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Here we present a fundamental comprehension of the microscopic mechanisms leading to the emergence of inverse melting transitions by considering a thorough mean-field analysis of a variety of minimal models with different competing…

Materials Science · Physics 2020-07-20 Alejandro Mendoza-Coto , Lucas Nicolao , Rogelio Díaz-Méndez

We present an exact microcanonical formulation, in the thermodynamic limit, for a system of $N$ noninteracting particles with $p$ equally spaced energy levels $\{0,\epsilon,2\epsilon,\ldots,(p-1)\epsilon\}$. Writing the microcanonical…

Statistical Mechanics · Physics 2026-05-05 J. Ricardo de Sousa

Two recently proposed expressions for the computation of the entropy in the microcanonical ensemble are compared, and their equivalence is proved. These expressions are valid for a certain class of statistical mechanics systems, that can be…

Statistical Mechanics · Physics 2007-05-23 Alessandro Campa

Ensemble inequivalence, i.e. the possibility of observing different thermodynamic properties depending on the statistical ensemble which describes the system, is one of the hallmarks of long-range physics, which has been demonstrated in…

Statistical Mechanics · Physics 2024-08-15 Nicolò Defenu , David Mukamel , Stefano Ruffo

It is well known that long-range interactions pose serious problems for the formulation of statistical mechanics. We show in this paper that ensemble equivalence is violated in a simple mean-field model of N fully coupled classical rotators…

Statistical Mechanics · Physics 2015-06-24 Thierry Dauxois , Peter Holdsworth , Stefano Ruffo

We study the Hamiltonian Mean Field (HMF) model, a system of $N$ fully coupled particles, in the microcanonical ensemble. We use the previously obtained free energy in the canonical ensemble to derive entropy as a function of energy, using…

Condensed Matter · Physics 2007-05-23 Mickael Antoni , Haye Hinrichsen , Stefano Ruffo

The classical wave-particle Hamiltonian is considered in its generalized version, where two modes are assumed to interact with the co-evolving charged particles. The equilibrium statistical mechanics solution of the model is worked out…

Statistical Mechanics · Physics 2015-06-18 Tarcísio N. Teles , Duccio Fanelli , Stefano Ruffo

A generalized entropy arising in the context of superstatistics is obtained for an ideal gas. The curvature scalar associated to the thermodynamic space generated by this modified entropy is calculated using two formalisms of the geometric…

Statistical Mechanics · Physics 2018-04-18 J. L. López , O. Obregón , J. Torres-Arenas

We introduce the idea of weakly coherent collisional models, where the elements of an environment interacting with a system of interest are prepared in states that are approximately thermal, but have an amount of coherence proportional to a…

One of the outstanding problems in non-equilibrium physics is to precisely understand when and how physically relevant observables in many-body systems equilibrate under unitary time evolution. General equilibration results show that…

Quantum Physics · Physics 2020-02-18 Henrik Wilming , Marcel Goihl , Ingo Roth , Jens Eisert

We consider viscous, heat conducting mixtures of molecularly miscible chemical species forming a fluid in which the constituents can undergo chemical reactions. Assuming a common temperature for all components, we derive a closed system of…

Fluid Dynamics · Physics 2016-04-01 Dieter Bothe , Wolfgang Dreyer

The paper is concerned with proving the equivalence of convexity or concavity properties of thermodynamic functions, such as energy and entropy, depending on different sets of variables. These variables are the basic thermodynamic state…

Analysis of PDEs · Mathematics 2025-10-29 Mária Lukáčová-Medvid'ová , Ferdinand Thein , Gerald Warnecke , Yuhuan Yuan

A pure quantum state can fully describe thermal equilibrium as long as one focuses on local observables. Thermodynamic entropy can also be recovered as the entanglement entropy of small subsystems. When the size of the subsystem increases,…

Statistical Mechanics · Physics 2018-05-31 Yuya O. Nakagawa , Masataka Watanabe , Hiroyuki Fujita , Sho Sugiura

We apply the method of gauge transformation to spin glasses under the microcanonical ensemble to study the possibility of ensemble inequivalence in systems with long-range interactions and quenched disorder. It is proved that all the…

Disordered Systems and Neural Networks · Physics 2015-03-17 Hidetoshi Nishimori

In systems with long-range interactions, since energy is a non-additive quantity, ensemble inequivalence can arise: it is possible that different statistical ensembles lead to different equilibrium descriptions, even in the thermodynamic…

Statistical Mechanics · Physics 2018-09-05 Marco Baldovin

Ensemble inequivalence has been previously displayed only for long-range interacting systems with non-extensive energy. In order to perform the thermodynamic limit, such systems require an unphysical, so-called, Kac rescaling of the…

Statistical Mechanics · Physics 2017-06-12 Levon Chakhmakhchyan , Tarcisio N. Teles , Stefano Ruffo

The development of reliable methods for estimating microcanonical averages constitutes an important issue in statistical mechanics. One possibility consists of calculating a given microcanonical quantity by means of typical relations in the…

Statistical Mechanics · Physics 2015-06-11 Carlos E. Fiore , Cláudio J. DaSilva

The relationship between the mean-field approximations in various interacting models of statistical physics and measures of classical and quantum correlations is explored. We present a method that allows us to bound the total amount of…

Quantum Physics · Physics 2009-11-10 Vlatko Vedral

We discuss the thermodynamic limit in the canonical area ensemble used in loop quantum gravity to model quantum black holes. The computation of the thermodynamic limit is the rigorous way to obtain a smooth entropy from the counting entropy…

General Relativity and Quantum Cosmology · Physics 2011-09-27 J. Fernando Barbero G. , Eduardo J. S. Villaseñor

Introduced by Boltzmann under the name "monode," the microcanonical ensemble serves as the fundamental representation of equilibrium thermodynamics in statistical mechanics by counting all possible realizations of a system's states.…

Statistical Mechanics · Physics 2026-01-27 Roman Belousov , Jenna Elliott , Florian Berger , Lamberto Rondoni , Anna Erzberger