Related papers: Chiral Plasmonic Hydrogen Sensors
Anisotropic nanostructured porous Pd films are fabricated using oblique angle deposition in vacuum on a glass substrate. They display a dichroic response, due to localised surface plasmon resonances (LSPR) within the nanoparticles forming…
Here we demonstrate the gas sensing ability of cavity-coupled metallic nanoparticle systems, comprising gold nanoparticles separated from a gold mirror with a polymer spacer. An increase in relative humidity (RH) causes the spacer to…
The detection and discrimination of molecular chirality are essential for advancing pharmaceutical and biological applications. While nanophotonic platforms offer a route to enhance chiral light-matter interactions, existing device concepts…
Chiral sensitive techniques have been used to probe the fundamental symmetries of the universe, study biomolecular structures, and even develop safe drugs. As chiral signals are inherently weak and often suppressed by large backgrounds,…
In this thesis, we propose to tackle this important issue by designing and realizing a novel nano-optical device based on the use of a photonic crystal (PC) structure to generate an efficient coupling between the external source and a NA.…
Chiroptical enantioselective sensing is gaining traction across various applications. However, intrinsic molecular chiroptical responses are weak, and existing amplification approaches add synthesis, manufacturing, or operational complexity…
Hydrogen arranges at dislocations in palladium to form nanoscale hydrides, changing the vibrational spectra. An ab initio hydrogen potential energy model versus Pd neighbor distances allows us to predict the vibrational excitations for H…
Hydrogen detection in a reliable, fast, and cost-effective manner is a prerequisite for the large-scale implementation of hydrogen in a green economy. We present thin film Ta$_{1-y}$Pd$_y$ as effective optical sensing materials with…
Chirality, the property of asymmetry, is of great importance in biological and physical phenomena. This prospective offers an overview of the emerging field of chiral bioinspired plasmonics and metamaterials, aiming to uncover nature's…
Pd nanoalloys show great potential as hysteresis-free, reliable hydrogen sensors. Here, a multi-scale modeling approach is employed to determine optimal conditions for optical hydrogen sensing using the Pd-Au-H system. Changes in hydrogen…
The possibility of creating and manipulating nanostructured materials encouraged the exploration of new strategies to control electromagnetic properties. Among the most intriguing nanostructures are those that respond differently to helical…
Dark-field illumination is shown to make planar chiral nanoparticle arrangements exhibit circular dichroism in extinction analogous to true chiral scatterers. Circular dichrosim is experimentally observed at the maximum scattering of single…
Chiral photonics aims to control and engineer light handedness for many applications in optical communications, biological and chemical sensing, and quantum technologies. While traditional approaches focus on engineering strong linear…
While plasmonic particles can provide optical resonances in a wide spectral range from the lower visible up to the near-infrared, often symmetry effects are utilized to obtain particular optical responses. By breaking certain spatial…
Over the past two decades, metamaterials have led to an increasing number of biosensing and nanophotonic applications due to the possibility of a careful control of light propagating through subwavelength features. Chiral nanostructures…
The ability to measure weak signals such as pressure, force, electric field, and temperature with nanoscale devices and high spatial resolution offers a wide range of applications in fundamental and applied sciences. Here we present a…
Molecular chirality is a geometric property that is of great importance in chemistry, biology, and medicine. Recently, plasmonic nanostructures that exhibit distinct chiroptical responses have attracted tremendous interest, given their…
Plasmonic double helical antennas are a means to funnel circularly polarized light down to the nanoscale. Here, an existing design tool for single helices is extended to the case of double helices and used to design antennas that combine…
Nanoporous gold can be exploited as plasmonic material for enhanced spectroscopy both in the visible and in the near infrared spectral regions. In particular, with respect to bulk metal it presents interesting optical properties in the…
Adsorption in nanoporous materials is one strategy that can be used to store hydrogen at conditions of temperature and pressure that are economically viable. Adsorption capacity of nanoporous materials depends on surface area which can be…