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We present a method for performing path integral molecular dynamics (PIMD) simulations for fermions and address its sign problem. PIMD simulations are widely used for studying many-body quantum systems at thermal equilibrium. However, they…

Chemical Physics · Physics 2020-05-07 Barak Hirshberg , Michele Invernizzi , Michele Parrinello

Path integral Monte Carlo (PIMC) simulations are used to calculate the momentum distribution of the homogeneous electron gas at finite temperature. This is done by calculating the off-diagonal elements of the real-space density matrix,…

Statistical Mechanics · Physics 2007-05-23 B. Militzer , E. L. Pollock , D. M. Ceperley

Work belongs to the most basic notions in thermodynamics but it is not well understood in quantum systems, especially in open quantum systems. By introducing a novel concept of work functional along individual Feynman path, we invent a new…

Statistical Mechanics · Physics 2018-07-30 Ken Funo , H. T. Quan

The static density response of the uniform electron gas is of fundamental importance for numerous applications. Here, we employ the recently developed \textit{ab initio} permutation blocking path integral Monte Carlo (PB-PIMC) technique…

Strongly Correlated Electrons · Physics 2017-08-23 Tobias Dornheim , Simon Groth , Jan Vorberger , Michael Bonitz

Classical and path integral molecular dynamics (PIMD) simulations are used to study alpha-quartz and beta-quartz in a large range of temperatures at zero external stress. PIMD account for quantum fluctuations of atomic vibrations, which can…

Materials Science · Physics 2015-06-24 Martin H. Muser

We address the problem of heat transport in a chain of coupled quantum harmonic oscillators, exposed to the influences of local environments of various nature, stressing the effects that the specific nature of the environment has on the…

Quantum Physics · Physics 2015-04-16 F. Nicacio , A. Ferraro , A. Imparato , M. Paternostro , F. L. Semião

The Feynman path integral for the generalized harmonic oscillator is reviewed, and it is shown that the path integral can be used to find a complete set of wave functions for the oscillator. Harmonic oscillators with different…

Quantum Physics · Physics 2007-05-23 Dae-Yup Song

We introduce a new path integral Monte Carlo method for investigating nonadiabatic systems in thermal equilibrium and demonstrate an approach to reducing stochastic error. We derive a general path integral expression for the partition…

Chemical Physics · Physics 2019-07-11 Neil Raymond , Dmitri Iouchtchenko , Pierre-Nicholas Roy , Marcel Nooijen

We derive the partition function of the one-body and two-body systems of classical noncommutative harmonic oscillator in two dimensions. Then, we employ the path integral approach to the quantum noncommutative harmonic oscillator and derive…

High Energy Physics - Theory · Physics 2015-07-08 I. Jabbari , A. Jahan , Z. Riazi

Residual entropy, which reflects the degrees of freedom in a system at absolute zero temperature, is crucial for understanding quantum and classical ground states. Despite its key role in explaining low-temperature phenomena and ground…

Statistical Mechanics · Physics 2025-02-20 Zenan Dai , Xiao Yan Xu

We develop a systematic framework for the quantum and thermal properties of a Klein-Gordon scalar field subject to an inverted harmonic potential $-{1\over2} m^2\omega^2 x^2$. Starting from a non-Hermitian momentum substitution $P \to P -…

Quantum Physics · Physics 2026-05-29 Kevin Hernández

In this thesis we deal with two different topics. In the first half we investigate how the Bayesian formalism can be introduced into the problem of quantum thermometry -- a field which exploits the high level of control in coherent devices…

Quantum Physics · Physics 2023-07-20 Gabriel O. Alves

The \emph{ab initio} path integral Monte Carlo (PIMC) approach is one of the most successful methods in quantum many-body theory. A particular strength of this method is its straightforward access to imaginary-time correlation functions…

Statistical Mechanics · Physics 2021-08-25 Tobias Dornheim , Zhandos A. Moldabekov , Jan Vorberger

Convergence of path integral simulations requires a substantial number of beads when quantum effects are significant. Traditional Trotter scaling approaches estimate the continuum limit through extrapolation, however they are restricted to…

Statistical Mechanics · Physics 2024-05-28 Sabry G Moustafa

Accounting for nuclear quantum effects (NQEs) can significantly alter material properties at finite temperatures. Atomic modeling using the path-integral molecular dynamics (PIMD) method can fully account for such effects, but requires…

Materials Science · Physics 2025-05-21 A. A. Solovykh , N. E. Rybin , I. S. Novikov , A. V. Shapeev

Understanding heat transport in semiconductors and insulators is of fundamental importance because of its technological impact in electronics and renewable energy harvesting and conversion. Anharmonic Lattice Dynamics provides a powerful…

Materials Science · Physics 2020-10-13 Giuseppe Barbalinardo , Zekun Chen , Nicholas W. Lundgren , Davide Donadio

This paper investigates a new formalism to describe real time evolution of quantum systems at finite temperature. A time correlation function among subsystems will be derived which allows for a probabilistic interpretation. Our derivation…

High Energy Physics - Theory · Physics 2009-10-31 E. Mendel , M. Nest

We derive two path integral estimators for the derivative of the quantum mechanical potential of mean force (PMF), which may be numerically integrated to yield the PMF. For the first estimator, we perform the differentiation on the exact…

Chemical Physics · Physics 2021-10-08 Dmitri Iouchtchenko , Kevin P. Bishop , Pierre-Nicholas Roy

We study non-interacting fermionic systems undergoing continuous monitoring and driven by biased reservoirs. Averaging over the measurement outcomes, we derive exact formulas for the particle and heat flows in the system. We show that these…

Quantum Physics · Physics 2024-04-10 João Ferreira , Tony Jin , Jochen Mannhart , Thierry Giamarchi , Michele Filippone

The results of analytical approximations and extensive calculations based on a path integral Monte Carlo (PIMC) scheme are presented. A new (direct) PIMC method allows for a correct determination of thermodynamic properties such as energy…

Astrophysics · Physics 2007-05-23 V. Filinov , M. Bonitz , D. Kremp , W. -D. Kraeft , V. Fortov