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Quantum computers open up new avenues for modelling the physical properties of materials and molecules. Density Functional Theory (DFT) is the gold standard classical algorithm for predicting these properties, but relies on approximations…

Quantum Physics · Physics 2024-02-29 Evan Sheridan , Lana Mineh , Raul A. Santos , Toby Cubitt

Recent developments in quantum hardware and quantum algorithms have made it possible to utilize the capabilities of current noisy intermediate-scale quantum devices for addressing problems in quantum chemistry and condensed matter physics.…

Quantum Physics · Physics 2023-05-01 Steffen Backes , Yuta Murakami , Shiro Sakai , Ryotaro Arita

Simulation of materials is one of the most promising applications of quantum computers. On near-term hardware the crucial constraint on these simulations is circuit depth. Many quantum simulation algorithms rely on a layer of unitary…

We propose a scheme for the construction of one-particle Green's function (GF) of an interacting electronic system via statistical sampling on a quantum computer. Although the non-unitarity of creation and annihilation operators for the…

Quantum Physics · Physics 2020-02-19 Taichi Kosugi , Yu-ichiro Matsushita

Dynamical mean-field theory (DMFT) maps the local Green's function of the Hubbard model to that of the Anderson impurity model and thus gives an approximate solution of the Hubbard model from the solution of simpler quantum impurity model.…

Quantum Krylov subspace diagonalization is a prominent candidate for early fault tolerant quantum simulation of many-body and molecular systems, but so far the focus has been mainly on computing ground-state energies. We go beyond this by…

Approximating the ground state of many-body systems is a key computational bottleneck underlying important applications in physics and chemistry. The most widely known quantum algorithm for ground state approximation, quantum phase…

The problem of estimating the ground-state energy of a quantum system is ubiquitous in chemistry and condensed matter physics. Krylov quantum diagonalization (KQD) has emerged as a promising approach for this task. However, many KQD methods…

Quantum Physics · Physics 2025-09-30 Adam Byrne , William Kirby , Kirk M. Soodhalter , Sergiy Zhuk

Density-functional theory (DFT) has revolutionized computer simulations in chemistry and material science. A faithful implementation of the theory requires self-consistent calculations. However, this effort involves repeatedly diagonalizing…

Quantum Physics · Physics 2023-07-17 Taehee Ko , Xiantao Li , Chunhao Wang

The quantum Fourier transform for discrete variable (dvQFT) is an efficient algorithm for several applications. It is usually considered for the processing of quantum bits (qubits) and its efficient implementation is obtained with two…

Quantum Physics · Physics 2025-12-16 Gianfranco Cariolaro , Edi Ruffa , Amir Mohammad Yaghoobianzadeh , Jawad A. Salehi

Quantum computers have been widely speculated to offer significant advantages in obtaining the ground state of difficult Hamiltonian in chemistry and physics. In this work, we first propose a Lyapunov control-inspired strategy to accelerate…

Quantum Physics · Physics 2022-12-21 Yu-Cheng Chen , Yu-Qin Chen , Alice Hu , Chang-Yu Hsieh , Shengyu Zhang

We introduce a variational hybrid classical-quantum algorithm to simulate the Lindblad master equation and its adjoint for time-evolving Markovian open quantum systems and quantum observables. Our method is based on a direct representation…

Quantum Physics · Physics 2023-05-19 Tasneem Watad , Netanel H. Lindner

The Krylov subspace methods, being one category of the most important classical numerical methods for linear algebra problems, can be much more powerful when generalised to quantum computing. However, quantum Krylov subspace algorithms are…

Quantum Physics · Physics 2024-08-14 Zongkang Zhang , Anbang Wang , Xiaosi Xu , Ying Li

A state-preserving quantum counting algorithm is used to obtain coefficients of a Lanczos recursion from a single ground state wavefunction on the quantum computer. This is used to compute the continued fraction representation of an…

Quantum Physics · Physics 2021-03-10 Thomas E. Baker

The non-equilibrium Green's function method combined with density functional theory (NEGF-DFT) provides a rigorous framework for simulating nanoscale electronic transport, but its computational cost scales steeply with system size. Recent…

Mesoscale and Nanoscale Physics · Physics 2025-10-21 Zili Tang , Xiaoxin Xie , Guanwen Yao , Ligong Zhang , Xiaoyan Liu , Xing Zhang , Liu Fei

While the ground state of magnetic materials is in general well described on the basis of spin density functional theory (SDFT), the theoretical description of finite-temperature and non-equilibrium properties require an extension beyond…

Materials Science · Physics 2022-06-22 Sergiy Mankovsky , Hubert Ebert

We introduce a practical hybrid approach that combines orbital-free density functional theory (DFT) with Kohn-Sham DFT for speeding up first-principles molecular dynamics simulations. Equilibrated ionic configurations are generated using…

In probability theory, the partition function is a factor used to reduce any probability function to a density function with total probability of one. Among other statistical models used to represent joint distribution, Markov random fields…

Emerging Technologies · Computer Science 2025-01-03 Timothe Presles , Cyrille Enderli , Gilles Burel , El Houssain Baghious

We propose quantum algorithms for projective ground-state preparation and calculations of the many-body Green's functions directly in frequency domain. The algorithms are based on the linear combination of unitary (LCU) operations and…

Quantum Physics · Physics 2021-12-13 Trevor Keen , Eugene Dumitrescu , Yan Wang

This work provides a nonasymptotic error analysis of quantum Krylov algorithms based on real-time evolutions, subject to generic errors in the outputs of the quantum circuits. We prove upper and lower bounds on the resulting ground state…

Quantum Physics · Physics 2024-09-04 William Kirby