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The coherent two-dimensional (2D) electronic spectra with respect to the singlet fission (SF) process in organic molecular aggregates are simulated by the Davydov ansatz combined with the Frenkel-Dirac time-dependent variational algorithm.…

Mesoscale and Nanoscale Physics · Physics 2018-01-17 Ke-Wei Sun , Yao Yao

Singlet fission, the molecular process through which photons are effectively converted into pairs of lower energy triplet excitons, holds promise as a means of boosting photovoltaic device efficiencies. In the preceding article of this…

Materials Science · Physics 2017-05-12 Roel Tempelaar , David R. Reichman

Helical structures like alpha helices, DNA, and microtubules have profound importance in biology. It has been suggested that these periodic arrangements of constituent units could support collective excitations similarly to crystalline…

Optics · Physics 2021-02-24 Asaf Farhi , Aristide Dogariu

Advances in light sources and time resolved spectroscopy have made it possible to excite specific atomic vibrations in solids and to observe the resulting changes in electronic properties but the mechanism by which phonon excitation causes…

Superconductivity · Physics 2017-05-05 Dante M. Kennes , Eli Y. Wilner , David R. Reichman , Andrew J. Millis

The electrical response of two-dimensional electron gas to vibrations of a nanomechanical cantilever containing it is studied. Vibrations of perpendicularly oriented cantilevers are experimentally shown to change oppositely the conductivity…

Mesoscale and Nanoscale Physics · Physics 2016-08-03 A. A. Shevyrin , A. G. Pogosov , A. K. Bakarov , A. A. Shklyaev

We consider how electron-phonon interaction influences the insulator-metal transitions driven by doping in the strongly correlated system. Using the polaronic version of the generalized tight-binding method, we investigate a multiband…

Strongly Correlated Electrons · Physics 2021-11-09 E. I. Shneyder , M. V. Zotova , S. V. Nikolaev , S. G. Ovchinnikov

We study the hopping mechanism of the vibron excitation transport in the simple 1D model of biological macromolecular chains. We supposed that the vibron interaction with thermal oscillations of the macromolecular structural elements will…

Mesoscale and Nanoscale Physics · Physics 2014-12-17 D. Čevizović , Z. Ivic. , S. Galović , A. Chizhov A. , A. Reshetnyak

The strength of the electron-phonon coupling parameter and its evolution throughout a solid's phase diagram often determines phenomena such as superconductivity, charge- and spin-density waves. Its experimental determination relies on the…

Intensity enhancement in vibrational circular dichroism (VCD) arises in open-shell transition metal complexes from coupling between ground-state vibrational transitions and magnetic dipole-allowed transitions to low-lying excited states…

Chemical Physics · Physics 2025-07-08 Mariia Sapova , Chandan Kumar , Sahar Ashtari-Jafari , Wybren J. Buma , Lucas Visscher

We calculate the effect of electron-vibration coupling on conduction through atomic gold wires, which was measured in the experiments of Agra\"it et al. [Phys. Rev. Lett. 88, 216803 (2002)]. The vibrational modes, the coupling constants,…

Mesoscale and Nanoscale Physics · Physics 2009-05-24 J. K. Viljas , J. C. Cuevas , F. Pauly , M. Häfner

The spectral properties of itinerant 2D systems with (nearly) ferromagnetic ground state are studied within the spin-fermion and the classical s-d exchange models. While the former model describes the effect of collective magnetic…

Strongly Correlated Electrons · Physics 2009-11-11 A. A. Katanin , V. Yu. Irkhin

The two-dimensional Su-Schrieffer-Heeger model of electrons coupled to quantum phonons is investigated using Langevin dynamics within the framework of auxiliary-field quantum Monte Carlo. Based on an explicit determination of the density of…

Strongly Correlated Electrons · Physics 2022-04-12 Anika Götz , Stefan Beyl , Martin Hohenadler , Fakher F. Assaad

We investigate the entanglement between electronic and vibrational degrees of freedom produced by a vibronic coupling in a molecular system described in the Born-Oppenheimer approximation. Entanglement in a pure state of the Hilbert space…

Quantum Physics · Physics 2014-03-05 Mihaela Vatasescu

We demonstrate that the coupling of excitonic and vibrational motion in biological complexes can provide mechanisms to explain the long-lived oscillations that have been obtained in non linear spectroscopic signals of different…

Chemical Physics · Physics 2015-06-17 M. B. Plenio , J. Almeida , S. F. Huelga

A model to describe electronic correlations in energy bands is considered. The model is a generalization of the conventional Hubbard model that allows for the fact that the wavefunction for two electrons occupying the same Wannier orbital…

Strongly Correlated Electrons · Physics 2009-11-07 J. E. Hirsch

Strongly-coupled quantum dot molecules (QDMs) are widely deployed in the design of a variety of optoelectronic, photovoltaic, and quantum information devices. An efficient and optimized performance of these devices demands engineering of…

Mesoscale and Nanoscale Physics · Physics 2015-10-28 Muhammad Usman

Looking for superconductors with higher transition temperature requires a guiding principle. In conventional superconductors, electrons pair up into Cooper pairs via the retarded attraction mediated by electron-phonon coupling.…

Strongly Correlated Electrons · Physics 2015-11-11 Da Wang , Wan-Sheng Wang , Qiang-Hua Wang

Synchronisation is a collective phenomenon widely investigated in classical oscillators and, more recently, in quantum systems. However, it remains unclear what features distinguish synchronous behaviour in these two scenarios. Recent works…

Quantum Physics · Physics 2019-07-19 Stefan Siwiak-Jaszek , Alexandra Olaya-Castro

Vibrational nonequilibrium effects in charge transport through single-molecule junctions are investigated. Focusing on molecular bridges with multiple electronic states, it is shown that electronic-vibrational coupling triggers a variety of…

Mesoscale and Nanoscale Physics · Physics 2011-03-15 R. Härtle , C. Benesch , M. Thoss

Following the observation of coherent oscillations in non-linear spectra of photosynthetic pigment protein complexes, particularly phycobilliprotein such as PC645, coherent vibronic transport has been suggested as a design principle for…