts by noting that the BGS entropy is a special case of relative entropy.…
Gibbs' theorem, which is originally intended for canonical ensembles with complete statistics has been generalized to open systems with incomplete statistics. As a result of this generalization, it is shown that the stationary equilibrium…
Particles dropped into a rotating black hole can collide near the inner horizon with enormous energies. The entropy produced by these collisions can be several times larger than the increase in the horizon entropy due to the addition of the…
It is well known that, in the context of General Relativity, some spacetimes, when described by a congruence of comoving observers, may consist in a distribution of a perfect (non-dissipative) fluid, whereas the same spacetime as seen by a…
Randomness is viewed through an analogy between a physical quantity, density of gas, and a mathematical construct -- probability density. Boltzmann's deduction of equilibrium distribution of ideal gas placed in an external potential field…
In an isolated ideal Bose system with a fixed energy, the number of microstates depends solely on the configurations of bosons in excited states, implying zero entropy for particles in the ground state. When two such systems merge, the…
The equilibria formed by the self-gravitating, collisionless collapse of simple initial conditions have been investigated for decades. We present the results of our attempts to describe the equilibria formed in $N$-body simulations using…
A plethora of natural, artificial and social systems exist which do not belong to the Boltzmann-Gibbs (BG) statistical-mechanical world, based on the standard additive entropy $S_{BG}$ and its associated exponential BG factor. Frequent…
Entropy of matter in a very strong gravity depends on cross-sectional area of the container of the system -- is being further bolstered by calculating entropy of a monoatomic gas kept under uniform strong gravity at Newtonian scale. This…
Although current sensitivity limits are such that true Solar System analogs remain challenging to detect, numerous planetary systems have been discovered that are very different from our own Solar System. The majority of systems harbor a…
A new kinetic theory Boltzmann-like collision term including correlations is proposed. In equilibrium it yields the one-particle distribution function in the form of a generalised-Lorentzian resembling but not being identical with the…
We discuss the effects of collisions on the expansion of a degenerate normal Fermi gas, following the sudden removal of the confining trap. Using a Boltzmann equation approach, we calculate the time dependence of the aspect ratio and the…
Based on the property of extensivity (mathematically, homogeneity of first degree), we derive in a mathematically consistent manner the explicit expressions of the chemical potential $\mu$ and the Clausius entropy $S$ for the case of…
The gravitational potential and the gravitational rotation field generated by a thin-disk mass distribution with exponential density are considered in the case when the force between any two mass elements is not the usual Newtonian one, but…
A molecular theory of liquid water is identified and studied on the basis of computer simulation of the TIP3P model of liquid water. This theory would be exact for models of liquid water in which the intermolecular interactions vanish…
For a gas confined in a container, particle-wall interactions produce modifications to the partition function involving the average surface density of gas particles. While such correlations have a vanishing effect in the thermodynamic…
The maximum complexity momentum distribution for an isolated monodimensional ideal gas out of equilibrium is derived analytically. In a first approximation, it consists of a double non-overlapping Gaussian distribution. In good agreement…