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Proximity to phase transitions (PTs) is frequently responsible for the largest dielectric susceptibilities in ferroelectrics. The impracticality of using temperature as a control parameter to reach those large responses has motivated the…

Due to the strong lattice-property relationships which exist in complex oxide epitaxial layers, their electronic and magnetic properties can be modulated by structural distortions induced at the atomic scale. The modification and control…

Electric field control of magnetic structures, particularly topological defects in magnetoelectric materials, draws a great attention in recent years, which has led to experimental success in creation and manipulation by electric field of…

Strongly Correlated Electrons · Physics 2017-05-24 P. I. Karpov , S. I. Mukhin

We have made magnetization and x-ray diffraction measurements on an epitaxial Pb(Fe1/2Nb1/2)O3 200 nm film. From the temperature dependence of the out-of-plane lattice parameter we can assign a Burns' temperature at Td ~ 640 K, a…

Materials Science · Physics 2009-11-13 W. Peng , N. Lemée , M. Karkut , B. Dkhil , V. V. Shvartsman , P. Borisov , W. Kleemann , J. Holc , M. Kosec , R. Blinc

In hybrid improper ferroelectric systems, polarization arises from the onset of successive nonpolar lattice modes. In this work, measurements and modeling were performed to determine the spatial symmetries of the phases involved in the…

Materials Science · Physics 2019-07-03 S. Liu , H. Zhang , S. Ghose , M. Balasubramanian , Zhenxian Liu , S. G. Wang , Y-S. Chen , B. Gao , J. Kim , S. -W. Cheong , T. A. Tyson

We present a phenomenological model of periodic ferroelectric-superconductor (FE-S) heterostructures containing two alternating ferroelectric and superconducting layers. The interaction at the FE-S contacts is described as a coupling of the…

Statistical Mechanics · Physics 2007-05-23 N. Pavlenko , F. Schwabl

Flexoelectric effect impact on the generalized susceptibility and soft phonons dispersion was not studied in the long-range ordered phases of ferroics. The gap in the knowledge motivated us to establish the impact of the flexocoupling on…

Epitaxial CaMnO3 films grown with 2.3% tensile strain on (001)-oriented LaAlO3 substrates are found to be incipiently ferroelectric below 25 K. Optical second harmonic generation (SHG) was used for the detection of the incipient…

Materials Science · Physics 2015-06-05 T. Günter , E. Bousquet , A. David , Ph. Boullay , Ph. Ghosez , W. Prellier , M. Fiebig

Non-conductive materials like rubbers, plastics, ceramics, and even semiconductors have the property of flexoelectricity, which means that they can generate electricity when bent and twisted. However, an irregular shape or a peculiar load…

Applied Physics · Physics 2021-04-07 Mingyuan Zhang , Dongze Yan , Jianxiang Wang , Li-Hua Shao

Strain engineering of perovskite oxide thin films has proven to be an extremely powerful method for enhancing and inducing ferroelectric behavior. In ferroelectric thin films and superlattices, the polarization is intricately linked to…

The depolarization fields set up to due to uncompensated surface charges in a ferroelectric thin film can suppress the ferroelectric phase below a critical size. Recent experiments show that 180 degree domain structures can help to…

Materials Science · Physics 2007-05-23 Rajeev Ahluwalia , David J. Srolovitz

Ferroelectric nematic phases are a new class of polar fluids in which spontaneous polarization is directly coupled to the orientational order, providing unique opportunities for creating self-organized materils with spatially modulated…

Nonlinear electrostatic interaction between the surface ions of electrochemical nature and ferroelectric dipoles gives rise to the coupled ferroionic states in nanoscale ferroelectrics. Here, we investigated the role of the surface ions…

Cross-coupling of ordering parameters in multiferroic materials by multiple external stimuli other than electric field and magnetic field is highly desirable from both practical application and fundamental study points of view. Recently,…

Materials Science · Physics 2016-09-27 Tingting Jia , Hideo Kimura , Zhenxiang Cheng , Hongyang Zhao

Flexoelectricity is the polar response of an insulator to strain gradients such as bending. While the size dependence of this effect makes it weak in bulk systems in comparison to piezoelectricity, it suggests that it plays a bigger role in…

Mesoscale and Nanoscale Physics · Physics 2022-08-12 Daniel Bennett

We report on the crystal structure and ferroelectric properties of epitaxial ZrO$_2$ films ranging from 7 to 42 nm thickness grown on La$_{0.67}$Sr$_{0.33}$MnO$_3$-buffered (110)-oriented SrTiO$_3$ substrate. By employing X-ray diffraction,…

We studied the ferroelectric and ferromagnetic properties of compressive strained and unstrained BiMnO3 thin films grown by rf-magnetron sputtering. BiMnO3 samples exhibit a 2D cube-on-cube growth mode and a pseudo-cubic struc-ture up to a…

Materials Science · Physics 2013-06-06 G. M. De Luca , D. Preziosi , F. Chiarella , R. Di Capua , S. Gariglio , S. Lettieri , M. Salluzzo

We use numerical minimization of a model free energy functional to study the effects of columnar pinning centers on the structure and thermodynamics of a system of pancake vortices in the mixed phase of highly anisotropic layered…

Superconductivity · Physics 2009-11-07 Chandan Dasgupta , Oriol T. Valls

The existence of ferroelectricity in {$\mathrm{BiMnO}_3$} has been a long-standing question for both experimentalists and theorists. In addition to a highly distorted bulk structure, the ionic crystal planes cause a large roughness in thin…

Materials Science · Physics 2017-04-11 Yun-Peng Wang , J. N. Fry , Hai-Ping Cheng

We consider a standard Ginzburg-Landau model of a ferroelectric whose electrical polarization is coupled to gradients of elastic strain. At the harmonic level, such flexoelectric interaction is known to hybridize acoustic and optic phonon…

Materials Science · Physics 2023-07-27 G. G. Guzmán-Verri , C. H. Liang , P. B. Littlewood