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Friction at water-carbon interfaces remains a major puzzle with theories and simulations unable to explain experimental trends in nanoscale waterflow. A recent theoretical framework -- quantum friction (QF)-- proposes to resolve these…

Soft Condensed Matter · Physics 2023-01-10 Anna T. Bui , Fabian L. Thiemann , Angelos Michaelides , Stephen J. Cox

The interface between a liquid and a solid is the location of plethora of intrincate mechanisms at the nanoscale, at the root of their specific emerging properties in natural processes or technological applications. However, while the…

Water-flow in carbon nanotubes (CNT's) starkly contradicts classical fluid mechanics, with permeabilities that can exceed no-slip Haagen-Poiseuille predictions by two to five orders of magnitude. Semi-classical molecular dynamics accounts…

Materials Science · Physics 2022-07-27 Alberto Ambrosetti , Giorgio Palermo , Pier Luigi Silvestrelli

A simple model for the friction experienced by the one dimensional water chains that flow through subnanometer diameter carbon nanotubes is studied. The model is based on a lowest order perturbation theory treatment of the friction…

Fluid Dynamics · Physics 2023-05-17 J. B. Sokoloff , A. W. C. Lau

Experimental measurements have reported ultra-fast and radius-dependent water transport in carbon nanotubes which are absent in boron nitride nanotubes. Despite considerable effort, the origin of this contrasting (and fascinating) behaviour…

Materials Science · Physics 2022-02-11 Fabian L Thiemann , Christoph Schran , Patrick Rowe , Erich A Müller , Angelos Michaelides

Nanoscale fluid transport is typically pictured in terms of atomic-scale dynamics, as is natural in the real-space framework of molecular simulations. An alternative Fourier-space picture, that involves the collective charge fluctuation…

Mesoscale and Nanoscale Physics · Physics 2023-10-02 Baptiste Coquinot , Maximilian Becker , Roland R. Netz , Lydéric Bocquet , Nikita Kavokine

Quantum friction describes the transfer of energy and momentum from electronically excited states in a material to a surrounding solvent. Here, we show that near-infrared (NIR) fluorescent single-walled carbon nanotubes (SWCNTs) exhibit…

Friction is one of the main sources of dissipation at liquid water/solid interfaces. Despite recent progress, a detailed understanding of water/solid friction in connection with the structure and energetics of the solid surface is lacking.…

Mesoscale and Nanoscale Physics · Physics 2015-03-19 Gabriele Tocci , Laurent Joly , Angelos Michaelides

We compared the diffusion of water confined in armchair and zigzag carbon nanotubes for rigid and flexible water models. Using one rigid model, TIP4P/2005, and two flexible models, SPC/Fw and SPC/FH, we found that the number of the number…

Measurements of the surface diffusivity of colloidal spheres translating along a vapor/liquid inter- face show an unexpected decrease in diffusivity, or increase in surface drag (from the Stokes-Einstein relation) when the particles situate…

Soft Condensed Matter · Physics 2016-07-08 Joel Koplik , Charles Maldarelli

In this study, using non-equilibrium molecular dynamics simulation, the flow of water in deformed carbon nanotubes is studied for two water models TIP4P/2005 and SPC/FH. The results demonstrated a non-uniform dependence of the flow on the…

Evidence is accumulating for the crucial role of a solid's free electrons in the dynamics of solid-liquid interfaces. Liquids induce electronic polarization and drive electric currents as they flow; electronic excitations, in turn,…

Mesoscale and Nanoscale Physics · Physics 2023-06-27 Xiaoqing Yu , Alessandro Principi , Klaas-Jan Tielrooij , Mischa Bonn , Nikita Kavokine

The physics of dynamic friction on water molecule contaminated surfaces is still poorly understood. In line with the growing interest in hydrophobic contact for industrial applications, this paper focuses on friction mechanisms in such…

Soft Condensed Matter · Physics 2022-06-24 Olivier Noël , Pierre-Emmanuel Mazeran , Igor Stanković

Recent experiments of fluid transport in nano-channels have shown evidence of a coupling between charge-fluctuations in polar fluids and electronic excitations in graphene solids, which may lead to a significant reduction of friction a…

Mesoscale and Nanoscale Physics · Physics 2025-03-30 S. Succi , M. Lauricella , A. Tiribocchi

An electronic current driven through a conductor can induce a current in another conductor through the famous Coulomb drag effect. Similar phenomena have been reported at the interface between a moving fluid and a conductor, but their…

Mesoscale and Nanoscale Physics · Physics 2024-03-27 Baptiste Coquinot , Lydéric Bocquet , Nikita Kavokine

The world of nanoscales in fluidics is the frontier where the continuum of fluid mechanics meets the atomic, and even quantum, nature of matter. While water dynamics remains largely classical under extreme confinement, several experiments…

Mesoscale and Nanoscale Physics · Physics 2025-01-03 Baptiste Coquinot , Anna T. Bui , Damien Toquer , Angelos Michaelides , Nikita Kavokine , Stephen J. Cox , Lydéric Bocquet

Interfacial friction in nanofluidic systems can arise from fluctuation-induced coupling between liquid charge fluctuations and the internal excitations of the confining solid. Here, we develop a microscopic theory of exciton-mediated…

Mesoscale and Nanoscale Physics · Physics 2026-05-11 Timur Pryadilin , Alexey Kavokin , Baptiste Coquinot

Water inside a nanocapillary becomes ordered, resulting in unconventional behavior. A profound enhancement of water flow inside nanometer thin capillaries made of graphene has been observed [B. Radha et.al., Nature (London) 538, 222…

Soft Condensed Matter · Physics 2018-09-05 M. Neek-Amal , A. Lohrasebi , M. Mousaei , F. Shayeganfar , B. Radha , F. M. Peeters

We introduce new classes of hydrodynamic theories inspired by the recently discovered fracton phases of quantum matter. Fracton phases are characterized by elementary excitations (fractons) with restricted mobility. The hydrodynamic…

Strongly Correlated Electrons · Physics 2020-07-29 Andrey Gromov , Andrew Lucas , Rahul M. Nandkishore

Hydrophobic solid-water interfaces underpin processes in nanofluidics, electrochemistry, and energy technologies. Microscopic insights into these systems are often inferred from our understanding of the air-water interface, which is assumed…

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