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The interaction between dust, ice, and gas during the formation of stars produces complex organic molecules. While observations indicate that several species are formed on ice-covered dust grains and are released into the gas phase, the…

Solar and Stellar Astrophysics · Physics 2020-11-04 G. Perotti , W. R. M. Rocha , J. K. Jørgensen , L. E. Kristensen , H. J. Fraser , K. M. Pontoppidan

During the journey from the cloud to the disc, the chemical composition of the protostellar envelope material can be either preserved or processed to varying degrees depending on the surrounding physical environment. This works aims to…

A rich inventory of complex organic molecules (COMs) has been observed in high abundances in the gas phase toward Class 0 protostars. These molecules are suggested to be formed in ices and sublimate in the warm inner envelope close to the…

Context. The molecular composition of interstellar ice mantles is defined by gas-grain processes in molecular clouds, with the main components being $H_2O$, $CO$, and $CO_2$. $CH_3OH$ ice is detected towards the denser regions, where large…

Astrophysics of Galaxies · Physics 2021-08-25 B. Müller , B. M. Giuliano , M. Goto , P. Caselli

We investigate the formation and evolution of interstellar dust-grain ices under dark-cloud conditions, with a particular emphasis on CO2. We use a three-phase model (gas/surface/mantle) to simulate the coupled gas--grain chemistry,…

Astrophysics of Galaxies · Physics 2015-05-28 Robin T. Garrod , Tyler Pauly

Up to 90% of the chemical reactions during star formation occurs on ice surfaces, probably including the formation of complex organics. Only the most abundant ice species are however observed directly by infrared spectroscopy. This study…

Solar and Stellar Astrophysics · Physics 2015-05-13 Karin I. Oberg , Sandrine Bottinelli , Ewine F. van Dishoeck

Gas-phase complex organic molecules have been detected toward a range of high- and low-mass star-forming regions at abundances which cannot be explained by any known gas-phase chemistry. Recent laboratory experiments show that UV…

Astrophysics of Galaxies · Physics 2015-05-18 Karin I. Oberg , Sandrine Bottinelli , Jes K. Jorgensen , Ewine F. van Dishoeck

Methane is one of the simplest stable molecules that is both abundant and widely distributed across space. It is thought to have partial origin from interstellar molecular clouds, which are near the beginning of the star formation cycle.…

Solar and Stellar Astrophysics · Physics 2020-04-16 D. Qasim , G. Fedoseev , K. -J. Chuang , J. He , S. Ioppolo , E. F. van Dishoeck , H. Linnartz

Using the Planck far-infrared and Arecibo GALFA 21-cm line surveys, we identified a set of isolated interstellar clouds (approximately degree-sized on the sky and comprising 100 solar masses) and assessed the ratio of gas mass to dust mass.…

Astrophysics of Galaxies · Physics 2015-10-07 William T. Reach , Carl Heiles , Jean-Philippe Bernard

We investigate the chemical history of interstellar OCS and SO2 by deriving a statistically-significant sample of gas-phase column densities towards massive protostars and comparing to observations of gas and ices towards other sources…

Astrophysics of Galaxies · Physics 2024-09-25 Julia C. Santos , Martijn L. van Gelder , Pooneh Nazari , Aida Ahmadi , Ewine F. van Dishoeck

Nitrogen-bearing complex organic molecules have been commonly detected in the gas phase but not yet in interstellar ices. This has led to the long-standing question of whether these molecules form in the gas phase or in ices. $\textit{James…

The formation of methanol (CH3OH) on icy grain mantles during the star formation cycle is mainly associated with the CO freeze-out stage. Yet there are reasons to believe that CH3OH also can form at an earlier period of interstellar ice…

Astrophysics of Galaxies · Physics 2018-05-02 D. Qasim , K. -J. Chuang , G. Fedoseev , S. Ioppolo , A. C. A. Boogert , H. Linnartz

Water and methanol are key components of interstellar ices and gas in star- and planet-forming regions, but direct observations of water in low-mass protostars are challenging due to atmospheric absorption. We present high-resolution (R =…

Currently ~36 different absorption bands have been detected in the infrared spectra of cold, dense interstellar and circumstellar environments. These are attributed to the vibrational transitions of ~17 different molecules frozen on dust…

Astrophysics · Physics 2007-05-23 A. C. A. Boogert , P. Ehrenfreund

Context. The formation and destruction of molecules in the interstellar medium is a complex interplay between gas-phase reactions as well as processes on grain surfaces and within icy mantles. For many decades, the gas-phase composition of…

Whether ice in cold cosmic environments is physically separated from the silicate dust or mixed with individual silicate moieties is not known. However, different grain models give very different compositions and temperatures of grains. The…

Astrophysics of Galaxies · Physics 2020-08-26 Alexey Potapov , Jeroen Bouwman , Cornelia Jäger , Thomas Henning

Since most high- and intermediate-mass protostars are at great distance and form in clusters, high linear resolution observations are needed to investigate their physical properties. To study the gas in the innermost region around the…

Astrophysics · Physics 2009-11-13 S. Leurini , H. Beuther , P. Schilke , F. Wyrowski , Q. Zhang , K. M. Menten

Ice is ubiquitous in the interstellar medium. We model the formation of the main constituents of interstellar ices, including H2O, CO2 , CO, and CH3 OH. We strive to understand what physical or chemical parameters influence the final…

Astrophysics of Galaxies · Physics 2023-07-26 A. Clément , A. Taillard , V. Wakelam , P. Gratier , J. -C. Loison , E. Dartois , F. Dulieu , J. A. Noble , M. Chabot

In the last years, ultra-low temperature chemical kinetic experiments have demonstrated that some gas-phase reactions are much faster than previously thought. One example is the reaction between OH and CH3OH, which has been recently found…

Astrophysics of Galaxies · Physics 2016-05-25 M. Antinolo , M. Agundez , E. Jimenez , B. Ballesteros , A. Canosa , G. El Dib , J. Albaladejo , J. Cernicharo

Context. High latitude molecular clouds (hereafter HLMCs) permit the study of interstellar gas dynamics and astrochemistry with good accuracy due to their proximity, generally clear lines of sight, and lack of internal star-forming activity…

Astrophysics of Galaxies · Physics 2023-01-16 Marco Monaci , Loris Magnani , Steven N. Shore
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