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The principle of microscopic reversibility lies at the core of fluctuation theorems, which have extended our understanding of the second law of thermodynamics to the statistical level. In the quantum regime, however, this elementary…

We prove the second law of thermodynamics and the nonequilibirum fluctuation theorem for pure quantum states.The entire system obeys reversible unitary dynamics, where the initial state of the heat bath is not the canonical distribution but…

Statistical Mechanics · Physics 2017-09-13 Eiki Iyoda , Kazuya Kaneko , Takahiro Sagawa

We study an arbitrary non-equilibrium dynamics of a quantum bipartite system coupled to a reservoir. For its characterization, we present a fluctuation theorem (FT) that explicitly addresses the quantum correlation of subsystems during the…

Quantum Physics · Physics 2020-05-22 Jung Jun Park , Hyunchul Nha , Sang Wook Kim , Vlatko Vedral

Stochastic thermodynamics extends the notions and relations of classical thermodynamics to small systems that experience strong fluctuations. The definitions of work and heat and the microscopically reversible condition are two key concepts…

Statistical Mechanics · Physics 2019-07-23 Geng Li , Z. C. Tu

The nonzero ground-state energy of the quantum mechanical harmonic oscillator implies quantum fluctuations around the minimum of the potential with the mean square value proportional to Planck's constant. In classical mechanics thermal…

Quantum Physics · Physics 2020-09-02 K. Schönhammer

This article sets up a new formalism to investigate stochastic thermodynamics of out-of-equilibrium quantum systems, where stochasticity primarily comes from quantum measurement. In the absence of any bath, we define a purely quantum…

Quantum Physics · Physics 2016-10-17 Cyril Elouard , David Herrera Marti , Maxime Clusel , Alexia Auffèves

We study quantum measurements of temporal equilibrium fluctuations in macroscopic quantum systems. It is shown that the fluctuation-dissipation theorem, as a relation between observed quantities, is partially violated in quantum systems,…

Statistical Mechanics · Physics 2017-02-13 Akira Shimizu , Kyota Fujikura

Quantum measurement is a physical process. A system and an apparatus interact for a certain time period (measurement time), and during this interaction, information about an observable is transferred from the system to the apparatus. In…

Quantum Physics · Physics 2016-10-31 Takayuki Miyadera

The past two decades witnessed important developments in the field of non-equilibrium statistical mechanics. Among these developments, the Jarzynski equality, being a milestone following the landmark work of Clausius and Kelvin, stands out.…

Quantum Physics · Physics 2015-06-22 Shuoming An , Jing-Ning Zhang , Mark Um , Dingshun Lv , Yao Lu , Junhua Zhang , Zhang-qi Yin , H. T. Quan , Kihwan Kim

We treat a quantum mechanical system with certain general properties which are expected to be common in macroscopic quantum systems. Starting from a PURE initial state (which may not describe an equilibrium) in which energy is mildly…

Statistical Mechanics · Physics 2007-05-23 Hal Tasaki

We present a fluctuation theorem for quantum bipartite systems in which the subsystems exchange information with each other. Our information fluctuation theorem includes correlations by introducing a quantum mechanical mutual information…

Quantum Physics · Physics 2020-06-24 Jung Jun Park , Sang Wook Kim , Vlatko Vedral

The second law of thermodynamics for adiabatic operations -- constraints on state transitions in closed systems under external control -- is one of the fundamental principles of thermodynamics. On the other hand, it is recently established…

Statistical Mechanics · Physics 2026-02-09 Yuuya Chiba , Yasushi Yoneta , Ryusuke Hamazaki , Akira Shimizu

A main goal of single-molecule experiments is to evaluate equilibrium free energy differences by applying fluctuation relations to repeated work measurements along irreversible processes. We quantify the error that is made in a free energy…

Statistical Mechanics · Physics 2009-06-22 Alessandro Mossa , Sara de Lorenzo , Josep Maria Huguet , Felix Ritort

We investigate the statistics of heat exchange between a finite system coupled to reservoir(s). We have obtained analytical results for heat fluctuation theorem in the transient regime considering the Hamiltonian dynamics of the composite…

Statistical Mechanics · Physics 2017-04-19 P. S. Pal , Sourabh Lahiri , A. M. Jayannavar

We have experimentally checked the Jarzynski equality and the Crooks relation on the thermal fluctuations of a macroscopic mechanical oscillator in contact with a heat reservoir. We found that, independently of the time scale and amplitude…

Statistical Mechanics · Physics 2009-11-11 F. Douarche , S. Ciliberto , A. Petrosyan , I. Rabbiosi

Quantum thermodynamics allows for the interconversion of quantum coherence and mechanical work. Quantum coherence is thus a potential physical resource for quantum machines. However, formulating a general nonequilibrium thermodynamics of…

Quantum Physics · Physics 2025-11-05 Franklin L. S. Rodrigues , Eric Lutz

Fluctuation relations (FRs) are among the few existing general results in non-equilibrium systems. Their verification requires the measurement of the total work (or entropy production) performed on a system. Nevertheless in many cases only…

Statistical Mechanics · Physics 2015-09-25 Marco Ribezzi-Crivellari , Felix Ritort

The second law of thermodynamics posits that in closed macroscopic systems the rate of entropy production must be positive. However, small systems can exhibit negative entropy production over short timescales, seemingly in contradiction…

Quantum Gases · Physics 2023-08-08 Rama Sharma , Tapio P. Simula , Andrew J. Groszek

In this paper, we study Jarzynski's equality and fluctuation theorems for diffusion processes. While some of the results considered in the current work are known in the (mainly physics) literature, we review and generalize these…

Mathematical Physics · Physics 2019-04-09 Carsten Hartmann , Christof Schuette , Wei Zhang

We consider a finite dimensional quantum system $S$ in an arbitrary initial state coupled to an infinitely extended quantum thermal reservoir $R$ in equilibrium at inverse temperature $\beta$. The coupling is given by a bounded perturbation…

Mathematical Physics · Physics 2021-10-06 Jane Panangaden