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Episodic accretion in protostars leads to luminosity outbursts that end up heating their surroundings. This rise in temperature pushes the snow lines back, enabling the desorption of chemical species from dust grain surfaces, which may…

Astrophysics of Galaxies · Physics 2024-07-17 P. Marchand , A. Coutens , J. Scigliuto , F. Cruz-Sáenz de Miera , A. Andreu , J. -C. Loison , Á. Kóspál , P. Ábrahám

Molecular nitrogen is one of the key species in the chemistry of interstellar clouds and protoplanetary disks and the partitioning of nitrogen between N and N2 controls the formation of more complex prebiotic nitrogen-containing species.…

Astrophysics of Galaxies · Physics 2015-06-15 Xiaohu Li , Alan N. Heays , Ruud Visser , Wim Ubachs , Brenton R. Lewis , Stephen T. Gibson , Ewine F. van Dishoeck

Formed at an early stage of gas-phase ion-molecule chemistry, hydrides -- molecules containing a heavy element covalently bonded to one or more hydrogen atoms -- play an important role in interstellar chemistry as they are the progenitors…

Astrophysics of Galaxies · Physics 2023-09-20 Arshia Maria Jacob

The presence of H3+ in the interstellar medium was forecast almost four decades ago. Almost three decades ago it was asserted that its reactions with neutral molecular and atomic species directly lead to the production of many of the…

Astrophysics · Physics 2009-11-06 T. R. Geballe

Methyl formate, HCOOCH$_3$, and many of its isotopologues have been detected in astrophysical regions with considerable abundances. However, the recipe for the formation of this molecule and its isotopologues is not yet known. In this work,…

Astrophysics of Galaxies · Physics 2021-06-30 Zainab Awad , Audrey Coutens , Serena Viti , Jonathan Holdship

Modern observations of the interstellar medium (ISM) in galaxies detect a variety of atomic and molecular species. The goal is to connect these observations to the astrochemical properties of the ISM. 3D hydro-chemical simulations attempt…

Astrophysics of Galaxies · Physics 2019-02-20 Thomas G. Bisbas , Andreas Schruba , Ewine F. van Dishoeck

Nanodust, which undergoes stochastic heating by single starlight photons in the interstellar medium, ranges from angstrom-sized large molecules containing tens to thousands of atoms (e.g. polycyclic aromatic hydrocarbon molecules) to grains…

Astrophysics of Galaxies · Physics 2015-06-11 Aigen Li , Ingrid Mann

Interstellar chemistry is important for galaxy formation, as it determines the rate at which gas can cool, and enables us to make predictions for observable spectroscopic lines from ions and molecules. We explore two central aspects of…

The form of depleted sulphur in dense clouds is still unknown. Until now, only two molecules, OCS and SO2, have been detected in interstellar ices but cannot account for the elemental abundance of sulphur observed in diffuse medium.…

Astrophysics of Galaxies · Physics 2015-06-05 C. Druard , V. Wakelam

Recent studies of the nearest star-forming clouds of the Galaxy at submillimeter wavelengths with the Herschel Space Observatory have provided us with unprecedented images of the initial and boundary conditions of the star formation…

We present a comprehensive survey of boron abundances in diffuse interstellar clouds from observations made with the Space Telescope Imaging Spectrograph (STIS) of the Hubble Space Telescope. Our sample of 56 Galactic sight lines is the…

Astrophysics of Galaxies · Physics 2011-02-02 A. M. Ritchey , S. R. Federman , Y. Sheffer , D. L. Lambert

Measurements by dust detectors on interplanetary spacecraft appear to indicate a substantial flux of interstellar particles with masses exceeding 10^{-12}gram. The reported abundance of these massive grains cannot be typical of interstellar…

Astrophysics · Physics 2009-11-13 B. T. Draine

Formaldehyde is a key precursor in the formation routes of many complex organic molecules (COMs) in space. It is also an intermediate step in CO hydrogenation sequence that leads to methanol formation on the surface of interstellar grains…

Astrophysics of Galaxies · Physics 2025-02-04 A. F. Punanova , K. Borshcheva , G. S. Fedoseev , P. Caselli , D. S. Wiebe , A. I. Vasyunin

The construction of viable and physically-realistic interstellar dust models is only possible if the constraints imposed by laboratory data on interstellar dust analogue materials are respected and used within a meaningful theoretical…

Astrophysics of Galaxies · Physics 2015-11-26 Ant Jones

Observations of low mass protostars which probe small enough size scales to be within likely CO depletion regions show the highest [NH2D]/[NH3] ratios yet measured, of 4--33%. These molecular D/H ratios are higher than those measured on…

Astrophysics · Physics 2011-05-23 Jennifer Hatchell

In order to understand how molecular clouds form in the Galactic interstellar medium, we would like to be able to map the structure and kinematics of the gas flows responsible for forming them. However, doing so is observationally…

Astrophysics of Galaxies · Physics 2016-06-01 Simon C. O. Glover , Paul C. Clark

ESA has identified interferometry as one of the major goals of the Horizon 2000+ programme. Infrared interferometers are a highly sensitive astronomical instruments that enable us to observe terrestrial planets around nearby stars. In this…

Astrophysics · Physics 2016-08-16 M. Landgraf , R. Jehn , W. Flury , M. Fridlund , A. Karlsson , A. Léger

Although still poorly understood, the chemistry that occurs on the surfaces of interstellar dust particles profoundly affects the growth of molecules in the interstellar medium. An important set of surface reactions produces icy mantles of…

Astrophysics · Physics 2009-11-13 H. M. Cuppen , Eric Herbst

Freeze-out of the gas phase elements onto cold grains in dense interstellar and circumstellar media builds up ice mantles consisting of molecules that are mostly formed in situ (H2O, NH3, CO2, CO, CH3OH, and more). This review summarizes…

Astrophysics of Galaxies · Physics 2015-09-23 Adwin Boogert , Perry Gerakines , Douglas Whittet

Interstellar objects are interlopers from other planetary systems, and their volatile compositions provide a glimpse into planet formation around their host star. We present near-infrared spectra of the coma of interstellar object 3I/ATLAS…

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