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We introduce affordable computational strategies for calculating orbital and pair-orbital energies in atomic and molecular systems. Our methods are based on the pair Coupled Cluster Doubles (pCCD) ansatz and its orbital-optimized variant.…

Chemical Physics · Physics 2025-02-06 Seyedehdelaram Jahani , Somayeh Ahmadkhani , Katharina Boguslawski , Paweł Tecmer

We establish a comprehensive theoretical framework for systems subjected to a static uniform temperature gradient, employing the non-equilibrium Keldysh-Dyson formalism. This framework interprets the statistical force due to the temperature…

Mesoscale and Nanoscale Physics · Physics 2024-02-01 Luqman Saleem , Udo Schwingenschlogl , Aurelien Manchon

We study time-dependent coupled-cluster theory in the framework of nuclear physics. Based on Kvaal's bi-variational formulation of this method [S. Kvaal, arXiv:1201.5548], we explicitly demonstrate that observables that commute with the…

Nuclear Theory · Physics 2012-07-04 D. A. Pigg , G. Hagen , H. Nam , T. Papenbrock

Atmospheric systems incorporating thermal dynamics must be stable with respect to both energy and entropy. While energy conservation can be enforced via the preservation of the skew-symmetric structure of the Hamiltonian form of the…

Numerical Analysis · Mathematics 2023-10-31 Kieran Ricardo , David Lee , Kenneth Duru

We describe an extension of the Keldysh method for fermions from constant temperature to steady state case with spatially varying temperature field.This is done with the use on the imaginary section of the Keldysh path of a thermal…

High Energy Physics - Theory · Physics 2020-03-24 Alyx Jourjine

Using a manifestly invariant Lagrangian density based on Clebsch fields and suitable for geophysical fluid dynamics, the conservation of mass, entropy, momentum and energy, and the associated symmetries are investigated. In contrast, it is…

Fluid Dynamics · Physics 2017-11-10 Martin Charron , Ayrton Zadra

We examine the effective theory of critical dynamics near superfluid phase transitions in the framework of the Keldysh-Schwinger formalism. We focus on the sector capturing the dynamics of the complex order parameter and the conserved…

High Energy Physics - Theory · Physics 2024-01-31 Aristomenis Donos , Polydoros Kailidis

We employ the numerical linked-cluster expansion to study finite-temperature properties of the uniform cubic lattice Hubbard model in the thermodynamic limit for a wide range of interaction strengths and densities. We carry out the…

Strongly Correlated Electrons · Physics 2016-09-13 Ehsan Khatami

We introduce a non-equilibrium version of the Caldeira-Leggett model in which a quantum particle is strongly coupled to a set of engineered reservoirs. The reservoirs are composed by collections of squeezed and displaced thermal modes, in…

Quantum Physics · Physics 2026-05-19 Vasco Cavina , Massimiliano Esposito

This paper is devoted to the Hartree-Fock model with temperature in the euclidean space. For large classes of free energy functionals, minimizers are obtained as long as the total charge of the system does not exceed a threshold which…

Analysis of PDEs · Mathematics 2009-04-01 Jean Dolbeault , Patricio Felmer , Mathieu Lewin

In this note, we study the optimal control of a nonisothermal phase field system of Cahn-Hilliard type that constitutes an extension of the classical Caginalp model for nonisothermal phase transitions with a conserved order parameter. It…

Optimization and Control · Mathematics 2023-03-24 Pierluigi Colli , Gianni Gilardi , Andrea Signori , Jürgen Sprekels

The multi-layer multi-configurational time-dependent Hartree (MCTDH) in optimized second quantization representation (oSQR) approach combines the tensor contraction scheme of the multi-layer MCTDH approach with the use of an optimized…

Chemical Physics · Physics 2020-02-19 Thomas Weike , Uwe Manthe

We study the dynamical equation of the time-ordered Green's function at finite temperature. We show that the time-ordered Green's function obeys a conventional Dyson equation only at equilibrium and in the limit of zero-temperature. In all…

Other Condensed Matter · Physics 2013-04-08 H. Ness , L. K. Dash

We study the dynamics of a quantum Brownian particle weakly coupled to a thermal bath. Working in the Schwinger-Keldysh formalism, we develop an effective action of the particle up to quartic terms. We demonstrate that this quartic…

High Energy Physics - Theory · Physics 2019-08-09 Bidisha Chakrabarty , Soumyadeep Chaudhuri

The previously proposed ansatz for density cumulant theory that combines orbital-optimization and a parameterization of the 2-electron reduced density matrix cumulant in terms of unitary coupled cluster amplitudes (OUDCT) is carefully…

Chemical Physics · Physics 2020-12-23 Jonathon P. Misiewicz , Justin M. Turney , Henry F. Schaefer , Alexander Yu. Sokolov

A recent paper arXiv:1312.4890 on multi-symplectic magnetohydrodynamics (MHD) using Clebsch variables in an Eulerian action principle with constraints is further extended. We relate a class of symplecticity conservation laws to a vorticity…

Plasma Physics · Physics 2015-12-16 G. M. Webb , J. F. McKenzie , G. P. Zank

In this work, we study the time-dependent behaviour of quantum correlations of a system of an inverted oscillator governed by out-of-equilibrium dynamics using the well-known Schwinger-Keldysh formalism in presence of quantum mechanical…

High Energy Physics - Theory · Physics 2024-10-04 Sayantan Choudhury , Suman Dey , Rakshit Mandish Gharat , Saptarshi Mandal , Nilesh Pandey

We compute the current and the noise power matrix in a quantum dot connected to two metallic reservoirs by using the Keldysh field theory approach, a non-equilibrium quantum field theory language in the functional integral formalism. We…

Mesoscale and Nanoscale Physics · Physics 2024-11-20 Marco Uguccioni , Luca Dell'Anna

A dynamical formulation of coupled cluster theory is derived using a variational principle. By allowing time-dependent single-particle functions, a high degree of adaptivity is introduced, allowing complex systems to be simulated with high…

Quantum Physics · Physics 2014-11-25 Simen Kvaal

We derive the fundamental equations of an optimal control theory for systems containing both quantum electrons and classical ions. The system is modeled with Ehrenfest dynamics, a non-adiabatic variant of molecular dynamics. The general…

Chemical Physics · Physics 2015-06-16 Alberto Castro , E. K. U. Gross