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Porous electrodes are an integral part of many electrochemical devices since they have high porosity to maximize electrochemical transport and high surface area to maximize activity. Traditional porous electrode materials are typically…

Applied Physics · Physics 2022-05-23 Thomas Roy , Miguel A. Salazar de Troya , Marcus A. Worsley , Victor A. Beck

In this paper, we introduce a density-based topology optimization framework to design porous electrodes for maximum energy storage. We simulate the full cell with a model that incorporates electronic potential, ionic potential, and…

Understanding how to structure a porous electrode to facilitate fluid, mass, and charge transport is key to enhance the performance of electrochemical devices such as fuel cells, electrolyzers, and redox flow batteries (RFBs). Using a…

Fluid Dynamics · Physics 2024-06-19 Simone Dussi , Chris H. Rycroft

The properties of rechargeable lithium-ion batteries are determined by the electrochemical and kinetic properties of their constituent materials as well as by their underlying microstructure. Microstructural design can be leveraged to…

Materials Science · Physics 2022-03-11 Giovanna Bucci , Tushar Swamy , W. Craig Carter , Morad Behandish

Porous metallic structures are regularly used in electrochemical energy storage devices as supports, current collectors or active electrode materials. Bulk metal porosification, dealloying, welding or chemical synthesis routes involving…

Applied Physics · Physics 2020-08-26 Vladimir Egorov , Colm O'Dwyer

Electrochemical energy systems rely on particulate porous electrodes to store or convert energies. While the three-dimensional porous structures were introduced to maximize the interfacial area for better overall performance of the system,…

Applied Physics · Physics 2021-02-16 Shubham Agrawal , Peng Bai

The rising demand for high-performing batteries requires new technological concepts. To facilitate fast charge and discharge, hierarchically structured electrodes offer short diffusion paths in the active material. However, there are still…

As power generated from renewables becomes more readily available, the need for power-efficient energy storage devices, such as redox flow batteries, becomes critical for successful integration of renewables into the electrical grid. An…

Chemical Physics · Physics 2022-06-07 Tiras Y. Lin , Sarah E. Baker , Eric B. Duoss , Victor A. Beck

Ionic liquids are widely used as electrolytes in electrochemical devices. In this context, many experimental and theoretical approaches have been recently developed for characterizing their interface with electrodes. In this perspective…

Materials Science · Physics 2017-09-13 Céline Merlet , Benjamin Rotenberg , Paul Madden , Mathieu Salanne

In this work, a two-dimensional mathematical model is developed to study the flow patterns and volumetric flow penetrations in the flow channel over the porous electrode layered system in vanadium flow battery with serpentine flow field…

Soft Condensed Matter · Physics 2016-11-01 Xinyou Ke , Joseph M. Prahl , J. Iwan D. Alexander , Robert F. Savinell

Porous electrodes composed of multiphase active materials are widely used in Li-ion batteries, but their dynamics are poorly understood. Two-phase models are largely empirical, and no models exist for three or more phases. Using a modified…

Chemical Physics · Physics 2014-02-07 Todd R. Ferguson , Martin Z. Bazant

Thick Li-ion battery electrodes with high ion transport rates could enable batteries that cost less and that have higher gravimetric and volumetric energy density, because they require fewer inactive cell-components. Finding ways to…

Materials Science · Physics 2015-05-14 V. Pavan Nemani , Stephen J. Harris , Kyle C. Smith

Porous electrodes are fast emerging as essential components for next generation supercapacitors. Using porous structures of Co3O4, Mn3O4, alpha Fe2O3, and carbon, their advantages over the solid counterpart is unequivocally established. The…

As the design of single-component battery electrodes has matured, the battery industry has turned to hybrid electrodes with blends of two or more active materials to enhance battery performance. Leveraging the best properties of each…

Materials Science · Physics 2023-05-26 Qiaohao Liang , Martin Z. Bazant

As widely used electrochemical storage devices, supercapacitors deliver higher power density than batteries, but suffer from significantly lower energy density. In this work, we propose a topology optimization model for electrode structure…

Optimization and Control · Mathematics 2025-11-27 Jiajie Li , Xiang Ji , Shenggao Zhou , Shengfeng Zhu

Porous media are ubiquitous in energy storage and conversion, catalysis, biomechanics, hydrogeology, as well as many other fields. These materials possess high surface-to-volume ratios and their complex channels can restrict and guide the…

As modern electronic devices are increasingly miniaturized and integrated, their performance relies more heavily on effective thermal management. Two-phase cooling methods enhanced by porous surfaces, which capitalize on thin-film…

Machine Learning · Computer Science 2023-10-31 Jonathan Tammer Eweis-LaBolle , Chuanning Zhao , Yoonjin Won , Ramin Bostanabad

Nanostructured electrodes with voids or interconnected pores accommodate large volume changes, shorten ion diffusion pathways, and enhance the structural reversibility of alloying electrodes. While these nanoporous features improve the…

The structure of lithium ion battery components, such as electrodes and separators, are commonly characterised in terms of their porosity and tortuosity. The ratio of these values gives the effective transport of lithium ions in the…

Applied Physics · Physics 2018-06-04 Marie Francine Lagadec , Raphael Zahn , Simon Müller , Vanessa Wood

A novel 3-electrode cell type is introduced to run parametrical studies of H$_2$ evolution in an alkaline electrolyte on porous electrodes. Electrochemical methods combined with a high-speed optical measurement system are applied…

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