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Understanding high-pressure transitions in prototypical linear diatomic molecules, such as hydrogen, nitrogen, and oxygen, is an important objective in high-pressure physics. Recent ultrahigh-pressure study on hydrogen revealed that there…

Materials Science · Physics 2019-10-31 Shan Liu , Meifang Pu , Qiqi Tang , Feng Zhang , Binbin Wu , Li Lei

Electronic properties of silicon-based clathrates can be tuned by boron incorporation into the silicon cage network. Sodium borosilicides clathrate outstands with uncommon stoichiometry and expected metallic properties, in contrast to other…

Motivated by recent experimental measurements on pressure-driven phase transitions in Mott-insulators as well as the new iron pnictide superconductors, we show that first principles Car-Parrinello molecular dynamics calculations are a…

Strongly Correlated Electrons · Physics 2010-04-06 Yu-Zhong Zhang , Ingo Opahle , Harald O. Jeschke , Roser Valenti

In this paper, we present a thorough investigation of vibrational, structural, and electronic properties of perovskite-type rhombohedral Ba$_2$ZnTeO$_6$ (BZTO) under systematic application of pressure. To carry out the analysis, we have…

Recent advances of highly efficient solar cells based on organic-inorganic halide perovskites have triggered intense research efforts to establish the fundamental properties of these materials. In this work, we utilized diamond anvil cell…

Materials Science · Physics 2015-09-15 Kai Wang , Ran Liu , Yuancun Qiao , Jinxing Cui , Bo Song , Bingbing Liu , Bo Zou

In-situ high pressure single crystal X-ray diffraction study reveals that the quantum material CaMn$_2$Bi$_2$ undergoes a unique plane to chain structural transition between 2 and 3 GPa, accompanied by a large volume collapse. CaMn2Bi2…

Materials Science · Physics 2019-07-18 Xin Gui , Gregory J. Finkelstein , Keyu Chen , Tommy Yong , Przemyslaw Dera , Jinguang Cheng , Weiwei Xie

The recent report of near-ambient superconductivity in nitrogen doped lutetium hydride has triggered a worldwide fanaticism and raised major questions about the latest claims. An intriguing phenomenon of color changes in pressurized samples…

We investigated the effect of high pressure on the field dependences of magnetoresistance (MR) in La_{0.8}Ag_{0.1}MnO_{3} near the metal-insulator transition temperature. Our results showed that an increase in pressure results in a decrease…

Strongly Correlated Electrons · Physics 2023-12-12 A. G. Gamzatov , T. R. Arslanov , A. R. Kaul , Z. Z. Alisultanov

La$_3$Ni$_2$O$_7$, a bilayer nickelate with Ruddlesden-Popper structure, undergoes a pressure-induced structural transition from a tilted Amam phase to an untilted Fmmm (or I4/mmm) phase near 10-15 GPa, concomitant with the emergence of…

The high-pressure behavior of monoclinic VO$_2$ is revisited by a combination of Raman spectroscopy and X-ray diffraction on a single crystal under hydrostatic conditions at room temperature. A soft mode is observed up to P$_c$ = 13.9(1)…

Strongly Correlated Electrons · Physics 2025-01-14 P. Bouvier , L. Bussmann , D. Machon , I. Breslavetz , G. Garbarino , P. Strobel , V. Dmitriev

An extended study on PdS is carried out with the measurements of the resistivity, Hall coefficient, Raman scattering, and X-ray diffraction at high pressures up to 42.3 GPa. With increasing pressure, superconductivity is observed…

Materials Science · Physics 2018-04-18 Liu-Cheng Chen , Hao Yu , Hong-Jie Pang , Bin-Bin Jiang , Lei Su , Xun Shi , Li-Dong Chen , Xiao-Jia Chen

Cadmium arsenide Cd$_3$As$_2$ hosts massless Dirac electrons in its ambient-conditions tetragonal phase. We report X-ray diffraction and electrical resistivity measurements of Cd$_3$As$_2$ upon cycling pressure beyond the critical pressure…

We have demonstrated a pressure-induced phase transition from a low-Tc phase to a high-Tc phase in a single crystal of the superconductor LaO0.5F0.5BiSe2. The high-Tc phase appears at 2.16 GPa and the maximum superconducting transition…

Sm-doped BiFeO3 compacted powders with composition across the morphotropic phase boundary region were prepared by sol-gel method. Crystal structure, morphology and magnetic state of the compounds were analyzed as a function of dopant…

Two dimensional ferroic materials exhibit a variety of functional properties that can be tuned by temperature and pressure. CuInP2S6 is a layered material that is ferrielectric at room temperature and whose properties are a result of the…

Materials Science · Physics 2023-06-14 R. Rao , B. S. Conner , J. Jiang , R. Pachter , M. A. Susner

We studied the transmittance and reflectance of the low-dimensional Mott-Hubbard insulator TiOCl in the infrared and visible frequency range as a function of pressure. The strong suppression of the transmittance and the abrupt increase of…

Strongly Correlated Electrons · Physics 2012-06-05 C. A. Kuntscher , S. Frank , A. Pashkin , M. Hoinkis , M. Klemm , M. Sing , S. Horn , R. Claessen

We investigate pressure-induced structural changes to the Peierls-type distorted low-temperature phase of the low-dimensional Sc$_3$CoC$_4$ as a possible origin of its pressure-enhanced superconductivity. By means of cryogenic high-pressure…

X-ray diffraction (XRD) experiments have been carried out on quartz-like GaPO4 at high pressure and room temperature. A transition to a high pressure disordered crystalline form occurs at 13.5 GPa. Slight heating using a YAG infrared laser…

Condensed Matter · Physics 2009-10-31 James Badro , Jean-Paul Itie , Alain Polian

We propose an atomistic model for the pressure-induced isostructural phase transition of metal-doped silicon clathrates, Ba8Si46 and K8Si46, that has been observed at 14 GPa and 23 GPa, respectively. The model explains successfully the…

Materials Science · Physics 2007-05-23 Toshiaki Iitaka

The crystal structure, magnetic ordering, and electrical resistivity of TlFe1.6Se2 were studied at high pressures. Below ~7 GPa, TlFe1.6Se2 is an antiferromagnetically ordered semiconductor with a ThCr2Si2-type structure. The…