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The Pauli exclusion principle is fundamental to understanding electronic quantum systems. It namely constrains the expected occupancies $n_i$ of orbitals $\varphi_i$ according to $0 \leq n_i \leq 2$. In this work, we first refine the…

The $N$-representability problem places fundamental constraints on reduced density matrices (RDMs) that originate from physical many-fermion quantum states. Motivated by recent developments in functional theories, we introduce a hierarchy…

Quantum Physics · Physics 2026-04-28 Julia Liebert , Anna O. Schouten , Irma Avdic , Christian Schilling , David A. Mazziotti

The Pauli exclusion principle requires the spectrum of the occupation numbers of the one-electron reduced density matrix (1-RDM) to be bounded by one and zero. However, for a 1-RDM from a wave function, there exist additional conditions on…

Chemical Physics · Physics 2014-04-22 Romit Chakraborty , David A. Mazziotti

Motivated by the Penrose-Onsager criterion for Bose-Einstein condensation we propose a functional theory for targeting low-lying excitation energies of bosonic quantum systems through the one-particle picture. For this, we employ an…

Quantum Physics · Physics 2023-01-26 Julia Liebert , Christian Schilling

Functionals of the one-body reduced density matrix (1-RDM) are routinely minimized under Coleman's ensemble $N$-representability conditions. Recently, the topic of pure-state $N$-representability conditions, also known as generalized Pauli…

Chemical Physics · Physics 2015-05-05 Iris Theophilou , Nektarios N. Lathiotakis , Miguel A. L. Marques , Nicole Helbig

Lately, there has been a renewed interest in fermionic 1-body reduced density matrices and their restrictions beyond the Pauli principle. These restrictions are usually quantified using the polytope of allowed, ordered eigenvalues of such…

Quantum Physics · Physics 2024-06-19 Robin Reuvers

The question of whether given density operators for subsystems of a multipartite quantum system are compatible to one common total density operator is known as the quantum marginal problem. We briefly review the solution of a subclass of…

Quantum Physics · Physics 2014-04-07 Christian Schilling

The pseudo--spectral decomposition of an $N$--particle antisymmetric 1--body positive--semidefinite operator that corresponds to the canonical convex decomposition into the extreme elements of the dual cone of the set of fermion…

Quantum Physics · Physics 2009-10-28 Hubert Grudzinski

A representation of polymer self-consistent field theory equivalent to quantum density functional theory is given in terms of non-orthogonal basis sets. Molecular integrals and self-consistent equations for spherically symmetric systems…

Atomic Physics · Physics 2026-02-05 Phil A. LeMaitre , Russell B. Thompson

Postulated by Pauli to explain the electronic structure of atoms and molecules, the exclusion principle establishes an upper bound of 1 for the fermionic natural occupation numbers $\{n_i\}$. A recent analysis of the pure…

Quantum Physics · Physics 2015-07-17 Carlos L. Benavides-Riveros , Michael Springborg

We have found a (dense) basis for the N-representable, two-electron densities, in which all N-representable two-electron densities can be expanded, using positive coefficients. The inverse problem of finding a representative wavefunction,…

Strongly Correlated Electrons · Physics 2009-11-10 Mats-Erik Pistol

The exact nonequilibrium time evolution of the momentum distribution for a finite many particle system in one dimension with a linear energy dispersion coupled to optical phonons is presented. For distinguishable particles the influence…

Condensed Matter · Physics 2007-05-23 K. Schoenhammer , C. Woehler

Polytopes are the basic finite data structures for convex sets: they appear as feasible regions in linear optimization, as geometric summaries in algorithms, and as random objects in stochastic geometry. A natural geometric question is…

Metric Geometry · Mathematics 2026-03-10 Steven Hoehner

We develop a thermodynamical model of fermionic dark matter halos at finite temperature. Statistical equilibrium states may be justified by a process of violent collisionless relaxation in the sense of Lynden-Bell or from a collisional…

General Relativity and Quantum Cosmology · Physics 2022-09-07 Pierre-Henri Chavanis

The classical and quantum representations of thermal equilibrium are strikingly different, even for free, non-interacting particles. While the first involves particles with well-defined positions and momenta, the second usually involves…

Quantum Physics · Physics 2019-01-03 Aurélia Chenu , Agata M. Brańczyk , John E. Sipe

In this article we discuss the accuracy of effective one-dimensional theories used to describe the behavior of ultracold atomic ensembles confined in quantum wires by a harmonic trap. We derive within a fully many-body approach the…

Quantum Gases · Physics 2023-05-03 F Chevy , G Orso

Confined quantum systems involving $N$ identical interacting fermions are found in many areas of physics, including condensed matter, atomic, nuclear and chemical physics. In a previous series of papers, a manybody perturbation method that…

Quantum Physics · Physics 2015-06-18 D. K. Watson

Polymer self-consistent field theory techniques are used to find radial electron densities and total binding energies for isolated atoms. Quantum particles are modelled as Gaussian threads with ring-polymer architecture in a four…

Quantum Physics · Physics 2022-11-30 Russell B. Thompson

Traditional statistical mechanics is constrained by the binary paradigms of identical/distinguishable and bosonic/fermionic particle statistics, leading to a fundamental logical gap in describing systems with partial distinguishability. We…

Statistical Mechanics · Physics 2026-01-21 Wang Hao , Meng Yancen , Zhang Kuang , Zhou Rui'en

We demonstrate how the generalized Pauli exclusion principle emerges for quasiparticle excitations in 2d topological phases. As an example, we examine the Levin-Wen model with the Fibonacci data (specified in the text), and construct the…

Strongly Correlated Electrons · Physics 2014-04-23 Yuting Hu , Spencer D. Stirling , Yong-Shi Wu
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