Related papers: Electric quadrupole transitions in carbon dioxide

With the recent radioastronomical detection of cis-trans-carbonic acid (H$_2$CO$_3$) in a molecular cloud toward the galactic center, the more stable but currently unobserved cis-cis conformer is shown here to have strong IR features. While…

Most exoplanets detected so far have atmospheric T significantly higher than 300K. Often close to their star, they receive an intense UV photons flux that triggers important photodissociation processes. The T dependency of VUV absorption…

Mesospheric CO2 clouds are one of two types of carbon dioxide clouds known on Mars. We present observations of mesospheric CO2 clouds made by Atmospheric Chemistry Suit (ACS) onboard the ESA-Roscosmos ExoMars Trace Gas Orbiter (TGO). We…

Astrophysical molecular spectroscopy is an important method of searching for new physics through probing the variation of the proton-to-electron mass ratio, $\mu$, with existing constraints limiting variation to a fractional change of less…

Treating water as a linearly responding dielectric continuum on molecular length scales allows very simple estimates of solvation structure and thermodynamics for charged and polar solutes. While this approach can successfully account for…

Molecular hydrogen normally has only weak, quadrupole transitions between its rovibrational states, but in a static electric field it acquires a dipole moment and a set of allowed transitions. Here we use published ab initio calculations of…

Twisted light beams, or optical vortices, have been used to drive the circular motion of microscopic particles in optical tweezers and have been shown to generate vortices in quantum gases. Recent studies have established that electric…

In hot plasmas, a temperature of a few tens of eV is sufficient for producing highly stripped ions where multipole transitions become important. At low density, the transitions from tightly bound inner shells lead to electric-quadrupole…

Atmospheric carbon dioxide concentrations are being closely monitored by remote sensing experiments which rely on knowing line intensities with an uncertainty of 0.5% or better. We report a theoretical study providing rotation-vibration…

The desorption characteristics of molecules on interstellar dust grains are important for modelling the behaviour of molecules in icy mantles and, critically, in describing the solid-gas interface. In this study, a series of laboratory…

We present in this paper mid-infrared (5-8~$\mu$m) spectroscopy toward the massive young binary W3~IRS~5, using the EXES spectrometer in high-resolution mode ($R\sim$50,000) from the NASA Stratospheric Observatory for Infrared Astronomy…

We report a precise measurement of the isotope shifts in the $4^2$S$_{1/2} \rightarrow 3^2$D$_{5/2}$ electric quadrupole transition at 729~nm in the $^{40 - 42,44,48}$Ca$^+$. The measurement has been made via high-resolution laser…

Water, methane and carbon-monoxide are expected to be among the most abundant molecules besides molecular hydrogen in the hot atmosphere of close-in EGPs. Transit observations in the mid-IR allow the atmospheric content of transiting…

We report the detection of the H_2O molecule in absorption at a redshift z = 0.68466 in front of the gravitationally lensed quasar B0218+357. We detect the fundamental transition of ortho-water at 556.93 GHz (redshifted to 330.59 GHz). The…

Analytical expressions of the wave functions are derived for a Bohr Hamiltonian with the Manning{Rosen potential in the cases of {\gamma}-unstable nuclei and axially symmetric prolate deformed ones with {\gamma}=0. By exploiting the results…

We report new precise H$(e,e^\prime p)\pi^0$ measurements at the $\Delta(1232)$ resonance at $Q^2= 0.127$ (GeV/c)$^2$ using the MIT/Bates out-of-plane scattering (OOPS) facility. The data reported here are particularly sensitive to the…

Transit spectroscopy is a powerful tool for probing atmospheric structures of exoplanets. Accurately accounting for the effects of aerosols is key to reconstructing atmospheric properties from transit spectra, yet this remains a significant…

Despite being studied for over a century, the use of quadrupoles have been limited to Cartesian coordinates in flat spacetime due to the incorrect transformation rules used to define them. Here the correct transformation rules are derived,…

Molecules dominate the cooling function of neutral metal-poor gas at high density. Observation of molecules at high redshift is thus an important tool toward understanding the physical conditions prevailing in collapsing gas. Up to now,…

With the rapid developments in the exoplanet field, more and more terrestrial exoplanets are being detected. Characterising their atmospheres using transit observations will become a key datum in the quest for detecting an Earth-like…