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We have studied the optical properties of four (LaNiO$_3$)$_n$/(LaMnO$_3$)$_2$ superlattices (SL) ($n$=2, 3, 4, 5) on SrTiO$_3$ substrates. We have measured the reflectivity at temperatures from 20 K to 400 K, and extracted the optical…

Strongly Correlated Electrons · Physics 2015-06-24 P. Di Pietro , J. Hoffman , A. Bhattacharya , S. Lupi , A. Perucchi

(LaNiO3)n/(LaMnO3)2 superlattices were grown using ozone-assisted molecular beam epitaxy, where LaNiO3 is a paramagnetic metal and LaMnO3 is an antiferromagnetic insulator. The superlattices exhibit excellent crystallinity and interfacial…

We report on the infrared absorption spectra of three oxides where charged superlattices have been recently observed in diffraction experiments. In La$_{1.67}$Sr$_{0.33}$NiO$_4$, polaron localization is found to suppress the low-energy…

Condensed Matter · Physics 2009-10-28 P. Calvani , A. Paolone , P. Dore , S. Lupi , P. Maselli , P. G. Medaglia , S-W. Cheong

Epitaxial bilayered thin films consisting of La0.6Sr0.4MnO3 (LSMO) and 0.7 Pb(Mg1/3Nb2/3)O3 0.3 PbTiO3 (PMN-PT) layers of relatively different thicknesses were fabricated on LaNiO3 coated LaAlO3 (100) single crystal substrates by pulsed…

Materials Science · Physics 2011-06-29 Ayan Roy Chaudhuri , S. B. Krupanidhi , P. Mandal , A. Sundaresan

The spontaneous polarization of epitaxial BaTiO$_3$/SrTiO$_3$ superlattices is studied as a function of composition using first-principles density functional theory within the local density approximation. With the in-plane lattice parameter…

Materials Science · Physics 2009-11-07 J. B. Neaton , K. M. Rabe

We investigate the structural, electronic, transport, and thermoelectric properties of LaNiO$_3$/SrTiO$_3(001)$ superlattices containing either exclusively $n$- or $p$-type interfaces or coupled interfaces of opposite polarity by using…

Materials Science · Physics 2017-03-03 Benjamin Geisler , Ariadna Blanca-Romero , Rossitza Pentcheva

Charge transfer is of particular importance in manipulating the interface physics in transition-metal oxide heterostructures. In this work, we have fabricated epitaxial bilayers composed of polar 3d LaMnO3 and nonpolar 5d SrIrO3. Systematic…

Mesoscale and Nanoscale Physics · Physics 2019-04-12 Tao Yu , Bei Deng , Liang Zhou , Pingbo Chen , Qiying Liu , Xingkun Ning , Jingtian Zhou , Zhiping Bian , Zhenlin Luo , Chunyin Qiu , Xingqing Shi , Hongtao He

Based on density functional theory calculations and group theoretical analysis, we have studied NaLaMnWO$_{6}$ compound which has been recently synthesized [Phys. Rev. B 79, 224428 (2009)] and belongs to the $AA'BB'{\rm O}_{6}$ family of…

Materials Science · Physics 2017-09-13 T. Fukushima , A. Stroppa , S. Picozzi , J. M. Perez-Mato

We present angle-resolved photoemission spectroscopy results on thin films of the three-dimensional manganite perovskite La1-xSrxMnO3, with TC = 240 K. In the low-binding energy region, we found two energy bands, one dispersing along the…

Strongly Correlated Electrons · Physics 2007-09-01 M. C. Falub , M. Shi , P. R. Willmott , J. Krempasky , S. G. Chiuzbaian , K. Hricovini , L. Patthey

We report a x-ray resonant diffraction study of the perovskite Pr0.6Ca0.4MnO3. At the Mn K-edge, this technique is sensitive to details of the electronic structure of the Mn atoms. We discuss the resonant x-ray spectra measured above and…

Strongly Correlated Electrons · Physics 2009-11-10 S. Grenier , J. P. Hill , Doon Gibbs , K. J. Thomas , M. v. Zimmermann , C. S. Nelson , V. Kiryukhin , Y. Tokura , D. Casa , T. Gog , C. Venkataraman

The temperature dependence of the electrical resistivity of the heterostructures consisting of single crystalline LaMnO$_3$ samples with different crystallographic orientations covered by the epitaxial ferroelectric…

Strongly Correlated Electrons · Physics 2017-10-20 D. P. Pavlov , I. I. Piyanzina , V. M. Mukhortov , A. M. Balbashov , D. A. Tayurskii , I. A. Garifullin , R. F. Mamin

We use density functional calculations to investigate the accommodation and migration of oxygen vacancies in bulk hexagonal YMnO$_3$, and to study interactions between neutral ferroelectric domain walls and oxygen vacancies. Our…

Using first-principles density functional theory we predict a ferroelectric ground state -- driven by off-centering of the magnetic Mn$^{4+}$ ion -- in perovskite-structure BaMnO$_3$. Our finding is surprising, since the competition between…

Materials Science · Physics 2009-05-28 James M. Rondinelli , Aaron S. Eidelson , Nicola A. Spaldin

Motivated by the colossal negative thermal expansion recently found in BiNiO$_3$, the valence transition accompanied by the charge transfer between the Bi and Ni sites is theoretically studied. We introduce an effective model for Bi-$6s$…

Strongly Correlated Electrons · Physics 2016-02-10 Makoto Naka , Hitoshi Seo , Yukitoshi Motome

Ferroelectric soft mode in Pb(Mg1/3Nb2/3)O3 (PMN) has been clearly resolved by precision Raman scattering measurements for the first time. A polarization direction of the incident laser was chosen along [110] in cubic configuration in order…

Materials Science · Physics 2009-09-23 Hiroki Taniguchi , Masanori Oishi , Desheng Fu , Mitsuru Itoh

Recent works suggest that the surface chemistry, in particular, the presence of oxygen vacancies can affect the polarization in a ferroelectric material. This should, in turn, influence the domain ordering driven by the need to screen the…

Materials Science · Physics 2018-06-08 Yanyu Mi , Gregory Geneste , Julien Rault , Claire Mathieu , Alexandre Pancotti , Nicholas Barrett

We present a first-principles study on the interface between perovskite ferroelectrics (PbTiO3) and conducting magnetic manganites La_{1-x}Sr_xMnO3. We show that by switching the ferroelectric polarization, additional carriers are…

Materials Science · Physics 2015-06-11 Hanghui Chen , Sohrab Ismail-Beigi

The instability of ferroelectric ordering in ultra-thin films is one of the most important fundamental issues pertaining realization of a number of electronic devices with enhanced functionality, such as ferroelectric and multiferroic…

We report an electric-field poling study of the geometric-driven improper ferroelectric h-ErMnO$_3$. From a detailed dielectric analysis we deduce the temperature and frequency dependent range for which single-crystalline h-ErMnO$_3$…

This paper presents the bond valence calculation for several perovskite systems and describes the evidences for a valence charge transfer process in these compounds. The reviewing of the crystal structures of La1-xPbxMnO3 (x=0.1-0.5),…

Materials Science · Physics 2007-05-23 Hoang Nam Nhat
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