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We study the core hole-electron correlation in coherently coupled molecules by energy dispersive near edge X-ray absorption fine-structure spectroscopy. In a transient phase, which exists during the transition between two bulk arrangements,…

Materials Science · Physics 2013-12-03 M. Scholz , F. Holch , C. Sauer , M. Wiessner , A. Schöll , F. Reinert

We report the implementation of energy dispersive X-ray spectroscopy for layered semiconductors in the form of atomically thin transition metal dichalcogenides. The technique is based on a scanning electron microscope equipped with a…

Mesoscale and Nanoscale Physics · Physics 2022-11-17 Anna Rupp , Jonas Göser , Zhijie Li , Philipp Altpeter , Ismail Bilgin , Alexander Högele

Most violent and energetic processes in our universe, including mergers of compact objects, explosions of massive stars and extreme accretion events, produce copious amounts of X-rays. X-ray follow-up is an efficient tool for identifying…

Time-resolved soft-X-ray photoemission spectroscopy is used to simultaneously measure the ultrafast dynamics of core-level spectral functions and excited states upon excitation of excitons in WSe$_2$. We present a many-body approximation…

Transition Edge Sensor (TES) spectrometers for hard X-ray beamline science will enable improved X-ray emission and absorption spectroscopy in the information-rich 2 to 20 keV energy range. We are building a TES-based instrument for the…

Instrumentation and Detectors · Physics 2020-08-26 Tejas Guruswamy , Lisa M. Gades , Antonino Miceli , Umeshkumar M. Patel , John T. Weizeorick , Orlando Quaranta

Ongoing developments in ultrafast X-ray sources offer powerful new means of probing the com- plex non-adiabatically coupled structural and electronic dynamics of photoexcited molecules. These non-Born-Oppenheimer effects are governed by…

Chemical Physics · Physics 2018-07-04 Simon P. Neville , Majed Chergui , Albert Stolow , Michael S. Schuurman

Carrier and phonon dynamics in a multilayer WSe2 film are captured by extreme ultraviolet (XUV) transient absorption (TA) spectroscopy at the W N6,7, W O2,3, and Se M4,5 edges (30-60 eV). After the broadband optical pump pulse, the XUV…

Materials Science · Physics 2023-03-06 Juwon Oh , Hung-Tzu Chang , Christopher T. Chen , Shaul Aloni , Adam Schwartzberg , Stephen R. Leone

Electron energy loss spectroscopy is consolidating as a powerful tool to explore electronic (as well as vibrational) excitations of matter, including molecules. Performed in a scanning transmission electron microscope, this technique is…

Chemical Physics · Physics 2021-03-05 Ciro A. Guido , Enzo Rotunno , Matteo Zanfrognini , Stefano Corni , Vincenzo Grillo

The Transition Edge Sensor is extremely sensitive to the change of temperature, combined with the high-Z metal of a certain thickness, it can realize the high energy resolution measurement of particles such as X-rays. X-rays with energies…

Studies of ultrafast dynamics along with femtosecond-pulse metrology rely on non-linear processes, induced solely by the exciting/probing pulses or the pulses to be characterized. Extension of these approaches to the extreme-ultraviolet…

Atomic Physics · Physics 2015-05-27 P. Tzallas , E. Skantzakis , L. A. A. Nikolopoulos , G. D. Tsakiris , D. Charalambidis

The electronic excitation occurring on adsorbates at ultrafast time scales from optical lasers that initiate surface chemical reactions is still an open question. Here, we report the ultrafast temporal evolution of X-ray absorption…

X-ray interaction with matter is an energy-dependent process that is contingent on the atomic structure of the constituent material elements. The most advanced models to capture this relationship currently rely on Monte Carlo (MC)…

Machine Learning · Computer Science 2023-07-11 Raziye Kubra Kumrular , Thomas Blumensath

Pre-edge features in X-ray absorption spectroscopy contain key information about the lowest excited states and thus on the most interesting physical properties of the system. In transition metal oxides they are particularly structured but…

Materials Science · Physics 2008-07-01 C. Gougoussis , M. Calandra , A. Seitsonen , Ch. Brouder , A. Shukla , F. Mauri

Emergent phenomena at complex-oxide interfaces have become a vibrant field of study in the past two decades due to the rich physics and a wide range of possibilities for creating new states of matter and novel functionalities for potential…

Materials Science · Physics 2024-06-19 C. -T. Kuo , G. Conti , J. E. Rault , C. M. Schneider , S. Nemšák , A. X. Gray

Strong light-matter coupling to form exciton- and vibropolaritons is increasingly touted as a powerful tool to alter the fundamental properties of organic materials. It is proposed that these states and their facile tunability can be used…

We present X-ray absorption spectroscopy and resonant inelastic X-ray scattering (RIXS) measurements on the iron L-edge of 0.5 mM aqueous ferricyanide. These measurements demonstrate the ability of high-throughput transition-edge-sensor…

Core excitons in solids have garnered increasing interest, yet their behavior and decay mechanisms are not fully understood. Here, we use attosecond extreme ultraviolet (XUV) transient absorption spectroscopy, performed with a broadband…

Materials Science · Physics 2023-11-07 Rafael Quintero-Bermudez Stephen R. Leone

The development of X-ray free-electron lasers (XFELs) has enabled ultrafast X-ray diffraction (XRD) experiments, which are capable of resolving electronic/vibrational transitions and structural changes in molecules, or capturing molecular…

Chemical Physics · Physics 2024-08-29 Sebastian V. Pios , Jiaji Zhang , Maxim F. Gelin , Hong-Guang Duan , Lipeng Chen

Transition-edge sensors (TESs) are capable of highly accurate single particle energy measurement. TESs have been used for a wide range of photon detection applications, particularly in astronomy, but very little consideration has been given…

Instrumentation and Detectors · Physics 2023-05-11 K. M. Patel , S. Withington , C. N. Thomas , A. G. Shard , D. J. Goldie