Related papers: Vibronic coupling in energy transfer dynamics and …
Interaction of an electron system with a strong electromagnetic wave leads to rearrangement both the electron and vibrational energy spectra of a dissipative system. For instance, the optically coupled electron levels become split in the…
This is the first in a series of two papers investigating the effect of electron-phonon coupling in two-dimensional Fourier transformed electronic spectroscopy. We present a series of one- and two-dimensional nonlinear spectroscopic…
The vibronic coupling effect in nitrogen 1s X-ray photoelectron spectra (XPS) was systematically studied for a family of 17 bicyclic indole molecules by combining Franck-Condon simulations (including the Duschinsky rotation effect) and…
Vacuum fluctuations fundamentally affect an atom by inducing a finite excited state lifetime along with a Lamb shift of its transition frequency. Here we report the reverse effect: modification of vacuum modes by a single atom in circuit…
The frequency dependence of dynamical conductivity of the quasi-one-dimensional structures with hydrogen bonds is studied on the basis of pseudospin-electron model. It takes into account the proton-electron interaction, external…
The spontaneous generation of charge-density-wave order in a Dirac fermion system via the natural mechanism of electron-phonon coupling is studied in the framework of the Holstein model on the honeycomb lattice. Using two independent and…
In single vibronic level (SVL) fluorescence experiments, the electronically excited initial state is also excited in one or several vibrational modes. Whereas computing all contributing Franck-Condon factors individually becomes impractical…
We theoretically analyzed inelastic effects in the electron transport through molecular junctions originating from electron-vibron interactions. The molecular bridge was simulated by a periodic chain of identical interacting hydrogen-like…
The strong coupling effect in the (2+1)-dimensional quantum electrodynamics (QED_3) description of the $S=1/2$ Heisenberg antiferromagnet is studied in terms of a canonical transformation which has been used in the small polaron theory in…
The ultrafast dynamics of charge carriers in organic donor-acceptor interfaces are of primary importance to understanding the fundamental properties of these systems. In this work, we focus on a charge-transfer complex formed by…
Optimizing energy and charge transport is key in design and implementation of efficient two-dimensional (2D) conductive metal-organic frameworks (MOFs) for practical applications. In this work, for the first time, we investigate the role of…
We propose a simple Hamiltonian to describe the motion and the merging of Dirac points in the electronic spectrum of two-dimensional electrons. This merging is a topological transition which separates a semi-metallic phase with two Dirac…
In this paper we analyse the mechanisms responsible for the bonding of electrons to metal surfaces. We present and validate a method to measure the energy distribution of dense electron ensembles at ambient conditions. We have found sharp…
We develop a theoretical approach to study the transient dynamics and the time-dependent statistics for the Anderson-Holstein model in the regime of strong electron-phonon coupling. For this purpose we adapt a recently introduced…
We consider a fully quadratic vibronic model Hamiltonian for studying photoinduced electronic transitions through conical intersections. Using a second order perturbative approximation for diabatic couplings we derive an analytical…
Using a controlled analytic non-perturbative treatment, that accounts for the quantum nature of the phonons, we derive a model that generically describes cooperative breathing-mode at strong electron-phonon interaction in one-band…
The interaction between electronic and vibrational degrees of freedom in single-molecule junctions may result from the dependence of the electronic energies or the electronic states of the molecular bridge on the nuclear displacement. The…
Optical properties of symmetry-forbidden pi-pi transitions in benzene are calculated with the time-dependent density functional theory (TDDFT), using an adiabatic LDA functional. Quantities calculated are the envelopes of the Franck-Condon…
Electron coupling to intra- and inter-molecular vibrational modes is investigated in models appropriate to single crystal organic semiconductors, such as oligoacenes. Focus is on spectral and transport properties of these systems beyond…
We theoretically examine the effect of the coupling of the transport electrons to a vibrational mode of the molecule on the ac linear-response conductance of molecular junctions. Representing the molecule by a single electronic state, we…