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A study of the STEM probe channeling in a heterostructures crystalline specimen is presented here with a goal to guide appropriate STEM-based characterization for complex structures. STEM analysis of perovskite BaSnO3/LaAlO3 bilayers is…

Materials Science · Physics 2019-11-12 Hwanhui Yun , Abhinav Prakash , Bharat Jalan , Jong Seok Jeong , K. Andre Mkhoyan

We have investigated the temperature-dependent changes in the near-$E$$_F$ occupied and unoccupied states of Pr$_{0.67}$Ca$_{0.33}$MnO$_3$ which shows the presence of ferromagnetic and antiferromagnetic phases. The temperature-dependent…

Strongly Correlated Electrons · Physics 2009-11-11 M. K. Dalai , P. Pal , B. R. Sekhar , N. L. Saini , R. K. Singhal , K. B. Garg , B. Doyle , S. Nannarone , C. Martin , F. Studer

Electron microdiffraction study of phase transition in La2/3Ca1/3MnO3 revealed temperature dependent (h+1/2,0,l) diffraction spots. Their intensity peaks at Tc. Quantitative electron diffraction intensity analysis shows that they come from…

Strongly Correlated Electrons · Physics 2009-10-31 J. M. Zuo , J. Tao

We present results of our study of polarized Raman scattering and infrared reflectivity of rhombohedral ceramic La_1-ySr_yMn_1-xM_xO_3 manganites in the temperature range between 77 and 320K. In our samples, a part of the Mn atoms is…

Strongly Correlated Electrons · Physics 2009-11-11 A. Dubroka , J. Humlicek , M. V. Abrashev , Z. V. Popovic , F. Sapina , A. Cantarero

Taking advantage of the large electron escape depth of soft x-ray angle resolved photoemission spectroscopy we report electronic structure measurements of (111)-oriented [LaNiO3/LaMnO3] superlattices and LaNiO3 epitaxial films. For thin…

Measurements of the low-frequency (f<=100 kHz) permittivity and conductivity at T<= 150 K are reported for La(1-x)Ca(x)MnO(3) (0<=x<=1) and Ca(1-y)Sr(y)MnO(3) (0<=y<=0.75) having antiferromagnetic, insulating ground states covering a broad…

Strongly Correlated Electrons · Physics 2009-11-10 J. L. Cohn , M. Peterca , J. J. Neumeier

The valence band electronic structure of Pr$_{0.5}$Sr$_{0.5}$MnO$_3$ has been investigated across its paramagnetic metallic (PMM) - ferromagnetic metallic (FMM) - antiferromagnetic insulator (AFMI) transition. Using surface sensitive high…

Materials Science · Physics 2011-04-19 P. Pal , M. K. Dalai , I. Ulfat

In this paper, we investigate the ground state properties of the $\rm{RMnO}_3/\rm{AMnO}_3$ ($\rm{RMO/AMO}$) heterostructures (R=trivalent cation, and A=divalent cation) by using a two-orbital double-exchange model supplemented by the…

Strongly Correlated Electrons · Physics 2015-05-13 Rong Yu , Seiji Yunoki , Shuai Dong , Elbio Dagotto

The local atomic disorder and the electronic structure in the environment of manganese atoms in LaMnO_3 has been studied by x-ray absorption spectroscopy, over a temperature range (300K to 870K) covering the orbital ordering transition…

Strongly Correlated Electrons · Physics 2009-11-10 Raquel A. Souza , Narcizo M. Souza-Neto , Aline Y. Ramos , Helio C. N. Tolentino , Eduardo Granado

We investigate the effect of $A$-site size differences in the double perovskites BiScO$_3$-$M$NbO$_3$ ($M$$=$Na, K and Rb) using first-principles calculations. We find that the polarization of these materials is 70$\sim$90 $\mu$C/cm$^2$…

Materials Science · Physics 2010-11-24 S. Takagi , A. Subedi , V. R. Cooper , D. J. Singh

Artificial PbTiO$_{3}$/SrTiO$_{3}$ superlattices were constructed using off-axis RF magnetron sputtering. X-ray diffraction and piezoelectric atomic force microscopy were used to study the evolution of the ferroelectric polarization as the…

Materials Science · Physics 2009-11-11 M. Dawber , C. Lichtensteiger , M. Cantoni , M. Veithen , P. Ghosez , K. Johnston , K. M. Rabe , J. -M. Triscone

Depth-sensitive magnetic, structural and chemical characterization is important in the understanding and optimization of novel physical phenomena emerging at interfaces of transition metal oxide heterostructures. In a simultaneous approach…

By means of density-functional simulations for half-doped manganites, such as pseudocubic Pr0.5Ca0.5MnO3 and bilayer PrCa2Mn2O7, we discuss the occurrence of ferroelectricity and we explore its crucial relation to the crystal structure and…

Strongly Correlated Electrons · Physics 2013-10-07 Kunihiko Yamauchi , Silvia Picozzi

Results from dielectric and structural measurements on epitaxial SrTiO$_3$/BaZrO$_3$ superlattices reveal properties that cannot be explained simply in terms of those measured on single films of the constituent materials. For large…

Materials Science · Physics 2009-11-10 Hans M. Christen , Eliot D. Specht , Sherwood S. Silliman , K. S. Harshavardhan

The polar discontinuity at the SrTiO3/LaAlO3 interface (STO/LAO) can in principle sustain an electron density of 3.3E14 cm-2 (0.5 electrons per unit cell). However, experimentally observed densities are more than an order of magnitude…

Materials Science · Physics 2015-06-12 A. Janotti , L. Bjaalie , L. Gordon , C. G. Van de Walle

We have investigated the phonon and the magnetic excitations in LaCoO3 by inelastic neutron scattering measurements. The acoustic phonon dispersions show some characteristic features of the folded Brillouin zone (BZ) for the rhombohedrally…

Strongly Correlated Electrons · Physics 2009-11-11 Y. Kobayashi , Thant Sin Naing , M. Suzuki , M. Akimitsu , K. Asai , K. Yamada , J. Akimitsu , P. Manuel , J. M. Tranquada , G. Shirane

Since its original prediction 25 years ago, room-temperature out-of-plane ferroelectricity in compressively strained SrTiO3 remains an ongoing pursuit. In this work, we investigate the structural, electrical and electromechanical properties…

The ground state properties of the pure perovskite compounds PrMnO$_3$ and NdMnO$_3$ were investigated by magnetization, magnetic AC susceptibility and specific heat measurements. A strongly anisotropic behavior has been detected for…

Condensed Matter · Physics 2007-05-23 J. Hemberger , M. Brando , R. Wehn , V. Yu. Ivanov , A. A. Mukhin , A. M. Balbashov , A. Loidl

An unusual atomic scale chemical fluctuation in LaSrVMoO$_6$, in terms of narrow patches of La,V and Sr,Mo-rich phases, has been probed in detail to understand the origin of such a chemical state. Exhaustive tuning of the equilibrium…

Near or less than 10% Nb substitution on the Ti site in perovskite SrTiO$_3$ results in metallic behavior, in contrast to what is seen in BaTiO$_3$. Given the nearly identical structure and electron counts of the two materials, the distinct…

Materials Science · Physics 2008-12-14 Katharine Page , Taras Kolodiazhnyi , Thomas Proffen , Anthony K. Cheetham , Ram Seshadri