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We use stochastic rotation dynamics to examine the dynamics of the ejection of an initially strongly confined flexible polymer from a spherical capsid with and without hydrodynamics. The results obtained using SRD are compared to similar…

Biological Physics · Physics 2017-06-07 Joonas Piili , Pauli M. Suhonen , Riku P. Linna

This study focuses on comparing the individual polymer chain dynamics in an entangled polymeric liquid under different shear and extension rates. Polymer chains under various shear rates and extension rates were simulated using a…

Chemical Physics · Physics 2021-01-15 Behrouz Behdani , Tong Mou , Cody Spratt , Slava Butcovich , Ryan Gettler , Joontaek Park

We present exact and analytically accurate results for the problem of a flexible polymer chain in shear flow. Under such a flow the polymer tumbles, and the probability distribution of the tumbling times $\tau$ of the polymer decays…

Statistical Mechanics · Physics 2008-11-13 Dibyendu Das , Sanjib Sabhapandit

In this paper, we construct an effective model for the dynamics of an excluded-volume chain under confinement, by extending the formalism of Rouse modes. We make specific predictions about the behavior of the modes for a single polymer…

Soft Condensed Matter · Physics 2009-09-29 Joshua Kalb , Bulbul Chakraborty

We consider a continuum model of active viscoelastic matter, whereby an active nematic liquid-crystal is coupled to a minimal model of polymer dynamics with a viscoelastic relaxation time $\tau_C$. To explore the resulting interplay between…

Soft Condensed Matter · Physics 2016-03-30 E. J. Hemingway , M. E. Cates , S. M. Fielding

We show the presence of both a minimum and clear oscillations in the frequency dependence of the translocation time of a polymer described as a unidimensional Rouse chain driven by a spatially localized oscillating linear potential. The…

Soft Condensed Matter · Physics 2010-09-16 Alessandro Fiasconaro , Juan José Mazo , Fernando Falo

The research is important for a molecular theory of liquid and has a wide interest as an example solving the problem when dynamic parameters of systems can be indirectly connected with their equilibrium properties. In frameworks of the…

Statistical Mechanics · Physics 2007-05-23 Andrei N. Yakunin

The hydrodynamic radius of a polymer chain, obtained using Brownian dynamics simulations of the continuum Edwards model, is found to obey a crossover in the excluded volume parameter z, which is significantly different from that observed…

Soft Condensed Matter · Physics 2020-07-03 P. Sunthar , J. Ravi Prakash

We present a unified scaling theory for the dynamics of monomers for dilute solutions of semiflexible polymers under good solvent conditions in the free draining limit. Our theory encompasses the well-known regimes of mean square…

Soft Condensed Matter · Physics 2015-06-17 Aiqun Huang , Ramesh Adhikari , Aniket Bhattacharya , Kurt Binder

It is shown that the traditionally accepted "Rouse values" for the critical exponents at the gelation transition do not arise from the Rouse model for gelling polymers. The true critical behaviour of the Rouse model for gelling polymers is…

Statistical Mechanics · Physics 2007-05-23 Peter Müller

Dynamics of a discrete polymer in time-dependent external potentials is studied with the master equation approach. We consider both stochastic and deterministic switching mechanisms for the potential states and give the essential equations…

Statistical Mechanics · Physics 2008-06-25 Janne Kauttonen , Juha Merikoski , Otto Pulkkinen

Freezing of polymer solutions has been extensively investigated from many aspects, especially the complex pattern formation. The cell/dendrite micro-structures are believed to be in the type of diffusion-induced M-S instability. However,…

Soft Condensed Matter · Physics 2020-12-22 Tongxin Zhang , Zhijun Wang , Lilin Wang , Junjie Li , Jincheng Wang

Ring polymers remain a major challenge to our current understanding of polymer dynamics. Experimental results are difficult to interpret because of the uncertainty in the purity and dispersity of the sample. Using both equilibrium and…

Soft Condensed Matter · Physics 2015-06-03 Jonathan D. Halverson , Gary S. Grest , Alexander Y. Grosberg , Kurt Kremer

We study the dynamics of a tagged monomer of a Rouse polymer for different initial configurations. In the case of free evolution, the monomer displays subdiffusive behavior with strong memory of the initial state. In presence of either…

Statistical Mechanics · Physics 2013-12-03 Shamik Gupta , Alberto Rosso , Christophe Texier

We analyze the stress tensor and the gyration tensor of an unentangled polymer melt under flow by using a Rouse-type single chain model. We employ the bead-spring type single chain model, in which beads interact each other via nonlinear…

Soft Condensed Matter · Physics 2025-06-30 Takashi Uneyama

Many glass-forming fluids exhibit a remarkable thermodynamic scaling in which dynamic properties, such as the viscosity, the relaxation time, and the diffusion constant, can be described under different thermodynamic conditions in terms of…

Soft Condensed Matter · Physics 2015-06-16 Wen-Sheng Xu , Karl F. Freed

We consider a polymer of length $N$ translocating through a narrow pore in the absence of external fields. Characterization of its purportedly anomalous dynamics has so far remained incomplete. We show that the polymer dynamics is anomalous…

Soft Condensed Matter · Physics 2007-10-08 Debabrata Panja , Gerard T. Barkema , Robin C. Ball

By means of Brownian dynamics simulations we study the steady-state dynamic properties of a flexible active polymer in a poor solvent condition. Our results show that the effective diffusion constant of the polymer $D_{\rm eff}$ gets…

Soft Condensed Matter · Physics 2023-08-29 Suman Majumder , Subhajit Paul , Wolfhard Janke

We investigate the nature of the effective dynamics and statistical forces obtained after integrating out nonequilibrium degrees of freedom. To be explicit, we consider the Rouse model for the conformational dynamics of an ideal polymer…

Statistical Mechanics · Physics 2015-06-11 Christian Maes , Simi R. Thomas

Here we report the linear viscoelastic properties of amorphous poly(tetramethylene oxide) (PTMO), which is one of the key components in synthesizing segmented polyurethane (PU) elastomers. The temperature and molecular weight dependent…

Soft Condensed Matter · Physics 2022-02-21 Zakiya Shireen , Elnaz Hajizadeh , Peter Daivis , Christian Brandl